diallylpropylamine | 6798-84-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: diallylpropylamine
• 英文别名: diallyl-propyl-amine；N-(n-Propyl)-diallylamin；N,N-Diallyl-propyl-amin；Diallylpropylamin；N,N-diallylpropan-1-amine；N,N-bis(prop-2-enyl)propan-1-amine
• CAS: 6798-84-1
• 化学式: C₉H₁₇N
• 分子量: 139.241
• InChiKey: SEYMDVNXUCWGRD-UHFFFAOYSA-N

物化性质

• 沸点：
  76-78 °C(Press: 15 Torr)
• 密度：
  0.797±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  diallylpropylamine 、 triethyloxonium fluoroborate 以 二氯甲烷 为溶剂， 以77%的产率得到N-ethyl-N-propyl-N,N-diallylammonium tetrafluoroborate
  参考文献：
  名称：

  Kumar, P. Santhosh; Wurst, K.; Buchmeiser, Michael R., Journal of the American Chemical Society, 2009, vol. 131, p. 387 - 395

  摘要：

  DOI：
• 作为产物：
  描述：

  正丙胺 、 3-溴丙烯 在 potassium carbonate 作用下， 以 乙醚 为溶剂， 生成 diallylpropylamine
  参考文献：
  名称：

  The Sodium—Ammonia Reduction of Bispropargyl- and Propargylallylamines. Steric and Conformational Effects¹

  摘要：

  DOI：

  10.1021/jo01344a510

文献信息

• ORGANIC ELECTRONIC MATERIAL, POLYMERIZATION INITIATOR AND THERMAL POLYMERIZATION INITIATOR, INK COMPOSITION, ORGANIC THIN FILM AND PRODUCTION METHOD FOR SAME, ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTROLUMINESCENT ELEMENT, LIGHTING DEVICE, DISPLAY ELEMENT, AND DISPLAY DEVICE
  申请人：Ishitsuka Kenichi

  公开号：US20130037753A1

  公开（公告）日：2013-02-14

  Disclosed is an organic electronic material comprising charge transporting compounds and ionic compounds having electron-accepting properties and high solubility in a solvent. The organic electronic material is characterized by comprising charge transporting compounds and ionic compounds, and in that at least one of the ionic compounds is any one kind of compounds represented by general formulas (1b)-(3b). (In the formulas Y 1 -Y 6 each independently represent a divalent linking group, R 1 -R 6 each independently represent an electron-attracting organic substituent (these structures can further have substituents and hetero-atoms, and R 1 , R 2 and R 3 , or, R 4 -R 6 can respectively combine and become a ring shape or a polymer shape) and L + represents a monovalent cation.)

  本文揭示了一种有机电子材料，包括具有电荷传输化合物和具有接受电子性质且在溶剂中具有高溶解度的离子化合物。该有机电子材料的特点在于包括电荷传输化合物和离子化合物，并且至少其中一个离子化合物是由通用式（1b）-（3b）表示的化合物中的任意一种。（在式中，Y1-Y6分别表示二价连接基团，R1-R6分别表示吸引电子的有机取代基（这些结构可以进一步具有取代基和杂原子，且R1、R2和R3，或者R4-R6可以分别结合形成环状或聚合物形状），L+表示一价阳离子。）
• Partially decomposed catalyst and hydrocarbon oxidation processes using the same
  申请人：Dakka Mohammed Jihad

  公开号：US20060293544A1

  公开（公告）日：2006-12-28

  The present invention is related to a hydrocarbon oxidation process. The process comprises bringing one or more hydrocarbons into contact with a source of oxygen in the presence of a radical initiator and a catalyst. The catalyst comprises an organic metal complex located on a catalyst support, and is obtained by partial decomposition of the organic metal complex. For example, the process can be used to produce dimethyl carbonate from dimethoxy methane. The invention is also related to a partially decomposed catalyst that comprises a silica support and an organic metal complex, wherein at least 5% of the organic compound remains in the catalyst. The organic metal complex comprises an organic compound and a metal-based compound wherein the metal is selected from copper, nickel, and combinations thereof. The invention is also related to a process for manufacturing of a catalyst comprising mixing L-arginine, a Cu-based compound, water, and optionally another metal-based compound to form a solution; impregnating the solution onto a silica support to form a catalyst precursor; and partially decomposing the L-arginine to form the catalyst so that at least 5% of L-arginine remains in the catalyst.

  本发明涉及一种烃氧化过程。该过程包括将一个或多个烃与氧源在自由基引发剂和催化剂存在下接触。催化剂包括位于催化剂支撑物上的有机金属配合物，通过部分分解有机金属配合物获得。例如，该过程可用于从二甲氧甲烷生产二甲基碳酸酯。该发明还涉及一种部分分解的催化剂，该催化剂包括硅支撑物和有机金属配合物，其中催化剂中至少有5%的有机化合物残留。有机金属配合物包括有机化合物和基于金属的化合物，其中金属选自铜、镍和它们的组合。该发明还涉及一种催化剂制造方法，包括混合L-精氨酸、一种基于铜的化合物、水，以及可选的另一种基于金属的化合物以形成溶液；将溶液浸渍到硅支撑物上以形成催化剂前驱体；并部分分解L-精氨酸以形成催化剂，使催化剂中至少有5%的L-精氨酸残留。
• Process for Producing Phenol
  申请人：Xu Teng

  公开号：US20140148620A1

  公开（公告）日：2014-05-29

  In a process for the dehydrogenation of cyclohexanone to produce phenol, cyclohexanone is contacted in a reaction zone under dehydrogenation conditions with a dehydrogenation catalyst comprising (i) a support comprising silica; and (ii) a dehydrogenation component comprising at least one metal selected from Group 10 of Periodic Table of Elements. Contact of the dehydrogenation catalyst with the cyclohexanone is then terminated and the dehydrogenation catalyst is contacted with an inert gas and/or hydrogen at a temperature of at least 300° C. Contact of the dehydrogenation catalyst with additional cyclohexanone is subsequently reestablished.

  在用于脱氢环己酮制备苯酚的过程中，将环己酮在反应区域中在脱氢条件下与脱氢催化剂接触，所述脱氢催化剂包括（i）硅质载体和（ii）至少选自元素周期表第10族的一种金属的脱氢组分。然后终止脱氢催化剂与环己酮的接触，并将脱氢催化剂与惰性气体和/或氢接触，温度至少为300°C。随后重新建立脱氢催化剂与额外环己酮的接触。
• Polymers based on n,n-diallylamine derivatives their production and use
  申请人：Becker Stefan

  公开号：US20070004889A1

  公开（公告）日：2007-01-04

  The present invention relates to processes for the preparation of novel polymers starting from the reaction of diallylamine or diallylamine derivatives with olefinically unsaturated compounds within the framework of a Michael addition and subsequent free-radical polymerization of the Michael adducts, if appropriate in the presence of further free-radically polymerizable compounds. The invention also provides the corresponding Michael adducts of diallylamine and its derivatives, and also the use of the novel polymers.

  本发明涉及一种从二烯基胺或二烯基胺衍生物与烯丙基不饱和化合物进行迈克尔加成反应并随后自由基聚合迈克尔加成物的制备过程，如有必要，在进一步自由基聚合性化合物的存在下。本发明还提供了二烯基胺及其衍生物的相应迈克尔加成物，并提供了新型聚合物的使用。
• Organic Electronic Material, Ink Composition Containing Same, and Organic Thin Film, Organic Electronic Element, Organic Electroluminescent Element, Lighting Device, and Display Device Formed Therewith
  申请人：Funyuu Shigeaki

  公开号：US20120074360A1

  公开（公告）日：2012-03-29

  Provided are: an organic electronic material which can be easily multilayered and that can be used in substrates, such as resin, that cannot be processed at high temperatures; an ink composition containing the same; an organic thin film formed using said organic electronic material or said ink composition; and an organic electronic element and an organic EL element that are formed using said organic thin film and that have a superior luminous efficacy and emission lifespan than conventional elements. Specifically, provided are: an organic electronic material that is characterized by containing an oligomer or a polymer having a structure that branches into three or more directions and has at least one polymerizable substituent; an ink composition containing said organic electronic material; and an organic thin film prepared using the aforementioned organic electronic material. Further, provided are an organic electronic element and an organic electroluminescent element containing said organic thin film.

  提供了以下内容：一种有机电子材料，可以轻松地多层堆叠，并可用于无法在高温下加工的基板，例如树脂；包含相同材料的墨水组合物；使用该有机电子材料或该墨水组合物形成的有机薄膜；以及使用该有机薄膜形成的有机电子元件和有机EL元件，其具有比传统元件更优异的发光效率和发射寿命。具体而言，提供了一种有机电子材料，其特征在于包含具有分支结构且向三个或更多方向分支的寡聚物或聚合物，并具有至少一个可聚合取代基；包含该有机电子材料的墨水组合物；以及使用上述有机电子材料制备的有机薄膜。此外，还提供了包含该有机薄膜的有机电子元件和有机电致发光元件。