3-(p-tolyl)naphthalen-1-yl trifluoromethanesulfonate

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 3-(p-tolyl)naphthalen-1-yl trifluoromethanesulfonate
• 英文别名: [3-(4-Methylphenyl)naphthalen-1-yl] trifluoromethanesulfonate；[3-(4-methylphenyl)naphthalen-1-yl] trifluoromethanesulfonate
• 化学式: C₁₈H₁₃F₃O₃S
• 分子量: 366.361
• InChiKey: PHKZKDSXZVHDHI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  25
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  (10-苯基蒽-9-基)硼酸 、 3-(p-tolyl)naphthalen-1-yl trifluoromethanesulfonate 在 四(三苯基膦)钯 、 potassium carbonate 作用下， 以 乙醇 、 水 、 甲苯 为溶剂， 反应 12.0h， 以52.9%的产率得到9-[3-(4-Methylphenyl)naphthalen-1-yl]-10-phenylanthracene
  参考文献：
  名称：

  Anthracene derivatives and organic light emitting devices comprising the same

  摘要：

  公开了由公式1表示的蒽衍生物。还公开了一种包括阳极、阴极和位于阳极和阴极之间的有机层的有机发光器件，其中有机层包括至少一种由公式1表示的蒽衍生物。还公开了一种制造该有机发光器件的方法。

  公开号：

  US10388882B2
• 作为产物：
  描述：

  1-bromo-2-(p-tolylethynyl)benzene 在 copper(l) iodide 、 二(氰基苯)二氯化钯 、 三叔丁基膦 、 potassium carbonate 、 三乙胺 作用下， 以 四氢呋喃 、 甲醇 、 氯仿 、 甲苯 为溶剂， 反应 28.0h， 生成 3-(p-tolyl)naphthalen-1-yl trifluoromethanesulfonate
  参考文献：
  名称：

  Synthesis of Naphthalenyl Triflates via the Cationic Annulation of Benzodiynes with Triflic Acid

  摘要：

  A highly efficient and regioselective annulation of benzodiynes promoted by triflic acid has been developed. This protocol provides a step and atom-economic access to a series of naphthalenyl triflates. Furthermore, direct synthetic applications of this reaction are also elaborated through cross-coupling reactions to generate synthetically useful multisubstituted naphthalenes.

  DOI：

  10.1021/acs.orglett.9b01590

文献信息

• ORGANIC LIGHT-EMITTING DIODE WITH HIGH EFFICIENCY AND LONG LIFETIME
  申请人：SFC CO., LTD.

  公开号：US20170012214A1

  公开（公告）日：2017-01-12

  Disclosed herein is an organic light-emitting diode, comprising: an organic light-emitting diode, comprising: a first electrode; a second electrode facing the first electrode; a light-emitting layer intercalated between the first electrode and the second electrode, wherein the light-emitting layer comprises at least one of the amine compounds represented by Chemical Formula A or B, and at least one of the anthracene compounds represented by Chemical Formula C.

  本文揭示了一种有机发光二极管，包括：一个第一电极；一个朝向第一电极的第二电极；夹在第一电极和第二电极之间的发光层，其中该发光层包括化学式A或B所代表的至少一种胺化合物，以及化学式C所代表的至少一种蒽化合物。
• Organic light emitting diode of high efficiency
  申请人：SFC CO., LTD.

  公开号：US10559758B2

  公开（公告）日：2020-02-11

  Disclosed herein is an organic light-emitting diode, comprising: a first electrode; a second electrode facing the first electrode; and a light-emitting layer and an electron density control layer in that order between the first electrode and the second electrode, wherein the electron density control layer includes at least one selected from among compounds represented by the following Chemical Formulas A to D, and the light emitting layer includes at least one anthracene compound represented by the following Chemical Formula H. The structures of Chemical Formulas A to D and H are as described in the specification.

  本文公开了一种有机发光二极管，包括：第一电极；与第一电极面对的第二电极；以及在第一电极和第二电极之间依次设置的发光层和电子密度控制层，其中电子密度控制层包括从以下化学式A至D所代表的化合物中选出的至少一种，发光层包括以下化学式H所代表的至少一种蒽化合物。
• Organic light-emitting diode with high efficiency and long lifetime
  申请人：SFC CO., LTD.

  公开号：US10790450B2

  公开（公告）日：2020-09-29

  Disclosed herein is an organic light-emitting diode, comprising: an organic light-emitting diode, comprising: a first electrode; a second electrode facing the first electrode; a light-emitting layer intercalated between the first electrode and the second electrode, wherein the light-emitting layer comprises at least one of the amine compounds represented by Chemical Formula A or B, and at least one of the anthracene compounds represented by Chemical Formula C.

  本文公开了一种有机发光二极管，包括：有机发光二极管，其中包括：第一电极；正对第一电极的第二电极；夹在第一电极和第二电极之间的发光层，其中发光层包括化学式 A 或 B 所代表的胺化合物中的至少一种，以及化学式 C 所代表的蒽化合物中的至少一种。
• Synthesis of Naphthalenyl Triflates via the Cationic Annulation of Benzodiynes with Triflic Acid
  作者：Chenxin Ge、Guohua Wang、Panpan Wu、Chao Chen

  DOI：10.1021/acs.orglett.9b01590

  日期：2019.7.5

  A highly efficient and regioselective annulation of benzodiynes promoted by triflic acid has been developed. This protocol provides a step and atom-economic access to a series of naphthalenyl triflates. Furthermore, direct synthetic applications of this reaction are also elaborated through cross-coupling reactions to generate synthetically useful multisubstituted naphthalenes.
• Anthracene derivatives and organic light emitting devices comprising the same
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10388882B2

  公开（公告）日：2019-08-20

  An anthracene derivative represented by Formula 1 is disclosed. An organic light-emitting device including an anode, a cathode, and an organic layer between the anode and the cathode, where the organic layer includes at least one anthracene derivative represented by Formula 1, is also disclosed. A method of manufacturing the organic light-emitting device is also disclosed.

  公开了由公式1表示的蒽衍生物。还公开了一种包括阳极、阴极和位于阳极和阴极之间的有机层的有机发光器件，其中有机层包括至少一种由公式1表示的蒽衍生物。还公开了一种制造该有机发光器件的方法。