3,3-dimethyl-3H-benzo[c][1,2]oxathiol-1,1-dioxide | 81403-42-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 3,3-dimethyl-3H-benzo[c][1,2]oxathiol-1,1-dioxide
• 英文别名: 3,3-Dimethyl-3H-benzo[c][1,2]oxathiol-1,1-dioxid；3,3-Dimethyl-2,1lambda6-benzoxathiole 1,1-dioxide；3,3-dimethyl-2,1λ6-benzoxathiole 1,1-dioxide
• CAS: 81403-42-1
• 化学式: C₉H₁₀O₃S
• 分子量: 198.243
• InChiKey: RCNWKJWXBMZBGL-UHFFFAOYSA-N

物化性质

• 熔点：
  106-107 °C(Solv: ethanol (64-17-5))
• 沸点：
  303.0±22.0 °C(Predicted)
• 密度：
  1.282±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3,3-dimethyl-3H-benzo[c][1,2]oxathiol-1,1-dioxide 在 水 、 氢气 作用下， 生成 isopropenyl benzenesulfonic acid
  参考文献：
  名称：

  Intramolecularly catalyzed sulfonamide hydrolysis. 8. Intramolecular nucleophilic catalysis by a neighboring hydroxyl group in acid-catalyzed benzenesulfonamide hydrolysis

  摘要：

  DOI：

  10.1021/jo00193a001
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 盐酸 作用下， 生成 3,3-dimethyl-3H-benzo[c][1,2]oxathiol-1,1-dioxide
  参考文献：
  名称：

  Sachs; v. Wolff; Ludwig, Chemische Berichte, 1904, vol. 37, p. 3262

  摘要：

  DOI：

文献信息

• COMPOUND, PHOTOSENSITIVE RESIN COMPOSITION INCLUDING THE SAME, AND COLOR FILTER
  申请人：SAMSUNG SDI CO., LTD.

  公开号：US20180072709A1

  公开（公告）日：2018-03-15

  A compound, a photosensitive resin composition including the compound, and a color filter manufactured using the photosensitive resin composition, the compound being represented by Chemical Formula 1:

  一个化合物，包括该化合物的光敏树脂组合物，以及使用该光敏树脂组合物制造的彩色滤光片，该化合物由化学式1表示：
• PHOTOSENSITIVE COMPOSITIONS, PREPARATION METHODS THEREOF, AND QUANTUM DOT POLYMER COMPOSITE PREPARED
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP3136174A1

  公开（公告）日：2017-03-01

  A photosensitive composition including a quantum dot dispersion, a reactive compound having at least two thiol groups, a photopolymerizable monomer having a carbon-carbon double bond, and a photoinitiator, wherein the quantum dot dispersion includes a carboxylic acid group -containing polymer and a quantum dot dispersed in the carboxylic acid group containing polymer, and wherein the carboxylic acid group-containing polymer includes a copolymer of a monomer combination including a first monomer having a carboxylic acid group and a carbon-carbon double bond and a second monomer having a carbon-carbon double bond and a hydrophobic moiety and not having a carboxylic acid group.

  一种光敏组合物，包括量子点分散体、具有至少两个硫醇基团的活性化合物、具有碳碳双键的可光聚合单体和光引发剂，其中量子点分散体包括含羧酸基团的聚合物和分散在含羧酸基团聚合物中的量子点、其中含羧酸基团聚合物包括单体组合的共聚物，该单体组合包括具有羧酸基团和碳碳双键的第一单体以及具有碳碳双键和疏水分子且不具有羧酸基团的第二单体。
• QUANTUM DOTS, A COMPOSITION OR COMPOSITE INCLUDING THE SAME, AND AN ELECTRONIC DEVICE INCLUDING THE SAME
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP3327814A1

  公开（公告）日：2018-05-30

  A quantum dot including a first ligand and a second ligand on a surface of the quantum dot, a composition or composite including the same, and a device including the same. The first ligand includes a compound represented by Chemical Formula 1 and the second ligand includes a compound represented by Chemical Formula 2:          Chemical Formula 1     MAn wherein M, n, and A are the same as defined in the specification; and wherein, R1, L1, Y1, R, k1 and k2 are the same as defined in the specification.

  一种量子点，包括量子点表面的第一配位体和第二配位体，一种包括该量子点的组合物或复合材料，以及一种包括该量子点的装置。第一配体包括化学式 1 所代表的化合物，第二配体包括化学式 2 所代表的化合物： 化学式 1 MAn 其中 M、n 和 A 与说明书中定义的相同；以及 其中 R1、L1、Y1、R、k1 和 k2 与说明书中定义的相同。
• QUANTUM DOT COMPOSITION, QUANTUM DOT POLYMER COMPOSITE, AND LAYERED STRUCTURES AND ELECTRONIC DEVICES INCLUDING THE SAME
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP3480276A1

  公开（公告）日：2019-05-08

  A quantum dot composition comprising a quantum dot, a metal thiolate complex compound, and a solvent, wherein the metal thiolate complex compound includes a hydrophobic moiety, a thioether moiety (-S-), and a polyvalent metal, and wherein the hydrophobic moiety includes a fluorinated organic group, a multi-aromatic ring-containing group having a backbone structure that includes a quaternary carbon atom, which is a part of a cyclic group, and two aromatic rings bound to the quaternary carbon atom, or a combination thereof.

  一种量子点组合物，包括量子点、硫代金属络合物和溶剂，其中硫代金属络合物包括疏水基团、硫醚基团（-S-）和多价金属，疏水基团包括氟化有机基团、具有骨架结构的含多芳香环基团，骨架结构包括一个季碳原子，该季碳原子是环状基团的一部分，以及与季碳原子结合的两个芳香环，或它们的组合。
• PHOTOSENSITIVE COMPOSITIONS, PREPARATION METHODS THEREOF, AND QUANTUM DOT POLYMER COMPOSITE PREPARED THEREFROM
  申请人：Samsung Electronics Co., Ltd.

  公开号：EP3564750A1

  公开（公告）日：2019-11-06

  A photosensitive composition including a quantum dot dispersion, a reactive compound having at least two thiol groups, a photopolymerizable monomer having a carbon-carbon double bond, and a photoinitiator, wherein the quantum dot dispersion includes a carboxylic acid group -containing polymer and a quantum dot dispersed in the carboxylic acid group containing polymer, and wherein the carboxylic acid group-containing polymer includes a copolymer of a monomer combination including a first monomer having a carboxylic acid group and a carbon-carbon double bond and a second monomer having a carbon-carbon double bond and a hydrophobic moiety and not having a carboxylic acid group.

  一种光敏组合物，包括量子点分散体、具有至少两个硫醇基团的活性化合物、具有碳碳双键的可光聚合单体和光引发剂，其中量子点分散体包括含羧酸基团的聚合物和分散在含羧酸基团聚合物中的量子点、其中含羧酸基团聚合物包括单体组合的共聚物，该单体组合包括具有羧酸基团和碳碳双键的第一单体以及具有碳碳双键和疏水分子且不具有羧酸基团的第二单体。