trichlorovinylgermane | 4109-83-5

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: trichlorovinylgermane
• 英文别名: vinylgermanium trichloride；trichloroethenylgermane；vinyltrichlorogermane；Trichlor-vinyl-germanium；Trichlorgermyl-aethylen；(Trichlor)vinylgerman；trichloro(ethenyl)germane
• CAS: 4109-83-5
• 化学式: C₂H₃Cl₃Ge
• 分子量: 205.995
• InChiKey: DBJDXEXOJMALDQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.37
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  金刚烷 、 trichlorovinylgermane 在 三氯化铝 、 三氯氧磷 作用下， 以 neat (no solvent) 为溶剂， 以41.5%的产率得到1-[2-(trichlorogermyl)ethyl]adamantane
  参考文献：
  名称：

  Gar, T. K.; Chernysheva, O. N.; Kolesnikova, E. M., Journal of general chemistry of the USSR, 1983, vol. 53, p. 496 - 499

  摘要：

  DOI：
• 作为产物：
  描述：

  四氯化锗 在 氯乙烯 作用下， 以 neat (no solvent) 为溶剂， 以20%的产率得到trichlorovinylgermane
  参考文献：
  名称：

  Shcherbinin, V. V.; Shvedov, I. P.; Pavlov, K. V., Russian Journal of General Chemistry, 1993, vol. 63, p. 1336 - 1336

  摘要：

  DOI：

文献信息

• Reactions of diboron tetrahalides with some unsaturated organometallic compounds
  作者：T.D. Coyle、J.J. Ritter

  DOI：10.1016/s0022-328x(00)93848-8

  日期：1968.5

  Tetrachloro- and tetrafluorodiborane(4) add to the double bond in a number of vinyl derivatives of boron, carbon, silicon, germanium, and tin to form 1,2-bis(dihaloboryl)ethyl derivatives. Most of the compounds are stable in vacuo at temperatures in excess of 150°. Tetrachlorodiborane(4) undergoes addition considerably more readily than does tetrafluorodiborane(4). Relative rates of addition have been determined

  四氯和四氟二硼烷（4）在许多硼，碳，硅，锗和锡的乙烯基衍生物中加成双键，形成1,2-双（二卤硼基）乙基衍生物。大多数化合物在超过150°C的温度下在真空中稳定。与四氟二硼烷（4）相比，四氯二硼烷（4）的加成要容易得多。已经确定了相对的加成率，并且显示出其显着取决于乙烯基上取代基的性质。
• Monovinylgermasilsesquioxanes
  申请人：ADAM MICKIEWICZ UNIVERSITY

  公开号：US09249167B1

  公开（公告）日：2016-02-02

  A new cage monovinylgermasilsesquioxanes of the general formula 1, in which R1 are the same and represent a C1 to C6 alkyl group or a cyclopentyl or cyclohexyl group or a phenyl group. The invention also relates to the method of synthesis of cage monovinylgermasilsesquioxanes of the general formula 1.

  一种新的笼状单乙烯基硅氧烷，其通用公式为1，其中R1相同，表示C1到C6烷基、环戊基或环己基或苯基。本发明还涉及合成通用公式1的笼状单乙烯基硅氧烷的方法。
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.9, 5.2.8.3, page 226 - 229
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Fe: Org.Verb.B1, 1.1.4.3.1.2, page 133 - 135
  作者：

  DOI：——

  日期：——
• New Vinylgermanium Derivatives of Silsesquioxanes and Their Ruthenium Complexes—Synthesis, Structure, and Reactivity
  作者：Dawid Frąckowiak、Patrycja Żak、Grzegorz Spólnik、Mikołaj Pyziak、Bogdan Marciniec

  DOI：10.1021/acs.organomet.5b00142

  日期：2015.8.24

  New vinylgermanium cubic derivatives of silsesquioxanes (i.e., monovinylhepta(alkyl, phenyl)-germasilsesqiuoxanes and (dimethylvinylgermoxy)-heptaisobutylsilsesquioxanes) were synthesized and characterized by spectroscopic methods. The first ruthenium germasilsesquioxyl complexes were also prepared via stoichiometric reaction of RuHCl(CO)(PPh3)(3) with the above-mentioned vinylgermanium derivatives of silsesquioxanes, and their structures were determined by spectroscopic and X-ray analyses. The initial ruthenium complex as well as the above-mentioned Ge-Ru complexes were tested as catalysts, in the germylative coupling with olefins, and proved to be active in the case of (dimethylvinyl)-germoxyheptaisobutylsilsesquioxane but showed no activity toward vinylgermasilsesquioxanes. A general mechanism for the germylative coupling of the two vinylgermanium derivatives of silsesquioxanes is presented.