1,4-diisopropoxynaphthalene

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,4-diisopropoxynaphthalene
• 英文别名: 1,4-Di(propan-2-yloxy)naphthalene；1,4-di(propan-2-yloxy)naphthalene
• 化学式: C₁₆H₂₀O₂
• 分子量: 244.334
• InChiKey: ZZPGHNFYZUVXCF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,4-diisopropoxynaphthalene 在 氧气 、 tetraphenylporphyrin 作用下， 以 二氯甲烷-D2 为溶剂， 反应 0.5h， 生成 1,4-diisopropoxy-1,4-dihydro-1,4-epidioxidonaphthalene
  参考文献：
  名称：

  氧取代萘的光氧化

  摘要：

  已经研究了氧取代的萘与单线态氧（1 O 2）的反应，并且首次分离了不稳定的过氧化物，并在–78°C下进行了表征。紫外光谱的低温动力学表明，与1,4-二甲基萘相比，烷氧基和甲硅烷氧基取代基显着提高了光氧合速率，而酰氧基取代的并苯对1 O 2呈惰性。反应性与我们通过密度泛函理论计算确定的HOMO能量和自由活化能很好地相关。分离出的过氧化物的不稳定性是由于它们即使在–20°C下在释放1时也会与相应的萘发生非常快速的逆反应。O 2，使其在非常温和的条件下成为该反应物种的上等来源。最终，合成了碳水化合物取代的萘，该萘可与1 O 2可逆反应，并可能在未来的工作中用于对映选择性氧化。

  DOI：

  10.1002/poc.3734
• 作为产物：
  描述：

  1,4-二羟基萘 、 2-溴丙烷 在 potassium carbonate 作用下， 以 乙腈 为溶剂， 反应 6.0h， 以79%的产率得到1,4-diisopropoxynaphthalene
  参考文献：
  名称：

  氧取代萘的光氧化

  摘要：

  已经研究了氧取代的萘与单线态氧（1 O 2）的反应，并且首次分离了不稳定的过氧化物，并在–78°C下进行了表征。紫外光谱的低温动力学表明，与1,4-二甲基萘相比，烷氧基和甲硅烷氧基取代基显着提高了光氧合速率，而酰氧基取代的并苯对1 O 2呈惰性。反应性与我们通过密度泛函理论计算确定的HOMO能量和自由活化能很好地相关。分离出的过氧化物的不稳定性是由于它们即使在–20°C下在释放1时也会与相应的萘发生非常快速的逆反应。O 2，使其在非常温和的条件下成为该反应物种的上等来源。最终，合成了碳水化合物取代的萘，该萘可与1 O 2可逆反应，并可能在未来的工作中用于对映选择性氧化。

  DOI：

  10.1002/poc.3734

文献信息

• Phosphorus-containing polyphenylene oxide resin, its preparation method, method for preparing prepolymer of phosphorus-containing polyphenylene oxide, resin composition and its application
  申请人：Elite Material Co., Ltd.

  公开号：US10280260B2

  公开（公告）日：2019-05-07

  The present invention relates to a phosphorus-containing polyphenylene oxide resin, its preparation method, a method for preparing the prepolymer of the phosphorus-containing polyphenylene oxide, a resin composition and an article thereof, wherein the phosphorus-containing polyphenylene oxide resin has a chemical structure represented by the following formula (I): wherein R′ is R″ is R′″ is hydrogen, Through the use of the above phosphorus-containing polyphenylene oxide resin, an article made from the resin composition can has good flame retardance, good thermal resistance and a lower percent of thermal expansion while dielectric properties can be maintained, such that the present invention is suitable for use in products such as copper clad laminate and printed circuit board.

  本发明涉及一种含磷聚苯醚树脂、其制备方法、含磷聚苯醚预聚物的制备方法、树脂组合物及其制品，其中含磷聚苯醚树脂具有下式（I）所代表的化学结构： 其中 R′是 R″ 是 R′″ 是氢、 通过使用上述含磷聚苯氧化物树脂，由该树脂组合物制成的物品可以具有良好的阻燃性、良好的耐热性和较低的热膨胀率，同时还能保持介电性能，因此本发明适用于覆铜箔层压板和印刷电路板等产品。
• PHOSPHORUS-CONTAINING POLYPHENYLENE OXIDE RESIN, ITS PREPARATION METHOD, METHOD FOR PREPARING PREPOLYMER OF PHOSPHORUS-CONTAINING POLYPHENYLENE OXIDE, RESIN COMPOSITION AND ITS APPLICATION
  申请人：Elite Material Co., Ltd.

  公开号：US20170088669A1

  公开（公告）日：2017-03-30

  The present invention relates to a phosphorus-containing polyphenylene oxide resin, its preparation method, a method for preparing the prepolymer of the phosphorus-containing polyphenylene oxide, a resin composition and an article thereof, wherein the phosphorus-containing polyphenylene oxide resin has a chemical structure represented by the following formula (I): wherein R′ is R″ is R′″ is hydrogen, Through the use of the above phosphorus-containing polyphenylene oxide resin, an article made from the resin composition can has good flame retardance, good thermal resistance and a lower percent of thermal expansion while dielectric properties can be maintained, such that the present invention is suitable for use in products such as copper clad laminate and printed circuit board.
• ULTRAVIOLET CURABLE LIQUID COMPOSITION, ULTRAVIOLET CURING INKJET INK, ULTRAVIOLET CURING WET ELECTROPHOTOGRAPHIC LIQUID DEVELOPER, ULTRAVIOLET CURING ELECTROSTATIC INKJET INK, AND IMAGE FORMING METHOD USING THEREOF
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20170336728A1

  公开（公告）日：2017-11-23

  An object of the present invention is to provide an ultraviolet curing liquid composition having high sensitivity, excellent storage stability, low viscosity, and excellent fixability after ultraviolet curing. The ultraviolet curable liquid composition of the present invention is an ultraviolet curable liquid composition containing a cationically polymerizable liquid monomer, a photopolymerization initiator and a photopolymerization sensitizer, wherein the cationically polymerizable liquid monomer is a vinyl ether compound, the photopolymerization initiator includes a compound represented by general formula (1), and the photopolymerization sensitizer includes (A) at least one compound selected from the group consisting of a compound represented by general formula (2) and a compound represented by general formula (3), and (B) at least one compound selected from the group consisting of a compound represented by general formula (4) and a compound represented by general formula (5).
• RADICAL POLYMERIZATION CONTROL AGENT AND RADICAL POLYMERIZATION CONTROL METHOD
  申请人：Kawasaki Kasei Chemicals Ltd.

  公开号：US20210122692A1

  公开（公告）日：2021-04-29

  A conventional polymerization inhibitor is for example an agent to scavenge radicals generated during storage of a radical polymerizable compound and used to stably handle the radical polymerizable compound, but is unnecessary when the radical polymerizable compound is to be subjected to radical polymerization reaction, and is preferably removed at the time of the radical polymerization reaction. The object of the present invention is to obviate inconvenience of removing the polymerization inhibitor at the time of radical polymerization. The radical polymerization control agent contained in a radical polymerizable composition of the present invention functions as a radical polymerization inhibitor for example stored in a dark place, but loses its radical polymerization inhibiting effect when polymerization is initiated while being irradiated with light at a certain specific wavelength at the time of polymerization. Thus, radical polymerization of the radical polymerizable compound is easily initiated without increasing the amount of a radical polymerization initiator. That is, the radical polymerization control agent of the present invention is a radical polymerization control agent which is a corn pound having an effect to inhibit radical polymerization of a radical polymerizable compound and which loses the radical polymerization inhibiting effect under irradiation with light rays containing light within a wavelength range of from 300 nm to 500 nm.
• [EN] PHOTOCURABLE SILICONE RESIN COMPOSITION, SILICONE RESIN MOLDED BODY OBTAINED BY CURING SAME AND METHOD FOR MANUFACTURING SAID MOLDED BODY<br/>[FR] COMPOSITION DE RÉSINE DE SILICONE PHOTODURCISSABLE, CORPS MOULÉ EN RÉSINE DE SILICONE OBTENU PAR DURCISSEMENT DE CELLE-CI ET PROCÉDÉ DE FABRICATION DUDIT CORPS MOULÉ<br/>[JA] 光硬化性シリコーン樹脂組成物及びそれを硬化させたシリコーン樹脂成形体、並びに当該成形体の製造方法
  申请人：NIPPON STEEL CHEMICAL & MAT CO LTD

  公开号：WO2020162615A1

  公开（公告）日：2020-08-13

  シリコーン樹脂と不飽和化合物と光重合開始剤とを含む光硬化性シリコーン樹脂組成物を硬化させる際に生じる酸素阻害の影響を減少させ、低露光量でも、十分な耐擦傷性と着色の少ないシリコーン樹脂成形体を与えるような光硬化性シリコーン樹脂組成物を提供する。　シリコーン樹脂(A1)と、分子中に－Ｒ３－ＣＲ４＝ＣＨ２又は－ＣＲ４＝ＣＨ２で表される不飽和基を少なくとも１個含むと共に、前記シリコーン樹脂(A1)とラジカル共重合が可能な不飽和化合物(A2)とを、１：９９～９９：１の質量割合で配合したシリコーン樹脂組成物(A)と、0.01質量％溶液の光路長1cm、波長360nmの光透過率が90％未満である光重合開始剤（D）とを含み、上記A2は２０質量％以上が水酸基を含む不飽和化合物であり、前記シリコーン樹脂組成物(A)に対して上記Dが0.1質量%以上20質量%未満で配合される光硬化性シリコーン樹脂組成物およびその成形体である。