(3-丁烯基)三氯化锡 | 106162-53-2

• 分子结构分类: 有机化合物 - 有机金属化合物
• 中文名称: (3-丁烯基)三氯化锡
• 英文名称: 3-buten-1-yl tin trichloride
• 英文别名: But-3-enyl(trichloro)stannane
• CAS: 106162-53-2
• 化学式: C₄H₇Cl₃Sn
• 分子量: 280.169
• InChiKey: QHSWONGWTGVUBR-UHFFFAOYSA-K

物化性质

• 沸点：
  98 °C(Press: 3 Torr)

计算性质

• 辛醇/水分配系数(LogP)：
  3.22
• 重原子数：
  8.0
• 可旋转键数：
  3.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  (3-丁烯基)三氯化锡 在 甲基碘化镁 作用下， 以 四氢呋喃 为溶剂， 以92%的产率得到(3-butenyl)trimethylstannane
  参考文献：
  名称：

  Ryu, Ilhyong; Suzuki, Haruhisa; Mural, Shinji, Organometallics, 1987, vol. 6, # 1, p. 212 - 213

  摘要：

  DOI：
• 作为产物：
  描述：

  四氯化锡 、 Tetra(but-3-en-1-yl)zinn 在 四(三苯基膦)铂 作用下， 以 甲苯 为溶剂， 反应 14.0h， 以68.5%的产率得到(3-丁烯基)三氯化锡
  参考文献：
  名称：

  TW2021/10863

  摘要：

  公开号：

文献信息

• Synthesis and reactions of donor cyclopropanes: efficient routes to  cis - and trans -tetrahydrofurans
  作者：Jonathan Dunn、Adrian P. Dobbs

  DOI：10.1016/j.tet.2015.05.007

  日期：2015.9

  A detailed study on the synthesis and reactions of silylmethylcyclopropanes is reported. In their simplest form, these donor-only cyclopropanes undergo Lewis acid promoted reaction to give either cis- or trans-tetrahydrofurans, with the selectivity being reaction condition-dependant. The adducts themselves are demonstrated to be an important scaffold for structural diversification. The combination

  报道了对甲硅烷基甲基环丙烷的合成和反应的详细研究。这些仅供体的环丙烷以其最简单的形式进行路易斯酸促进的反应，以生成顺式或反式四氢呋喃，其选择性取决于反应条件。加合物本身被证明是结构多样化的重要支架。还讨论了供体-受体环丙烷中甲硅烷基供体基团与新型受体基团的组合。
• General Routes to Functional Organotin Trichlorides and Trialkoxides Involving the Tricyclohexylstannyl Group
  作者：Bernard Jousseaume、Mohammed Lahcini、Marie-Claude Rascle、Francois Ribot、Clement Sanchez

  DOI：10.1021/om00002a016

  日期：1995.2

  New functional organotin trialkoxides have been prepared in two steps from the corresponding organotricyclohexyltins, which were obtained by coupling an organometal species with tricyclohexyltin chloride, by reaction of (tricyclohexylstannyl)lithium with an organic halide, or by hydrostannation of alkenes. Treatment of organotricyclohexyltins with tin tetrachloride gave the corresponding organotin trichlorides which were further transformed into functional organotin trialkoxides.
• RYU ILHYONG; SUZUKI HARUHISA; MURAI SHINJI; SONODA NOBORU, ORGANOMETALLICS, 6,(1987) N 1, 212-213
  作者：RYU ILHYONG、 SUZUKI HARUHISA、 MURAI SHINJI、 SONODA NOBORU

  DOI：——

  日期：——
• HIGH PURITY TIN COMPOUNDS CONTAINING UNSATURATED SUBSTITUENT AND METHOD FOR PREPARATION THEREOF
  申请人：Gelest, Inc.

  公开号：US20240059717A1

  公开（公告）日：2024-02-22

  Monoorgano tin trialkoxide compounds having chemical formula R′Sn(OR) 3 and containing less than about 5 mol % diorgano tin dialkoxide are described. R′ is a linear or branched, optionally fluorinated, unsaturated hydrocarbon group having about 2 to about 20 carbon atoms and each R is independently a linear or branched, optionally fluorinated, alkyl group having about 1 to about 10 carbon atoms. Methods for synthesizing and purifying these compounds are also provided. The monoorgano tin compounds may be used for the formation of high-resolution EUV lithography patterning precursors and are attractive due to their high purity and minimal concentration of diorgano tin impurities.