1,3,5-tris{4-[1-naphthyl(phenyl)amino]phenyl}benzene | 197296-69-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,3,5-tris{4-[1-naphthyl(phenyl)amino]phenyl}benzene
• 英文别名: N-[4-[3,5-bis[4-(N-naphthalen-1-ylanilino)phenyl]phenyl]phenyl]-N-phenylnaphthalen-1-amine
• CAS: 197296-69-8
• 化学式: C₇₂H₅₁N₃
• 分子量: 958.217
• InChiKey: PNCDUADWZJWYTE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.3
• 重原子数：
  75
• 可旋转键数：
  12
• 环数：
  13.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N-苯基-1-萘胺 、 1,3,5-三(4-碘苯基)苯 在 氢氧化钾 、 1,10-菲罗啉 、 copper(l) chloride 作用下， 以 对二甲苯 为溶剂， 反应 1.0h， 以75.6%的产率得到1,3,5-tris{4-[1-naphthyl(phenyl)amino]phenyl}benzene
  参考文献：
  名称：

  Organic Light-Emitting Devices Consisting ofN-Triarylamine-Based Hole Injecting/Transporting Materials

  摘要：

  A series of N-triarylamine-based derivatives such as 4,4'-bis[N-(1-naphthyl)-N- phenyl-amino]biphenyl (alpha-NPD), 1,3,5-tris[4-(3-methylphenyl(phenyl)amino) phenyl]benzene (m-MTDAPB) and 1,3,5-tris-{4-[1-naphthyl(phenyl)amino]phenyl}-benzene (1-TNAPB) were synthesized and characterized. Specially, 1-TNAPB was synthesized with high yield in 1 hr. The hole injecting/transporting properties of these materials were investigated by using double-layered organic light-emitting diodes (OLEDs) with the configuration of ITO/N-triarylamine/Alq(3)/LiF/Al, in which Alq(3) was used as an emitting and electron transporting layer. A comparative study on EL performance of OLEDs fabricated with N-triarylamines as the hole injecting/transporting layer revealed that better results were observed in OLED with m-MTDAPB and alpha-NPD, respectively. OLED with m-MTDAPB (20nm thickness) showed maximum luminescence of 15,970 cd/m(2) at 10V and turn-on voltage of 4 V. On the other hand, alpha-NPD (50nm thickness) exhibited maximum luminescence of 17,650 cd/m(2) at 17V and turn-on voltage of 7 V.

  DOI：

  10.1080/15421400802619735

文献信息

• Organic electroluminescent device
  申请人：LG Display Co., Ltd.

  公开号：EP1603174B1

  公开（公告）日：2016-04-27
• ORGANIC EL DEVICE
  申请人：LG ELECTRONICS INC.

  公开号：EP1665896B1

  公开（公告）日：2007-10-24
• US7297417B2
  申请人：——

  公开号：US7297417B2

  公开（公告）日：2007-11-20
• US7485377B2
  申请人：——

  公开号：US7485377B2

  公开（公告）日：2009-02-03
• US7531247B2
  申请人：——

  公开号：US7531247B2

  公开（公告）日：2009-05-12