propanedioate;quinoline;zirconium(4+);peroxide | 187455-21-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯并吡啶类
• 英文名称: propanedioate;quinoline;zirconium(4+);peroxide
• CAS: 187455-21-6
• 化学式: C₂₁H₁₆N₂O₆Zr
• 分子量: 483.592
• InChiKey: QLOIYLULEUGQSZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  potassium iodide 、 propanedioate;quinoline;zirconium(4+);peroxide 以 水 为溶剂， 生成 氢碘酸
  参考文献：
  名称：

  Preparation and Reactivity of some Peroxo Complexes of Zirconium (IV) and Uranium (VI)

  摘要：

  New peroxo complexes of zirconium(IV) and uranium(IV) with dibasic acids and nitrogen containing heterocyclic bases have been prepared. The general compositions of the complexes are [M(O-2)(DB)(L)(2)] and [M'O(O-2)(DB)(L)(2)], where M, M' are Zr(IV) or U(VI), DB = dianion of homophthalic acid or malonic acid and L = quinoline (Q) or isoquinoline (IQ). These complexes were characterized on the basis of elemental analyses, conductivity measurements, magnetic measurements, TLC, GLC, infrared spectral studies and by reactions with allyl alcohol, triphenylphosphine and triphenylarsine. The zirconium complexes were found to be octahedral, whereas the uranium complexes were seven-coordinated.

  DOI：

  10.1080/00945719708000178
• 作为产物：
  描述：

  双氧水 、 zirconium(IV) nitrate pentahydrate 、 丙二酸 、 喹啉 以 乙醇 、 水 为溶剂， 以72%的产率得到propanedioate;quinoline;zirconium(4+);peroxide
  参考文献：
  名称：

  Preparation and Reactivity of some Peroxo Complexes of Zirconium (IV) and Uranium (VI)

  摘要：

  New peroxo complexes of zirconium(IV) and uranium(IV) with dibasic acids and nitrogen containing heterocyclic bases have been prepared. The general compositions of the complexes are [M(O-2)(DB)(L)(2)] and [M'O(O-2)(DB)(L)(2)], where M, M' are Zr(IV) or U(VI), DB = dianion of homophthalic acid or malonic acid and L = quinoline (Q) or isoquinoline (IQ). These complexes were characterized on the basis of elemental analyses, conductivity measurements, magnetic measurements, TLC, GLC, infrared spectral studies and by reactions with allyl alcohol, triphenylphosphine and triphenylarsine. The zirconium complexes were found to be octahedral, whereas the uranium complexes were seven-coordinated.

  DOI：

  10.1080/00945719708000178