{Pb(CH3CO2)2(th)} | 15633-11-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代酰胺
• 英文名称: {Pb(CH3CO2)2(th)}
• 英文别名: thiourea; compound with lead (II)-acetate；Thioharnstoff; Verbindung mit Blei(II)-acetat
• CAS: 15633-11-1
• 化学式: CH₄N₂S*2C₂H₃O₂*Pb
• 分子量: 401.411
• InChiKey: POKRXGUQUIGAGM-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.44
• 重原子数：
  9.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  92.17
• 氢给体数：
  2.0
• 氢受体数：
  3.0

反应信息

• 作为产物：
  描述：

  lead acetate 、 硫脲 以 水 为溶剂， 生成 {Pb(CH3CO2)2(th)}
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Pb: MVol.C4, 229, page 1726 - 1728

  摘要：

  DOI：

文献信息

• Nardelli, M.; Chierici, I., Ricerca Scientifica, 1959, vol. 29, p. 1731 - 1732
  作者：Nardelli, M.、Chierici, I.

  DOI：——

  日期：——
• Synthesis, optical and dielectric studies on novel semi organic nonlinear optical crystal by solution growth technique
  作者：V. Chithambaram、S. Jerome Das、S. Krishnan

  DOI：10.1016/j.jallcom.2011.01.091

  日期：2011.3

  Bisthiourea lead acetate Pb[SC(NH2)(2)](2)(CH3COO)(2)), a novel semi organic non linear optical crystal having dimensions 17 mm x 2 mm x 2 mm were grown using slow evaporation technique. The lattice parameters for the grown crystals were determined using single crystal XRD. The presence of functional groups for the grown crystals was confirmed using Fourier transform infrared (FT-IR) spectroscopy. The optical absorption studies show that the material has wide optical transparency in the entire visible region. The dielectric constant and dielectric loss has been studied as a function of frequency for various temperatures and the results were discussed in detail. The second harmonic generation was confirmed by Kurtz powder method and it is found to be 5 times than that of potassium dihydrogen phosphate (KDP) crystal. (c) 2011 Elsevier B.V. All rights reserved.