5,15-di(phenyl)-10-(bromo)-20-(4-benzonitrile)porphyrin zinc(II) | 1398574-28-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 5,15-di(phenyl)-10-(bromo)-20-(4-benzonitrile)porphyrin zinc(II)
• CAS: 1398574-28-1
• 化学式: C₃₉H₂₂BrN₅Zn
• 分子量: 705.931
• InChiKey: OFZLPSFFEBOQHC-SYJFUPKCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  5,15-di(phenyl)-10-(bromo)-20-(4-benzonitrile)porphyrin zinc(II) 在 palladium diacetate 、 sodium hydride 、 二异丁基氢化铝 、 双(2-二苯基磷苯基)醚 作用下， 以 四氢呋喃 、 二氯甲烷 、 甲苯 为溶剂， 反应 26.0h， 生成
  参考文献：
  名称：

  Novel D–π–A structured porphyrin dyes containing various diarylamino moieties for dye-sensitized solar cells

  摘要：

  A series of novel zinc porphyrins which are featured with a donor-pi-acceptor structure have been synthesized for use in the dye-sensitized solar cells. Various diarylamine moiety, such as diphenylamine, iminodibenzyl or iminostilbene, is introduced at porphyrin mesa position as an electron donating group. The cell fabricated with the iminodibenzyl-substituted porphyrin sensitizer yields a short circuit photocurrent density of 9.68 mA/cm(2), an open-circuit voltage of 740 mV, and a fill factor of 73.48%, corresponding to an overall conversion efficiency (eta) up to 5.26%, which is greater than those obtained by diphenylamine- and iminostilbene-substituted porphyrin-sensitized solar cells (eta = 4.05% and 2.62%, respectively). The theoretical studies reveal that the iminodibenzyl donor has the strongest electron donating ability among all three diarylamine substituents employed, which is believed to play a significant role in influencing the photovoltaic properties of these sensitizer-based solar cells. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2014.12.006
• 作为产物：
  描述：

  4-(di-1H-pyrrol-2-ylmethyl)benzonitrile 在 N-溴代丁二酰亚胺(NBS) 、 三氟化硼乙醚 、 zinc diacetate 作用下， 以 四氢呋喃 、 氯仿 为溶剂， 反应 38.0h， 生成 5,15-di(phenyl)-10-(bromo)-20-(4-benzonitrile)porphyrin zinc(II)
  参考文献：
  名称：

  Novel D–π–A structured Zn(ii)-porphyrin dyes containing a bis(3,3-dimethylfluorenyl)amine moiety for dye-sensitised solar cells

  摘要：

  在 100 mW cmâ2 AM 1.5 G 的模拟光照下，含有多功能共吸附剂的 2FluâZnPâCNâCOOH 染料的短路电流（Jsc）为 15.30 mA cmâ2 ，开路电压（Voc）为 669 mV，填充因子（FF）为 0.71，实现了 7.22% 的高太阳能发电转换效率。

  DOI：

  10.1039/c2cc31384g

文献信息

• 포르피린계 유도체, 이를 포함하는 염료감응 태양전지용 유기염료 및 이를 포함하는 염료감응 태양전지
  申请人：Korea University Research and Business Foundation 고려대학교 산학협력단(220040170680) BRN ▼209-82-08298

  公开号：KR101499476B1

  公开（公告）日：2015-03-06

  본 발명은 화학식 1, 화학식 2, 화학식 3, 화학식 4 또는 화학식 7로 표시되는 포르피린계 유도체, 상기 유도체를 포함하는 염료감응 태양전지용 유기염료 및 상기 유기염료를 포함하는 태양전지에 관한 것이다.

  本发明涉及一种以化学式1、化学式2、化学式3、化学式4或化学式7表示的卟啉类衍生物，包括该衍生物的染料敏化太阳能电池有机染料和包含该有机染料的太阳能电池。
• Novel D–π–A structured Zn(ii)–porphyrin dyes with bulky fluorenyl substituted electron donor moieties for dye-sensitized solar cells
  作者：Min Soo Kang、In Taek Choi、Yeon Wook Kim、Ban Seok You、Sung Ho Kang、Ji Yeoun Hong、Myung Jong Ju、Hwan Kyu Kim

  DOI：10.1039/c3ta11818e

  日期：——

  Two kinds of push–pull structured (D–π–A) Zn(II)–porphyrin dyes with bulky fluorenyl substituted electron donor moieties were designed and synthesized for use as sensitizers in dye-sensitized solar cells (DSSCs). A high solar-to-electricity conversion efficiency of 8.46% was achieved with a short circuit current (Jsc) of 15.39 mA cm−2, an open circuit voltage (Voc) of 0.74 V and a fill factor (FF) of 0.74 for the 2,4-ZnP-CN-COOH dye with HC-A1, which is a multi-functional co-adsorbent previously developed by our group, under 100 mW cm−2 AM 1.5 G simulated light.

  设计并合成了两种具有大量芴基取代的电子供体部分的推拉结构（D-α-A）Zn(II)-卟啉染料，用作染料敏化太阳能电池中的敏化剂。 DSSC）。太阳能-电能转换效率高达 8.46%，短路电流 (Jsc) 为 15.39 mA cm-2，开路电压 (Voc) 为 0.74 V，填充因子 (FF) 为 0.74 2,4-ZnP-CN-COOH染料与HC-A1，这是我们小组先前开发的多功能共吸附剂，在100 mW cm-2 AM 1.5 G模拟光下。