1,1'-(naphthalene-2,7-diylbis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine) | 863650-32-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,1'-(naphthalene-2,7-diylbis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine)
• CAS: 863650-32-2
• 化学式: C₂₆H₄₆N₄O₂P₂
• 分子量: 508.624
• InChiKey: GMVWIXMWUXPALR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.42
• 重原子数：
  34.0
• 可旋转键数：
  16.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  31.42
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  1,1'-(naphthalene-2,7-diylbis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine) 在 sulfur 作用下， 以 乙腈 为溶剂， 反应 1.5h， 生成 O,O-naphthalene-2,7-diyl bis(tetraethyldiamidophosphorothioate)
  参考文献：
  名称：

  摘要：

  1,5- and 2,7-dihydroxynaphthalenes were reacted with P(III) amides to obtain naphthocyclophanes. The structures and chemical properties of the products were studied.

  DOI：

  10.1023/a:1012378817167
• 作为产物：
  描述：

  2,7-二羟基萘 、 六乙基亚磷酸胺 以 乙腈 为溶剂， 反应 0.33h， 生成 1,1'-(naphthalene-2,7-diylbis(oxy))bis(N,N,N',N'-tetraethylphosphanediamine)
  参考文献：
  名称：

  Phosphomacrocyclic systems based on 2,2′-dihydroxy-1,1′-dinaphtylmethane

  摘要：

  For the first time phosphomacrocyclic systems were synthesized based on 2,2'-dihydroxy-1,1'-dinaphthylmethane, other aromatic diols, and phosphorous hexaethyltriamide. Spontaneous transformation of the obtained macrocycles into the more stable 1,3,2-dioxaphosphacyn and cyclobisamidophosphite was established.

  DOI：

  10.1134/s1070363210050099

文献信息

• Phosphorylation of 1,4-bis(hydroxymethyl)benzene with trivalent phosphorus derivatives
  作者：P. V. Slitikov、V. A. Bogoyavlenskii、E. N. Rasadkina、E. E. Nifant’ev

  DOI：10.1134/s1070363207060126

  日期：2007.6

  Phosphorylation of 1,4-bis(hydroxymethyl)benzene with complete phosphorous acid amides and phenyl phosphorodichloridite is studied. Some phosphorus-containing linear systems, the phosphamacrocycle precursors, are synthesized. The possibility of synthesis of phosphamacrocyclic systems based on 1,4-bis(hydroxymethyl)benzene is considered; it was shown that this compound does not tend to form macrocycles.
• Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use
  作者：E. N. Rasadkina、P. V. Slitikov、E. E. Nifant’ev

  DOI：10.1134/s1070363206020046

  日期：2006.2

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.
• Macrocyclic Systems on the Basis of Phosphorus Acids and 2,7-Dihydroxynaphthalene
  作者：E. N. Rasadkina、P. V. Slitikov、Yu. B. Evdokimenkova、E. E. Nifant'ev

  DOI：10.1023/b:rugc.0000007643.79978.ad

  日期：2003.8

  Syntheses of macrocyclic systems containing three 2,7-dihydroxynaphthalene residues and three residues of thiophosphoric and phosphorous amides in various ratios are developed. Chemical properties of the obtained compounds are studied.
• Phosphorylation of aminomethylated derivatives of 2,7-dihydroxynaphthalenes
  作者：P. V. Slitikov、E. N. Rasadkina

  DOI：10.1134/s1070363216030099

  日期：2016.3

  Phosphorylation of 2,7-dihydroxynaphthalene derivatives, containing different amine components was performed by full amides of phosphorous acid. A substantial effect of the intramolecular hydrogen bond on the process of phosphorylation was shown. Cyclophosphorylation was performed and principal possibility of the synthesis of naphthophosphacrownaphanes having aminomethyl linkers was shown. Mannich aminomethylation of naphthophosphacyclophanes was found to be impossible.