(+/-)-3,8,13-tris(salicylaldimino)-2,7,12-trihydroxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene | 319431-17-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: (+/-)-3,8,13-tris(salicylaldimino)-2,7,12-trihydroxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene
• 英文别名: 6,13,20-Tris[(2-hydroxyphenyl)methylideneamino]tetracyclo[15.4.0.03,8.010,15]henicosa-1(21),3,5,7,10,12,14,17,19-nonaene-5,12,19-triol
• CAS: 319431-17-9
• 化学式: C₄₂H₃₃N₃O₆
• 分子量: 675.741
• InChiKey: DEIMTDLEVJTRQF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  51
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  159
• 氢给体数：
  6
• 氢受体数：
  9

反应信息

• 作为反应物：
  描述：

  N-丁基咪唑 、 (+/-)-3,8,13-tris(salicylaldimino)-2,7,12-trihydroxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene 、 nickel diacetate 以 甲醇 为溶剂， 以77%的产率得到(+/-)-3,8,13-tris(salicylaldiminato(nickel(II)(1-n-butylimidazole)))-2,7,12-trimethoxy-10,15-dihydro-5H-tribenzo[a,d,g]cyclononene
  参考文献：
  名称：

  Salicylaldiminato Derivatives of Cyclotriveratrylene:  Flexible Strategy for New Rim-Metalated CTV Complexes

  摘要：

  The amino-derivatized cyclotriveratrylene analogue, triaminotrimethoxytribenzocyclononene [CTV(NH2)(3)(OMe)(3)], 1, is readily converted into triply substituted imine compounds [CTV(sal)(3)(OMe)(3)], 2, in high yield by treatment of the acid salt of 1 with a variety of substituted salicylaldehydes. Cleavage of the protecting methoxy group generates the tristridentate chelate CTV(sal)(3)(OH)(3), 3, which is readily converted into new rim-metalated species CTV(sal)(3)(ONiL)(3), 4a (a, L = pyrrolidine; b, L = 1-n-butyl-imidazole). Taken together, these results illustrate the remarkable synthetic flexibility that is possible for the CTV-based metal complexes by alteration of the metal, the salicylaldehyde component of the CTV ligand, or the ancillary ligands coordinated to the metal.

  DOI：

  10.1021/ic0005240