(Z)-sinapaldehyde | 205534-54-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: (Z)-sinapaldehyde
• 英文别名: sinapaldehyde；2-Propenal, 3-(4-hydroxy-3,5-dimethoxyphenyl), (Z)-；(Z)-3-(4-hydroxy-3,5-dimethoxyphenyl)prop-2-enal
• CAS: 205534-54-9
• 化学式: C₁₁H₁₂O₄
• 分子量: 208.214
• InChiKey: CDICDSOGTRCHMG-ARJAWSKDSA-N

物化性质

• 沸点：
  372.3±37.0 °C(Predicted)
• 密度：
  1.195±0.06 g/cm3(Predicted)
• 保留指数：
  1856;1851.4

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  55.8
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  catechin hydrate 、 (Z)-sinapaldehyde 以 乙醇 为溶剂， 生成 syringylcatechinpyrylium
  参考文献：
  名称：

  Synthesis of a new catechin-pyrylium derived pigment

  摘要：

  A new catechin-pyrylium derived pigment compound was synthesised from the reaction of catechin with sinapaldehyde in acidic conditions and its structure has been characterised by UV-vis, MS and NMR spectroscopy. Similar compounds could be expected to be formed in wines and contribute to changes in colour and astringency during ageing. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.10.132

文献信息

• Synthesis of a new catechin-pyrylium derived pigment
  作者：Victor de Freitas、Carlos Sousa、Artur M.S. Silva、Celestino Santos-Buelga、Nuno Mateus

  DOI：10.1016/j.tetlet.2004.10.132

  日期：2004.12

  A new catechin-pyrylium derived pigment compound was synthesised from the reaction of catechin with sinapaldehyde in acidic conditions and its structure has been characterised by UV-vis, MS and NMR spectroscopy. Similar compounds could be expected to be formed in wines and contribute to changes in colour and astringency during ageing. (C) 2004 Elsevier Ltd. All rights reserved.