3-(5-Chloro-2-oxobenzothiazolin-3-yl)propyl Diethylthionocarbamate | 124480-33-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻唑类
• 英文名称: 3-(5-Chloro-2-oxobenzothiazolin-3-yl)propyl Diethylthionocarbamate
• 英文别名: O-[3-(5-chloro-2-oxo-1,3-benzothiazol-3-yl)propyl] N,N-diethylcarbamothioate
• CAS: 124480-33-7
• 化学式: C₁₅H₁₉ClN₂O₂S₂
• 分子量: 358.913
• InChiKey: XCOHPPPBUMPQAO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  22
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  90.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  5-氯-2-苯骈噻唑酮 、 3-chloropropyl diethylthionocarbamate 在 氢氧化钾 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 24.0h， 以81%的产率得到3-(5-Chloro-2-oxobenzothiazolin-3-yl)propyl Diethylthionocarbamate
  参考文献：
  名称：

  D'Amico, John J.; Bollinger, Frederic G., Journal of Heterocyclic Chemistry, 1989, vol. 26, p. 655 - 660

  摘要：

  DOI：

文献信息

• N-Substituted oxobenzothiazoline and oxobenzoxazoline derivatives and
  申请人：Monsanto Company

  公开号：US04227915A1

  公开（公告）日：1980-10-14

  The present invention relates to compounds of the formula ##STR1## wherein X, Y and W represent independently oxygen or sulfur; T represents lower alkyl, lower alkoxy, halo, CF.sub.3 or NO.sub.2 ; m is an integer of from 0 to 2; n is an integer of from 1 to 3; and R is selected from the group consisting of ##STR2## morpholino, pyrrolidyl, pyrrolidyl substituted by from 1 to 2 lower alkyl or lower alkoxy moieties and ##STR3## where a is an integer of from 5 to 8 inclusive; R.sub.1 represents lower alkyl, lower alkenyl, benzyl, phenyl or phenyl substituted by from 1 to 3 lower alkyl, lower alkoxy, lower alkenyl, CF.sub.3 or NO.sub.2 moieties; R.sub.2 represents hydrogen, lower alkyl or lower alkenyl moieties, with the proviso that when X is oxygen, R.sub.1 and R.sub.2 cannot equal methyl. The invention also relates to the use of said compounds in a method of regulating leguminous plant growth as well as to plant growth regulant compositions.

  本发明涉及以下式的化合物 ##STR1## 其中X、Y和W分别表示氧或硫；T表示低碳基、低碳氧基、卤素、CF.sub.3或NO.sub.2；m为0到2的整数；n为1到3的整数；R选自以下组合物 ##STR2## 吗啡啉、吡咯烷基、被1至2个低碳基或低碳氧基基团取代的吡咯烷基和 ##STR3## 其中a为5到8的整数；R.sub.1表示低碳基、低烯烃基、苄基、苯基或被1至3个低碳基、低碳氧基、低烯烃基、CF.sub.3或NO.sub.2基团取代的苯基；R.sub.2表示氢、低碳基或低烯烃基，但当X为氧时，R.sub.1和R.sub.2不能等于甲基。本发明还涉及所述化合物在调节豆科植物生长方法中的使用，以及植物生长调节剂组合物。
• Novel N-substituted 2-oxo-3-benzothiazoline derivatives, their use as leguminous plant growth regulants, and plant growth regulating compositions containing said derivatives as the active ingredients
  申请人：MONSANTO COMPANY

  公开号：EP0007161A1

  公开（公告）日：1980-01-23

  The present invention relates to compounds of the formula wherein Y and W represent independently oxygen or sulfur; T represents lower alkyl, lower alkoxy, halo, CF, or NO2; m is an integer of from 0 to 2; n is an integer of from 1 to 3; and R is selected from the group consisting of morpholino, pyrrolidyl, pyrrolidyl substituted by from 1 to 2 lower alkyl or lower alkoxy moieties and -N(CH2)a, where a is an integer of from 5 to 8 inclusive; R, represents lower alkyl, lower alkenyl, benzyl, phenyl or phenyl substituted by from 1 to 3 lower alkyl, lower alkoxy, lower alkenyl, CF3 \or NO, moieties; R2 represents hydrogen, lower alkyl or loweralkenyl moieties. Examples are given for the preparation of said compounds. The invention also relates to the use of said compounds in a method of regulating leguminous plant growth as well as to plant growth regulant compositions.

  本发明涉及式如下的化合物 其中 Y 和 W 独立地代表氧或硫； T 代表低级烷基、低级烷氧基、卤代物、CF 或 NO2； m 是 0 到 2 的整数； n 是 1 至 3 的整数；以及 R 选自以下组成的组 吗啉基、吡咯烷基、被 1 至 2 个低级烷基或低级烷氧基取代的吡咯烷基和 -N(CH2)a，其中 a 是 5 至 8 的整数； R，代表被 1 至 3 个低级烷基、低级烷氧基、低级烯基、CF3 或 NO 取代的低级烷基、低级烯基、苄基、苯基或苯基； R2 代表氢、低级烷基或低级烯基。举例说明了上述化合物的制备方法。本发明还涉及上述化合物在豆科植物生长调节方法中的用途以及植物生长调节剂组合物。
• US4227915A
  申请人：——

  公开号：US4227915A

  公开（公告）日：1980-10-14
• D'Amico, John J.; Bollinger, Frederic G., Journal of Heterocyclic Chemistry, 1989, vol. 26, p. 655 - 660
  作者：D'Amico, John J.、Bollinger, Frederic G.

  DOI：——

  日期：——