2,2,3,3,3-pentafluoropropyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate | 893556-35-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: 2,2,3,3,3-pentafluoropropyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate
• 英文别名: 2,2,3,3,3-pentafluoropropylnonafluorobutane sulfonate；2,2,3,3,3-Pentafluoropropyl nonafluorobutanesulfonate
• CAS: 893556-35-9
• 化学式: C₇H₂F₁₄O₃S
• 分子量: 432.135
• InChiKey: RHOYTZWDGJGCCO-UHFFFAOYSA-N

物化性质

• 沸点：
  186.8±40.0 °C(Predicted)
• 密度：
  1.742±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  51.8
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为反应物：
  描述：

  2,2,3,3,3-pentafluoropropyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate 在 lithium bromide 作用下， 以 二乙二醇二甲醚 为溶剂， 反应 48.0h， 生成 3-溴-1,1,1,2,2-五氟丙烷
  参考文献：
  名称：

  [EN] HYDROFLUOROOLEFINS AND METHODS OF USING SAME
  [FR] HYDROFLUOROOLÉFINES ET LEURS PROCÉDÉS D'UTILISATION

  摘要：

  公开号：

  WO2020128964A3
• 作为产物：
  描述：

  全氟丁基磺酰氟 在 sodium hydride 作用下， 以 乙醚 为溶剂， 反应 3.25h， 生成 2,2,3,3,3-pentafluoropropyl 1,1,2,2,3,3,4,4,4-nonafluorobutane-1-sulfonate
  参考文献：
  名称：

  WO2006/64218

  摘要：

  公开号：

文献信息

• [EN] HYDROFLUORETHERS AND METHODS OF USING SAME<br/>[FR] HYDROFLUORÉTHERS ET LEURS PROCÉDÉS D'UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2021144678A1

  公开（公告）日：2021-07-22

  A compound having structural formula (II): where R2 is H, CH3, CF3, CH2CF2CF2H, or CH2CF2CF2CF2CF2H; where R2f is a perfluoroalkyl group having 1-4 carbon atoms, optionally comprising either or both of a catenated nitrogen heteroatom and a catenated oxygen heteroatom; where R2f' is CF3 or CF2CF3; and where R2f" is CF3 or CF2CF3; with the proviso that when R2f' is CF3, then R2f" is CF3, and when R2 is H or CH3, then R2f is not CF3.

  具有结构式（II）的化合物：其中R2为H、CH3、CF3、CH2CF2CF2H或CH2CF2CF2CF2CF2H；其中R2f为具有1-4个碳原子的全氟烷基基团，可选地包括串联的氮杂原子和/或串联的氧杂原子中的任一种或两种；其中R2f'为CF3或CF2CF3；其中R2f"为CF3或CF2CF3；但是当R2f'为CF3时，R2f"为CF3，当R2为H或CH3时，R2f不是CF3。
• PYRAZOLE-3-CARBOXYLIC ACID AMIDE DERIVATIVE AND PEST CONTROL AGENT
  申请人：KUMIAI CHEMICAL INDUSTRY CO., LTD.

  公开号：US20200199096A1

  公开（公告）日：2020-06-25

  Embodiments provide a harmful organism control agent containing a pyrazole-3-carboxylic acid amide derivative or a salt thereof as an active ingredient, having an excellent harmful organism controlling effect. A pyrazole-3-carboxylic acid amide derivative represented by general formula [I]: (wherein, R 1 , R 2 , R 3 , R 4 , and R 5 represent a hydrogen atom, halogen atom, C 1 -C 6 alkyl group or the like, R 6 represents a C 1 -C 12 alkyl group, C 1 -C 12 haloalkyl group or the like, R 7 and R 8 represent a hydrogen atom, C 1 -C 12 alkyl group or the like) or an agriculturally acceptable salt thereof, and a harmful organism control agent containing the pyrazole-3-carboxylic acid amide derivative or an agriculturally acceptable salt thereof as an active ingredient.

  实施例提供了一种含有吡唑-3-羧酸酰胺衍生物或其盐作为活性成分的有害生物控制剂，具有出色的有害生物控制效果。一种由通式[I]表示的吡唑-3-羧酸酰胺衍生物：（其中，R1、R2、R3、R4和R5代表氢原子、卤原子、C1-C6烷基或类似物，R6代表C1-C12烷基、C1-C12卤代烷基或类似物，R7和R8代表氢原子、C1-C12烷基或类似物）或其农业可接受的盐，以及一种含有吡唑-3-羧酸酰胺衍生物或其农业可接受的盐作为活性成分的有害生物控制剂。
• Preparation of (perfluoroalkyl)alkane thiols via Zemplén deacylation of fluorous (perfluoroalkyl)alkyl thioacetates
  作者：Bálint Menczinger、Anikó Nemes、Csongor Szíjjártó、József Rábai

  DOI：10.1016/j.jfluchem.2018.02.014

  日期：2018.6

  Convenient and robust synthesis of (perfluoroalkyl)alkane thiols [(CnF2n+1(CH2)mSH); m/n = 3/4,6,8,10, 4a-d; m/n = 2/6, 8; m/n = 1/1,2,3,7,8H, 12a-e] was developed starting from commercially available fluorous alcohols (1a-d, 5, 9a-e). The intermediate (perfluoroalkyl)alkyl iodides and/or sulfonates were reacted with potassium thioacetate in DMF, and the resulting thioacetates were deacetylated by

  （全氟烷基）烷硫醇[（C n F 2n + 1（CH 2）m SH）; 米/ Ñ  = 3 / 4,6,8,10，4A - d ; m / n  = 2/ 6，8 ; M / N  = 1 / 1,2,3,7,8H，12A - ë ]被开发由市售氟醇（起始1A - d，5，图9a - ë）。使中间体（全氟烷基）烷基碘化物和/或磺酸盐与硫代乙酸钾在DMF中反应，然后通过Zemplén类似反应使所得的硫代乙酸酯脱乙酰。以良好的总收率和高纯度获得了（全氟烷基）链烷硫醇。
• Hydantoin Derivatives Useful as Metalloproteinase Inhibitors
  申请人：Waterson David

  公开号：US20080280950A1

  公开（公告）日：2008-11-13

  Formula (I) wherein R 1 is a (2-4C)alkyl and is substituted by two or more fluorine groups and R 2 is methyl or ethyl, or a pharmaceutically acceptable salt thereof; processes for their preparation, pharmaceutical compositions containing them and their use in the treatment of diseases or medical conditions mediated by metalloproteinase enzymes.

  公式(I)中，R1是(2-4C)烷基，被两个或更多氟基取代，而R2是甲基或乙基，或其药学上可接受的盐；其制备方法，含有它们的制药组合物以及它们在治疗由金属蛋白酶酶介导的疾病或医疗状况中的应用。
• 3-ALKOXY-1-PHENYLPYRAZOLE DERIVATIVES AND PESTICIDES
  申请人：Ohata Satoru

  公开号：US20100210704A1

  公开（公告）日：2010-08-19

  To provide pesticides such as insecticides, miticides and nematicides, which are excellent in the safety, pesticidal effects, residual effectiveness, etc., which further have infiltration, and which can be applied by soil treatment. A pesticide comprising a 3-alkoxy-1-phenyl-pyrazole derivative represented by the formula [I] or an agriculturally acceptable salt thereof as an active ingredient: wherein, for example, R 1 is a C 1 -C 10 alkyl group or the like, R 2 is a hydrogen atom or the like, R 3 is a hydrogen atom or the like, and each of R 4 , R 5 , R 6 and R 8 which are independent of one another, is a hydrogen atom or the like, and R 7 is a C 2 -C 4 haloalkylthio group or the like.

  提供杀虫剂，如杀虫剂，杀螨剂和杀线虫剂，这些杀虫剂在安全性、杀虫效果、残留效果等方面都非常出色，而且具有渗透性，可以通过土壤处理应用的杀虫剂。该杀虫剂包括以下公式[I]所表示的3-烷氧基-1-苯基-吡唑烷衍生物或其农业上可接受的盐作为活性成分：其中，例如，R1是C1-C10烷基或类似物，R2是氢原子或类似物，R3是氢原子或类似物，而且独立于彼此的R4、R5、R6和R8是氢原子或类似物，而R7是C2-C4卤代烷基硫基或类似物。