4-methacryloyloxy-1-(1-heptoxy)-2,2,6,6-tetramethylpiperidine | 869812-04-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 哌啶类
• 英文名称: 4-methacryloyloxy-1-(1-heptoxy)-2,2,6,6-tetramethylpiperidine
• 英文别名: (1-Heptoxy-2,2,6,6-tetramethylpiperidin-4-yl) 2-methylprop-2-enoate；(1-heptoxy-2,2,6,6-tetramethylpiperidin-4-yl) 2-methylprop-2-enoate
• CAS: 869812-04-4
• 化学式: C₂₀H₃₇NO₃
• 分子量: 339.519
• InChiKey: ZMMPYPWOKPLQAX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  24
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.85
• 拓扑面积：
  38.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1-碘庚烷 在 吡啶 、 4-二甲氨基吡啶 、 三正丁基氢锡 作用下， 以 苯 为溶剂， 反应 27.0h， 生成 4-methacryloyloxy-1-(1-heptoxy)-2,2,6,6-tetramethylpiperidine
  参考文献：
  名称：

  Strategies for the Generation of Molecularly Imprinted Polymeric Nitroxide Catalysts

  摘要：

  [GRAPHICS]Two strategies for preparing catalytically active molecularly imprinted nitroxide-containing polymers are outlined. Both strategies rely upon the thermal rearrangement chemistry of tertiary amine N-oxides. To this end, several polymers were prepared and the polymeric nitroxides were revealed by oxidation with m-CPBA. All of the resulting polymeric catalysts proved to be competent mediators of the oxidation of alcohols.

  DOI：

  10.1021/ol051749n

文献信息

• Strategies for the Generation of Molecularly Imprinted Polymeric Nitroxide Catalysts
  作者：Christopher D. Anderson、Kenneth J. Shea、Scott D. Rychnovsky

  DOI：10.1021/ol051749n

  日期：2005.10.1

  [GRAPHICS]Two strategies for preparing catalytically active molecularly imprinted nitroxide-containing polymers are outlined. Both strategies rely upon the thermal rearrangement chemistry of tertiary amine N-oxides. To this end, several polymers were prepared and the polymeric nitroxides were revealed by oxidation with m-CPBA. All of the resulting polymeric catalysts proved to be competent mediators of the oxidation of alcohols.