2,2,3,3,5,5,6,6-octafluoro-4-(perfluoroprop-1-en-1-yl)morpholine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2,2,3,3,5,5,6,6-octafluoro-4-(perfluoroprop-1-en-1-yl)morpholine
• 英文别名: 2,2,3,3,5,5,6,6-octafluoro-4-(1,2,3,3,3-pentafluoroprop-1-enyl)morpholine
• 化学式: C₇F₁₃NO
• 分子量: 361.062
• InChiKey: HWINZWCWLOVBIS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  22
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  15

反应信息

• 作为反应物：
  描述：

  2,2,3,3,5,5,6,6-octafluoro-4-(perfluoroprop-1-en-1-yl)morpholine 在 sodium tetrahydroborate 作用下， 以 二乙二醇二甲醚 为溶剂， 反应 4.25h， 生成 2,2,3,3,5,5,6,6-octafluoro-4-(1,3,3,3-tetrafluoroprop-1-enyl)morpholine
  参考文献：
  名称：

  TW2017/14879

  摘要：

  公开号：
• 作为产物：
  描述：

  2-[difluoro-(2,2,3,3, 5,5,6,6-octafluoromorpholin-4-yl)methyl]-2,3,3,3-tetrafluoro-propanoyl fluoride 在 potassium carbonate 作用下， 以345 g的产率得到2,2,3,3,5,5,6,6-octafluoro-4-(perfluoroprop-1-en-1-yl)morpholine
  参考文献：
  名称：

  HYDROFLUOROETHER OLEFINS AND METHODS OF USING SAME

  摘要：

  由以下一般式（I）表示的氢氟醚化合物。

  公开号：

  US20170198186A1

文献信息

• [EN] AMINE-CONTAINING CYCLIC HYDROFLUOROETHERS AND METHODS OF USING THE SAME<br/>[FR] HYDROFLUOROÉTHERS CYCLIQUES CONTENANT UNE AMINE ET LEURS PROCÉDÉS D'UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2017155735A1

  公开（公告）日：2017-09-14

  Described herein is a cyclic fluorinated compound of formula (I) where: L is O, CH2, or a covalent bond; X is selected from F or CF3, and Y is selected from H, F, or CF3, wherein when X is CF3 then Y is F and when Y is CF3 then X is F„ each Rf1 is independently selected from a linear or branched perfluorinated alkyl group comprising 1-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof; or the two Rf1 groups are bonded together to form a fluorinated ring structure comprising 4-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof; the -CFZ-CHAQ group is bonded to a ring carbon that is alpha to at least one O atom of the ring; A is selected from F, or CF3; Z is selected from H, F, or CF3; and Q is selected from (i) a F atom, (ii) a Cl atom, (iii) a linear, cyclic, or branched perfluorinated alkyl group comprising 1-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof, or (iv) a G(Rf2)e group, where G is an O atom or a N atom wherein: when Q is a Cl atom, then Z and A are F atoms; when G is O then e is 1, Z is H, F, or CF3; A is F; and Rf2 is a linear or branched perfluorinated alkyl group comprising 1-10 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof; when G is N then e is 2, and each Rf2 group is independently a linear or branched perfluorinated alkyl group comprising 1-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof or the two Rf2 groups are bonded together to form a fluorinated ring structure comprising 4-8 carbon atoms and optionally comprising at least one catenated atom selected from O, N, or combinations thereof, with the proviso that when A is CF3 then Z is F, and when Z is CF3 then A is F.

  本文描述的是一个循环氟化合物，其化学式为(I)，其中：L为O、CH2或共价键；X从F或CF3中选择，Y从H、F或CF3中选择，当X为CF3时，Y为F，当Y为CF3时，X为F；每个Rf1独立地选择自由1-8个碳原子的线性或支链全氟烷基基团，并且可选地包含至少一个由O、N或其组合选择的连结原子；或两个Rf1基团结合在一起形成含有4-8个碳原子并且可选地包含至少一个由O、N或其组合选择的连结原子的氟化环结构；-CFZ-CHAQ基团与环的至少一个O原子的α位碳原子结合；A从F或CF3中选择；Z从H、F或CF3中选择；Q从(i)F原子、(ii)Cl原子、(iii)线性、环状或支链全氟烷基基团，包括1-8个碳原子，并且可选地包含至少一个由O、N或其组合选择的连结原子，或(iv)G(Rf2)e基团中选择，其中G为O原子或N原子，当Q为Cl原子时，Z和A为F原子；当G为O时，e为1，Z为H、F或CF3，A为F，Rf2为包括1-10个碳原子的线性或支链全氟烷基基团，并且可选地包含至少一个由O、N或其组合选择的连结原子；当G为N时，e为2，每个Rf2基团独立地选择自由1-8个碳原子的线性或支链全氟烷基基团，并且可选地包含至少一个由O、N或其组合选择的连结原子，或两个Rf2基团结合在一起形成含有4-8个碳原子并且可选地包含至少一个由O、N或其组合选择的连结原子的氟化环结构，但A为CF3时，Z为F，Z为CF3时，A为F。
• [EN] ALLYLIC TERMINALLY UNSATURATED HYDROFLUOROAMINE AND ALLYLIC TERMINALLY UNSATURATED HYDROFLUOROETHER COMPOUNDS AND METHODS OF USING THE SAME<br/>[FR] HYDROFLUOROAMINE À INSATURATION TERMINALE ALLYLIQUE ET COMPOSÉS DE TYPE HYDROFLUOROÉTHER À INSATURATION TERMINALE ALLYLIQUE ET PROCÉDÉS POUR LEUR UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2017095732A1

  公开（公告）日：2017-06-08

  Described herein is an unsaturated fluorinated compound of formula (I) where X is O or N; Y is F or H; Z is F or CF3; and A is F or CF3 wherein when X is O, then n is 1, Y is H, Z is F, A is F, and Rf is a linear or branched perfluorinated alkyl group comprising 1 to 10 carbon atoms and optionally comprising at least one catenated O or N; and when X is N, then n is 2 and each Rf group are (i) independently selected from a linear or branched perfluorinated alkyl group comprising 1 to 8 carbon atoms and optionally comprising at least one catenated O or N; or (ii) bonded together to form a ring structure comprising 4 to 8 carbon atoms and optionally comprising at least one catenated O or N with the proviso that when Z is CF3 then A is F and when A is CF3 then Z is F and methods of making and using the same.

  本文描述了一种不饱和氟化合物，其化学式为（I），其中X为O或N；Y为F或H；Z为F或CF3；A为F或CF3，其中当X为O时，n为1，Y为H，Z为F，A为F，Rf为包含1到10个碳原子的线性或支链全氟烷基基团，可选地包含至少一个连续的O或N；当X为N时，n为2，每个Rf基团（i）独立地选择自由包含1到8个碳原子的线性或支链全氟烷基基团，可选地包含至少一个连续的O或N；或（ii）结合在一起形成包含4到8个碳原子的环结构，可选地包含至少一个连续的O或N，但当Z为CF3时，A为F，当A为CF3时，Z为F，以及制备和使用这种化合物的方法。
• 작동 유체로서의 플루오르화 올레핀 및 이의 사용 방법
  申请人：3M INNOVATIVE PROPERTIES COMPANY 쓰리엠 이노베이티브 프로퍼티즈 컴파니(520010417718)

  公开号：KR20160101131A

  公开（公告）日：2016-08-24

  하기 일반 화학식 I로 표시되는 플루오르화 올레핀 화합물을 포함하는 작동 유체: [화학식 I]. 일부 실시 형태에서, 열 전달을 위한 장치가 제공된다. 본 장치는 디바이스, 및 디바이스로 또는 디바이스로부터 열을 전달하기 위한 메커니즘을 포함한다. 일부 실시 형태에서, 소화 조성물이 제공된다. 일부 실시 형태에서, 랭킨 사이클에서 열 에너지를 기계 에너지로 전환하기 위한 장치가 제공된다.

  这段文字描述了一种包含氟代烯烃化合物的工作流体，其化学式为[I]。在某些实施形式中，提供了用于热传递的装置。该装置包括设备和用于从设备或向设备传递热量的机制。在某些实施形式中，提供了灭火组分。在某些实施形式中，提供了用于将热能从朗肯循环转化为机械能的装置。
• TW2017/14880
  申请人：——

  公开号：——

  公开（公告）日：——
• [EN] NITROGEN AND DIOXOLANE-CONTAINING HYDROFLUOROETHERS AND METHODS OF USING THE SAME<br/>[FR] HYDROFLUOROÉTHERS CONTENANT DE L'AZOTE ET DU DIOXOLANE ET LEURS PROCÉDÉS D'UTILISATION
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2018044613A1

  公开（公告）日：2018-03-08

  Described herein is dioxolane-containing compound of formula (I): wherein (i) Rf1 and Rf2 are independently linear or branched perfluoroalkyi groups having with 1-8 carbon atoms and optionally comprise at least one catenated heteroatom, or (ii) Rf1 and Rf2 are bonded together to form a ring structure having 4-6 carbon atoms and optionally comprise one or more catenated heteroatoms; Rf2 is a linear or branched perfluoroalkyi groups having with 1 -3 carbon atoms; and R4 and R5 are independently selected from H, F, CI, a linear or branched alkyl group having 1 -3 carbon atoms, optionally wherein the alkyl group comprises at least one of: fluorine, chlorine, a hydroxyl group, or a catenated heteroatom; for use in cleaning compositions, as an electrolyte solvent, as a heat transfer fluid, or a vapor phase soldering fluid. There is also provided a method of making the dioxolane-containing compound, comprising: contacting a 1,2-diol compound with a fluorinated ethylenically unsaturated compound in the presence of a base.