dimethyl 2,5-bis[bis(4-tert-butylphenyl)amino]terephthalate | 1314743-34-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: dimethyl 2,5-bis[bis(4-tert-butylphenyl)amino]terephthalate
• 英文别名: dimethyl 2,5-bis[di(4-tert-butylphenyl)amino]terephthalate；dimethyl 2,5-bis(4-tert-butyl-N-(4-tert-butylphenyl)anilino)benzene-1,4-dicarboxylate
• CAS: 1314743-34-4
• 化学式: C₅₀H₆₀N₂O₄
• 分子量: 753.037
• InChiKey: VMPDEAKNABHXGR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.8
• 重原子数：
  56
• 可旋转键数：
  14
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  59.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  4-叔丁基苯胺 在 铜 、 potassium carbonate 、 溶剂黄146 作用下， 以 乙醇 为溶剂， 反应 56.0h， 生成 dimethyl 2,5-bis[bis(4-tert-butylphenyl)amino]terephthalate
  参考文献：
  名称：

  Twisting strategy applied to N,N-diorganoquinacridones leads to organic chromophores exhibiting efficient solid-state fluorescence

  摘要：

  A new molecular design of organic emitters exhibiting efficient solid-state fluorescence, which involves planarity breaking of N,N-diorganoquinacridones, is presented. The new design principle led to the development of dimethyl 2,5-diaminoterephthalates and 2,5-diamino-1,4-diaroylbenzenes, which emitted green to yellow and yellow to red light with high-to-excellent quantum yields, respectively. In addition, the photoluminescence properties of the diaroylbenzenes were dependent on the morphology and reversibly variable by thermal and solvent vapor stimuli. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.05.087

文献信息

• Twisting strategy applied to N,N-diorganoquinacridones leads to organic chromophores exhibiting efficient solid-state fluorescence
  作者：Masaki Shimizu、Yuiga Asai、Youhei Takeda、Akinori Yamatani、Tamejiro Hiyama

  DOI：10.1016/j.tetlet.2011.05.087

  日期：2011.8

  A new molecular design of organic emitters exhibiting efficient solid-state fluorescence, which involves planarity breaking of N,N-diorganoquinacridones, is presented. The new design principle led to the development of dimethyl 2,5-diaminoterephthalates and 2,5-diamino-1,4-diaroylbenzenes, which emitted green to yellow and yellow to red light with high-to-excellent quantum yields, respectively. In addition, the photoluminescence properties of the diaroylbenzenes were dependent on the morphology and reversibly variable by thermal and solvent vapor stimuli. (C) 2011 Elsevier Ltd. All rights reserved.