di-n-butyldi-thien-2-yltin | 54663-77-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属芳基
• 英文名称: di-n-butyldi-thien-2-yltin
• CAS: 54663-77-3
• 化学式: C₁₆H₂₄S₂Sn
• 分子量: 399.209
• InChiKey: XPPYCCWFFQZBLY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.96
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  56.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-溴噻吩 、 二丁基二氯化锡 在 magnesium 作用下， 以 not given 为溶剂， 生成 di-n-butyldi-thien-2-yltin
  参考文献：
  名称：

  A novel mode of access to polyfunctional organotin compounds and their reactivity in Stille cross-coupling reaction

  摘要：

  Mono-, di-, tri- and tetra-functional organotin compounds were easily prepared in a sonicated Barbier reaction using ultrasound technology via coupling reaction of organo halides with tin halides (Bu3SnCl, Bu2SnCl2, BuSnCl3, SnCl4) mediated by magnesium metal. The di- and tri- functional organotin compounds were tested in a Stille cross-coupling reaction in order to ascertain how many groups were transferred. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.03.030

文献信息

• A novel mode of access to polyfunctional organotin compounds and their reactivity in Stille cross-coupling reaction
  作者：Sandrine Lamandé-Langle、Mohamed Abarbri、Jérôme Thibonnet、Alain Duchêne

  DOI：10.1016/j.jorganchem.2009.03.030

  日期：2009.7

  Mono-, di-, tri- and tetra-functional organotin compounds were easily prepared in a sonicated Barbier reaction using ultrasound technology via coupling reaction of organo halides with tin halides (Bu3SnCl, Bu2SnCl2, BuSnCl3, SnCl4) mediated by magnesium metal. The di- and tri- functional organotin compounds were tested in a Stille cross-coupling reaction in order to ascertain how many groups were transferred. (C) 2009 Elsevier B.V. All rights reserved.