1,3-bis(2-hydroxybenzyl)-2-(2-hydroxynaphthalen-1-yl)imidazolidine | 312946-44-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,3-bis(2-hydroxybenzyl)-2-(2-hydroxynaphthalen-1-yl)imidazolidine
• 英文别名: 1-[1,3-Bis[(2-hydroxyphenyl)methyl]imidazolidin-2-yl]naphthalen-2-ol
• CAS: 312946-44-4
• 化学式: C₂₇H₂₆N₂O₃
• 分子量: 426.515
• InChiKey: ZWSYTWUZDWRHIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  32
• 可旋转键数：
  5
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  67.2
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  N,N-双(2-羟基苯)乙烯二胺 、 2-羟基-1-萘甲醛 在 对甲苯磺酸 作用下， 以 正丁醇 为溶剂， 反应 0.67h， 以84%的产率得到1,3-bis(2-hydroxybenzyl)-2-(2-hydroxynaphthalen-1-yl)imidazolidine
  参考文献：
  名称：

  Fluorescent sensors based on 2-substituted imidazolidines

  摘要：

  A number of 2-substituted imidazolidines were synthesized from N, N'-dibenzylethane-1,2-diamine derivatives and benzaldehyde, naphthalene-1-carbaldehyde, 2-hydroxynaphthalene-1-carbaldehyde, and anthracene-9-carbaldehyde. Examination of the obtained compounds by spectral methods revealed selective sensor properties of 2-(anthracen-9-yl)-1,3-dibenzylimidazolidine and 2-(anthracen-9-yl)-1,3-bis(2-hydroxybenzyl)-imidazolidine for Hg2+ and Cu2+ ions.

  DOI：

  10.1134/s1070428010080129

文献信息

• Fluorescent sensors based on 2-substituted imidazolidines
  作者：I. E. Tolpygin、E. N. Shepelenko、Yu. V. Revinskii、A. V. Tsukanov、A. D. Dubonosov、V. A. Bren’、V. I. Minkin

  DOI：10.1134/s1070428010080129

  日期：2010.8

  A number of 2-substituted imidazolidines were synthesized from N, N'-dibenzylethane-1,2-diamine derivatives and benzaldehyde, naphthalene-1-carbaldehyde, 2-hydroxynaphthalene-1-carbaldehyde, and anthracene-9-carbaldehyde. Examination of the obtained compounds by spectral methods revealed selective sensor properties of 2-(anthracen-9-yl)-1,3-dibenzylimidazolidine and 2-(anthracen-9-yl)-1,3-bis(2-hydroxybenzyl)-imidazolidine for Hg2+ and Cu2+ ions.