tetraheptylammonium | 35414-25-6

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tetraheptylammonium
• 英文别名: Tetra-n-heptylammonium；Tetra-n-heptylammonium-Ion；Tetraheptylammonium-Kation；tetraheptylazanium
• CAS: 35414-25-6
• 化学式: C₂₈H₆₀N
• 分子量: 410.791
• InChiKey: YFZDLRVCXDBOPH-UHFFFAOYSA-N

物化性质

• 碰撞截面：
  236.4 Ų [M]+ [CCS Type: DT, Method: stepped-field]

计算性质

• 辛醇/水分配系数(LogP)：
  11.8
• 重原子数：
  29
• 可旋转键数：
  24
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 海关编码：
  2923900090

反应信息

• 作为反应物：
  描述：

  tetraheptylammonium 、 hexabromo-osmate(IV) 以 氢溴酸 、 苯 为溶剂， 生成
  参考文献：
  名称：

  Kelly, D. A.; Good, M. L., Spectrochimica Acta, Part A: Molecular and Biomolecular Spectroscopy, 1977, vol. 28, p. 1529 - 1536

  摘要：

  DOI：

文献信息

• Silanol Compound, Composition, and Method for Producing Silanol Compound
  申请人：NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY

  公开号：US20170183363A1

  公开（公告）日：2017-06-29

  The purpose of the present invention is to provide silanol compounds that can be used as raw materials of siloxane compounds and the like, and a composition of the silanol compounds, as well as to provide a production method that makes it possible to produce silanol compounds at excellent yield. A composition comprising 5 mass % to 100 mass % of a silanol compound represented by Formulas (A) to (C) can be prepared by devising to produce silanol compounds under water-free conditions, to produce silanol compounds in a solvent having the effect of suppressing the condensation of silanol compounds, and to perform other such processes, the composition being able to be used as a raw material or the like of siloxane compounds because the silanol compounds can be stably present in the resulting composition.

  本发明的目的是提供可用作硅氧烷化合物等原料的硅醇化合物，以及硅醇化合物的组合物，并提供一种能够以优异产率生产硅醇化合物的生产方法。通过设计在无水条件下生产硅醇化合物，使用具有抑制硅醇化合物缩合作用的溶剂生产硅醇化合物，并执行其他类似过程，可以制备包含按照(A)至(C)式表示的硅醇化合物质量百分含量为5%至100%的组合物。由于硅醇化合物可以稳定存在于所得组合物中，因此该组合物可用作硅氧烷化合物等的原料。
• [EN] PREPARATION OF SUBSTITUTED 3-ARYL-5-TRIFLUOROMETHYL-1,2,4-OXADIAZOLES<br/>[FR] PRÉPARATION DE 3-ARYL-5-TRIFLUOROMÉTHYL-1,2,4-OXADIAZOLES SUBSTITUÉS
  申请人：BASF SE

  公开号：WO2019020501A1

  公开（公告）日：2019-01-31

  The present invention relates to a process for the preparation of 3-aryl-5-trifluoromethyl-1,2,4- oxadiazoles, which are useful as fungicidal compounds or as intermediates for the synthesis of fungicidal oxaciazole compounds, using trifluoroacetyl halides.

  本发明涉及一种制备3-芳基-5-三氟甲基-1,2,4-恶二唑的方法，这些恶二唑作为杀真菌化合物或作为合成杀真菌恶二唑化合物的中间体是有用的，使用三氟乙酰卤化物。
• Process for producing allyl halide compound
  申请人：——

  公开号：US20020107422A1

  公开（公告）日：2002-08-08

  There are disclosed a composition comprising (E)-1,4-dibromo-2-methyl-2-butene and (Z)-1,4-dibromo-2-methyl-2-butene, wherein the ratio of the E isomer to the total amount of the E and Z isomers is 0.9 or more; a process for producing the same and a process using the same to produce an allyl halide compound of formula (1): 1 wherein X denotes a bromine atom, Y denotes an ArS(O) 2 group or an RCOO group, wherein Ar denotes an aryl group which may be substituted and R denotes a hydrogen atom, a lower alkyl group or an aryl group which may be substituted, and the wavy line means that the derivative is a mixture of an E or Z geometrical isomer.

  本发明涉及一种包含(E)-1,4-二溴-2-甲基-2-丁烯和(Z)-1,4-二溴-2-甲基-2-丁烯的组合物，其中E异构体与E和Z异构体的总量之比为0.9或更高；一种生产该组合物的方法以及使用该组合物生产化合物的方法，所述化合物的分子式为（1）：其中X代表溴原子，Y代表ArS(O)2基团或RCOO基团，其中Ar代表可能被取代的芳基，R代表氢原子、低碳烷基或可能被取代的芳基，波浪线表示衍生物是E或Z几何异构体的混合物。
• ONIUM SALT, LIQUID COMPOSITION CONTAINING SAID ONIUM SALT AND CELLULOSE, AND CELLULOSE RECOVERY METHOD
  申请人：KOEI CHEMICAL COMPANY, LIMITED

  公开号：US20160009669A1

  公开（公告）日：2016-01-14

  The invention relates to an onium salt, a liquid composition containing the onium salt and cellulose, and a method for recovering cellulose. The invention makes it possible to provide an onium salt having an extremely high ability to dissolve cellulose at temperatures of 100° C. or lower. It also makes it possible to provide a liquid composition containing this onium salt and cellulose, as a composition suitable for the recovery of cellulose, and a method for recovering cellulose efficiently by using such a liquid composition containing the onium salt and cellulose.

  该发明涉及一种含有onium盐和纤维素的液体组合物以及一种恢复纤维素的方法。该发明使得能够在100°C或更低温度下提供具有极高溶解纤维素能力的onium盐成为可能。它还使得能够提供一种含有该onium盐和纤维素的液体组合物，作为适用于纤维素恢复的组合物，并通过使用含有onium盐和纤维素的这种液体组合物高效地恢复纤维素的方法成为可能。
• SULFONYLIMIDE SALT AND METHOD FOR PRODUCING THE SAME
  申请人：Okumura Yasunori

  公开号：US20110034716A1

  公开（公告）日：2011-02-10

  The present invention provides a method for producing fluorosulfonylimides more safely, rapidly and efficiently, which enables suppression of production of by-products, and fluorosulfonylimides. The method for producing a fluorosulfonylimide salt of the present invention includes a step of reacting a fluoride compound containing at least one element selected from the group consisting of elements of Group 11 to Group 15 and Period 4 to Period 6 (excluding arsenic and antimony) with a compound represented by the following general formula (I) to give a fluorosulfonylimide salt represented by the general formula (II): wherein R 1 denotes at least one element selected from the group consisting of elements of Group 11 to Group 15 and Period 4 to Period 6 (excluding arsenic and antimony); R 3 denotes fluorine, chlorine or a fluorinated alkyl group having 1 to 6 carbon atoms; R 4 denotes fluorine or a fluorinated alkyl group having 1 to 6 carbon atoms; and m denotes an integer of 2 or 3.

  本发明提供了一种更安全、更快速、更高效地生产氟磺酰亚胺的方法，该方法能够抑制副产物的生成，并得到氟磺酰亚胺。本发明的一种生产氟磺酰亚胺盐的方法包括以下步骤：将含有来自第11至第15族元素和第4至第6周期元素（不包括砷和锑）中至少一种元素的氟化物化合物与以下通式（I）所代表的化合物发生反应，得到以下通式（II）所代表的氟磺酰亚胺盐：其中R1代表来自第11至第15族元素和第4至第6周期元素（不包括砷和锑）中至少一种元素；R3代表氟、氯或具有1至6个碳原子的氟化烷基基团；R4代表氟或具有1至6个碳原子的氟化烷基基团；m代表2或3的整数。

表征谱图