bicyclo[2.2.1]hept-5-ene-2-(α-methyl)-acetonitrile | 859719-06-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bicyclo[2.2.1]hept-5-ene-2-(α-methyl)-acetonitrile
• 英文别名: 2-{Bicyclo[2.2.1]hept-5-en-2-yl}propanenitrile；2-(2-bicyclo[2.2.1]hept-5-enyl)propanenitrile
• CAS: 859719-06-5
• 化学式: C₁₀H₁₃N
• 分子量: 147.22
• InChiKey: AMMXZNJWOHAIPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.3
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  bicyclo[2.2.1]hept-5-ene-2-(α-methyl)-acetonitrile 、 氢氰酸 在 C₆₀H₆₄O₆P₂ 、 bis(1,5-cyclooctadiene)nickel (0) zinc(II) chloride 作用下， 以 甲苯 、 乙腈 为溶剂， 反应 16.0h， 以70%的产率得到5-(1-Cyanoethyl)bicyclo[2.2.1]heptane-2-carbonitrile
  参考文献：
  名称：

  Norbornane based cycloaliphatic compounds containing nitrile groups

  摘要：

  这项发明涉及新颖的去甲杂环戊烷腈衍生物，以及利用氢氰化反应制备它们的相应方法。

  公开号：

  US20050159614A1

文献信息

• NORBORNANE BASED CYCLOALIPHATIC COMPOUNDS CONTAINING NITRILE GROUPS
  申请人：INVISTA NORTH AMERICA S.A R.L.

  公开号：EP1706374A2

  公开（公告）日：2006-10-04
• Polar group-containing olefin copolymer, process for preparing the same, thermoplastic resin composition containing the copolymer, and uses thereof
  申请人：Imuta Junichi

  公开号：US20090137757A1

  公开（公告）日：2009-05-28

  A polar group-containing olefin copolymer having excellent adhesion properties to metals or polar resins and excellent compatibility therewith, a process for preparing the copolymer, a thermoplastic resin composition containing the copolymer, and uses thereof. The polar group-containing olefin copolymer comprises a constituent unit derived from an □-olefin of 2 to 20 carbon atoms, and a constituent unit derived from a straight-chain, branched or cyclic polar group-containing monomer having at the end a polar group such as a hydroxyl group or an epoxy group and/or a constituent unit derived from a macromonomer having at the end a polymer segment obtained by anionic polymerization, ring-opening polymerization or polycondensation. The polar group-containing olefin copolymer can be prepared by polymerizing the α-olefin with the polar group-containing monomer and/or the macromonomer in the presence of a metallocene catalyst. The polar group-containing olefin copolymer and the thermoplastic resin composition containing the copolymer are used for films, sheets, modifiers, building/civil engineering materials, automobile exterior trim, electric/electronic parts, coating bases, compatibilizing agents, etc.
• METHOD FOR PURIFYING POLYMER AND POLYMER
  申请人：Sunaga Tadahiro

  公开号：US20120208976A1

  公开（公告）日：2012-08-16

  Disclosed is a method for purifying a polymer in which a solution containing a cyclic olefin polymer having at least a repeating structural unit [A] represented by the general formula (1) and a metal component is brought into contact with an organic compound having a basic functional group and an acidic functional group, and then the resulting solution is brought into contact with a basic adsorbent to remove the metal component contained in the solution.
• US7393907B2
  申请人：——

  公开号：US7393907B2

  公开（公告）日：2008-07-01
• US7714087B2
  申请人：——

  公开号：US7714087B2

  公开（公告）日：2010-05-11