3-(heptyloxy)propanenitrile | 14144-76-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3-(heptyloxy)propanenitrile
• 英文别名: β-Heptyloxy-propionitril；3-Heptyloxy-propionsaeurenitril；β-Heptyloxypropionitril；β-n-Heptoxypropionitril；β-Heptoxy-propionitril；3-Heptyloxy-propionitril；3-heptoxypropanenitrile
• CAS: 14144-76-4
• 化学式: C₁₀H₁₉NO
• 分子量: 169.267
• InChiKey: NFUAZZQTQSWMCE-UHFFFAOYSA-N

物化性质

• 沸点：
  107.5-108 °C(Press: 5 Torr)
• 密度：
  0.8801 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  12
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  33
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  甲醇 、 3-(heptyloxy)propanenitrile 在 acid 作用下， 生成 methyl 3-(heptyloxy)propanoate
  参考文献：
  名称：

  Omega-hydrofluoroalkyl ethers, precursor carboxylic acids and derivatives thereof, and their preparation and application

  摘要：

  通常是液体的ω-氢氟烷基醚化合物（及其选定的混合物）具有由一个或多个醚氧原子中断的饱和全氟脂肪链的碳原子。这些化合物可以通过相应的氟烷基醚羧酸的脱羧反应制备，例如在清洁和干燥应用中很有用。

  公开号：

  EP1170275A3
• 作为产物：
  描述：

  正庚醇 以92%的产率得到
  参考文献：
  名称：

  SUN, XIAOYUN;PENG, GUICHUN, XUASYUEH TUNBAO,(1990) N, S. 48-49

  摘要：

  DOI：

文献信息

• Free-solvent Michael addition of glycerol to acrylic compounds
  作者：Frédéric Nadeau、Michèle Sindt、Nicolas Oget

  DOI：10.1039/c5nj02223a

  日期：——

  Functionalization of biobased glycerol by acrylic compounds was optimized and the tricyanoethylglycerol can be used as a prochiral core of dendrimers.

  生物基甘油通过丙烯酸类化合物的官能化被优化，三氰乙基甘油可以作为树状聚合物的前手手性核心。
• Photocatalyzed [2 + 2 + 2]-Cycloaddition of Nitriles with Acetylene:  An Effective Method for the Synthesis of 2-Pyridines under Mild Conditions
  作者：Barbara Heller、Bernd Sundermann、Helmut Buschmann、Hans-Joachim Drexler、Jingsong You、Ulrike Holzgrabe、Eberhard Heller、Günther Oehme

  DOI：10.1021/jo011032n

  日期：2002.6.1

  The photocatalyzed [2 + 2 + 2]-cycloaddition of nitriles with 2 equiv of acetylene to 2-pyridines can be carried out under mild conditions and represents a valuable extension to common synthetical methods. For the ideal wavelength range (350-500 nm), lamps as well as sunlight can be used. Working at room temperature and in organic solvents such as toluene or hexane as well as in water gives satisfying results in many cases. However, it is also possible to vary the solvent and the reaction temperature of the photocatalyzed synthesis and to choose, with respect to the specific substrate, specific requirements for this particular reaction and general requirements of the method. This simple and selective method derives its potential mainly from the large variety of applicable nitriles. Suitable substrates include (functionalized) aliphatic and aromatic nitriles as well as cyanamides derived from secondary amines.
• SUN, XIAOYUN;PENG, GUICUN, INYUN XUASYUEH, 7,(1990) N, S. 88-90
  作者：SUN, XIAOYUN、PENG, GUICUN

  DOI：——

  日期：——
• SUN, XIAOYUN;PENG, GUICHUN, XUASYUEH TUNBAO,(1990) N, S. 48-49
  作者：SUN, XIAOYUN、PENG, GUICHUN

  DOI：——

  日期：——
• MOVSUMZADE, EH. M.;KULIEVA, D. A.;MAMEDOV, M. G.;NASIROV, YA. F., IZV. VUZOV. XIMIYA I XIM. TEXNOL., 1985, 28, N 4, 12-16
  作者：MOVSUMZADE, EH. M.、KULIEVA, D. A.、MAMEDOV, M. G.、NASIROV, YA. F.

  DOI：——

  日期：——