Bis-(3,4-epoxy-cyclohexyl)-sulfon | 3775-87-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: Bis-(3,4-epoxy-cyclohexyl)-sulfon
• 英文别名: di(3,4-epoxycyclohexyl)sulfone；3-(7-Oxabicyclo[4.1.0]heptan-3-ylsulfonyl)-7-oxabicyclo[4.1.0]heptane
• CAS: 3775-87-9
• 化学式: C₁₂H₁₈O₄S
• 分子量: 258.339
• InChiKey: XMNMEKWSKPXZPK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  67.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  di(3,4-cyclohexenyl)-sulfone 在 过氧乙酸 作用下， 以 乙酸乙酯 为溶剂， 反应 6.0h， 生成 Bis-(3,4-epoxy-cyclohexyl)-sulfon
  参考文献：
  名称：

  EP1726588

  摘要：

  公开号：

文献信息

• Polymerizable Actinic Radiation Curable Composition, Polymerization Method, Actinic Radiation Curable Ink and Image Formation Method, and Ink Jet Recording Apparatus and Epoxy Compound
  申请人：Sasa Nobumasa

  公开号：US20080107821A1

  公开（公告）日：2008-05-08

  A polymerizable actinic radiation curable composition comprising a photo-acid generating compound and an epoxy compound represented by Formula (1): wherein X represents a divalent group selected form the group consisting of —O—, —S—, —SO—, —SO 2 —, —CBr 2 —, —C(CBr 3 ) 2 —, and —C(CF 3 ) 2 —; R 1 to R 18 each independently represent a hydrogen atom, a halogen atom, a hydrocarbon group having 1-8 carbon atoms, provided that the hydrocarbon group may contain an oxygen atom or a halogen atom, or a substituted or unsubstituted alkoxy group having 1-8 carbon atoms.

  一种可聚合光致酸固化组合物，包括一种光酸发生化合物和一种由式（1）表示的环氧化合物：其中X代表从羟基、硫基、磺酸基、磺酸酯基、溴代基、三溴甲基代基和三氟甲基代基中选择的二价基团；R1至R18各自独立地表示氢原子、卤素原子、具有1-8个碳原子的碳氢基团，其中碳氢基团可能含有氧原子或卤素原子，或具有1-8个碳原子的取代或未取代的烷氧基团。
• PROCESS FOR PRODUCING EPOXY COMPOUND, EPOXY RESIN COMPOSITION AND USE THEREOF, ULTRAVIOLET-CURABLE CAN COATING COMPOSITION, AND PROCESS FOR PRODUCING COATED METAL CAN
  申请人：DAICEL CHEMICAL INDUSTRIES, Ltd.

  公开号：EP1389615A1

  公开（公告）日：2004-02-18

  The invention I provides a method of producing an alicyclic epoxy compound having a specific structure, which comprises epoxidizing an alicyclic olefin compound having a specific structure by using an aliphatic percarboxylic acid having low water content. The alicyclic epoxy compound is useful for use in coatings, inks, adhesives, sealants, encapsulants, stabilizers or the like. The invention II provides an epoxy resin composition containing the alicyclic epoxy compound as a main component, and a photosemiconductor device comprising a photosemiconductor element encapsulated with the epoxy resin composition. The epoxy resin composition can be cured by heating, thereby obtaining a cured product having excellent moisture and heat resistance and transparency. The invention III provides: an ultraviolet rays-curable can-coating composition containing the alicyclic epoxy compound as a main component, which can be cured by ultraviolet irradiation, and can form a coating film having excellent film performances such as processability, adhesion, hardness and scratch resistance, particularly film appearance and retort resistance; and a process of producing a coated metal can using the composition.

  本发明一提供了一种生产具有特定结构的脂环族环氧化合物的方法，该方法包括使用含水量低的脂肪族过羧酸对具有特定结构的脂环族烯烃化合物进行环氧化。脂环族环氧化合物可用于涂料、油墨、粘合剂、密封剂、封装剂、稳定剂等。 本发明二提供了一种含有脂环族环氧化合物作为主要成分的环氧树脂组合物，以及一种光电半导体器件，该器件包括用环氧树脂组合物封装的光电半导体元件。环氧树脂组合物可以通过加热固化，从而获得具有优异的耐湿性、耐热性和透明度的固化产品。 本发明III提供了：一种紫外线固化罐涂层组合物，该组合物以脂环族环氧化合物为主要成分，可通过紫外线照射固化，并可形成具有优异涂膜性能（如加工性、附着力、硬度和抗划伤性）的涂膜，特别是涂膜外观和耐蒸煮性；以及一种使用该组合物生产涂层金属罐的工艺。
• Process for producing epoxy compound, epoxy resin composition and use thereof, ultraviolet-curable can coating composition, and process for producing coated metal can§
  申请人：DAICEL CHEMICAL INDUSTRIES, LTD.

  公开号：EP2031006A1

  公开（公告）日：2009-03-04

  The invention relates to a liquid epoxy resin composition containing an alicyclic epoxy compound of formula I as a main component. It also relates to a photosemiconductor device comprising a photosemiconductor element encapsulated with the epoxy resin composition. The epoxy resin composition can be cured by heating, thereby obtaining a cured product having excellent moisture and heat resistance and transparency.

  本发明涉及一种液体环氧树脂组合物，其中含有式 I 的脂环族环氧化合物 作为主要成分。 本发明还涉及一种光电半导体器件，该器件包括用环氧树脂组合物封装的光电半导体元件。 该环氧树脂组合物可通过加热固化，从而获得具有优异的耐湿性、耐热性和透明度的固化产品。
• Method of producing epoxy compound, epoxy resin composition and its applications, ultraviolet rays-curable can-coating composition and method of producing coated metal can
  申请人：——

  公开号：US20030059618A1

  公开（公告）日：2003-03-27

  The invention I provides a method of producing an alicyclic epoxy compound having a specific structure, which comprises epoxidizing an alicyclic olefin compound having a specific structure by using an aliphatic percarboxylic acid having low water content. The alicyclic epoxy compound is useful for use in coatings, inks, adhesives, sealants, encapsulants, stabilizers or the like. The invention II provides an epoxy resin composition containing the alicyclic epoxy compound as a main component, and a photosemiconductor device comprising a photosemiconductor element encapsulated with the epoxy resin composition. The epoxy resin composition can be cured by heating, thereby obtaining a cured product having excellent moisture and heat resistance and transparency. The invention III provides: an ultraviolet rays-curable can-coating composition containing the alicyclic epoxy compound as a main component, which can be cured by ultraviolet irradiation, and can form a coating film having excellent film performances such as processability, adhesion, hardness and scratch resistance, particularly film appearance and retort resistance; and a process of producing a coated metal can using the composition.

  本发明一提供了一种生产具有特定结构的脂环族环氧化合物的方法，该方法包括使用含水量低的脂肪族过羧酸对具有特定结构的脂环族烯烃化合物进行环氧化。脂环族环氧化合物可用于涂料、油墨、粘合剂、密封剂、封装剂、稳定剂等。 本发明二提供了一种含有脂环族环氧化合物作为主要成分的环氧树脂组合物，以及一种光电半导体器件，该器件包括用环氧树脂组合物封装的光电半导体元件。环氧树脂组合物可以通过加热固化，从而获得具有优异的耐湿性、耐热性和透明度的固化产品。 本发明III提供了：一种紫外线固化罐涂层组合物，该组合物以脂环族环氧化合物为主要成分，可通过紫外线照射固化，并可形成具有优异涂膜性能（如加工性、附着力、硬度和抗划伤性）的涂膜，特别是涂膜外观和耐蒸煮性；以及一种使用该组合物生产涂层金属罐的工艺。
• US3954650A
  申请人：——

  公开号：US3954650A

  公开（公告）日：1976-05-04