Tert-butyl 9-oxo-9H-fluorene-2-carboperoxoate | 94630-66-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: Tert-butyl 9-oxo-9H-fluorene-2-carboperoxoate
• 英文别名: tert-butyl 9-oxofluorene-2-carboperoxoate
• CAS: 94630-66-7
• 化学式: C₁₈H₁₆O₄
• 分子量: 296.3
• InChiKey: MGQWBZUGSZVOOK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.22
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• Method of generating a reactive species and applications thereof
  申请人：KIMBERLY-CLARK CORPORATION

  公开号：EP0994125A1

  公开（公告）日：2000-04-19

  A method of generating reactive species which includes providing a wavelength-specific sensitizer associated with a reactive species generating photoinitiator, wherein the wavelength-specific sensitizer comprises a phthalic acid derivative or a phenyl-substituted aliphatic ketone derivative; and irradiating the wavelength-specific sensitizer. The sensitizer absorbs energy and transfers the absorbed energy to the photoinitiator, which, in turn, generates reactive species. The radiation to which the polymolecular photoreactor is exposed generally will have a wavelength of from about 4 to about 1,000 nanometers. Thus, the radiation may be ultraviolet radiation, including near ultraviolet and far or vacuum ultraviolet radiation: visible radiation: and near infrared radiation. Also described are methods of polymerizing unsaturated monomers and curing an unsaturated oligomer/monomer mixture.

  一种产生反应物的方法，包括提供与产生反应物的光引发剂相关联的波长特异性敏化剂，其中波长特异性敏化剂包括邻苯二甲酸衍生物或苯基取代的脂肪族酮衍生物；以及照射波长特异性敏化剂。敏化剂吸收能量并将吸收的能量转移给光引发剂，光引发剂反过来产生反应物。聚合分子光反应器受到的辐射波长一般在 4 纳米到 1000 纳米之间。因此，辐射可以是紫外线辐射，包括近紫外线辐射、远紫外线辐射或真空紫外线辐射、可见光辐射和近红外线辐射。还描述了不饱和单体聚合和不饱和低聚物/单体混合物固化的方法。
• Light curable articles containing azinium salts
  申请人：Majumdar Debasis

  公开号：US20060223902A1

  公开（公告）日：2006-10-05

  The present invention relates to a light curable material comprising a splayed layered material, at least one aqueous dispersible polymerizer, and at least one aqueous soluble N-oxyazinium compound, wherein the polymerizer polymerizes upon exposure to light. The present invention also includes a method for curing a material comprising providing layered material, splaying the layered material, combining the splayed layered material with a polymerizer and an aqueous soluble N-oxyazinium compound, and subjecting the combination to light for a period of time sufficient to effect the polymerization of the polymerizer.

  本发明涉及一种光固化材料，该材料包括分层材料、至少一种水性可分散聚合剂和至少一种水溶性N-氧嗪化合物，其中聚合剂在光照下聚合。本发明还包括一种固化材料的方法，该方法包括提供分层材料，将分层材料平铺，将平铺的分层材料与聚合剂和水溶性N-氧嗪化合物结合，并将该组合物置于光照下一段时间，足以使聚合剂聚合。
• METHOD OF GENERATING A REACTIVE SPECIES AND APPLICATIONS THEREFOR
  申请人：KIMBERLY-CLARK WORLDWIDE, INC.

  公开号：EP0767803B1

  公开（公告）日：2000-08-23
• US5685754A
  申请人：——

  公开号：US5685754A

  公开（公告）日：1997-11-11
• US5686503A
  申请人：——

  公开号：US5686503A

  公开（公告）日：1997-11-11