Nylon MXD6 based biaxially stretched polyamide film of low permeability to gases and production method thereof
申请人:MITSUBISHI GAS CHEMICAL COMPANY, INC.
公开号:EP1350806A1
公开(公告)日:2003-10-08
The biaxially stretched film of the present invention comprises a polyamide resin composition (C) obtained by melt-kneading a smectite (B) with a polyamide (A) produced by the polycondensation of a diamine component containing 70 mol% or higher of m-xylylenediamine and a dicarboxylic acid component containing 70 mol% or higher of a C4-C20 α,ω-linear aliphatic dicarboxylic acid, or comprises at least one layer made of the polyamide resin composition (C). The polyamide resin composition (C) comprises the polyamide (A) in an amount of 80 to 99.9 parts by weight and the smectite (B) in an amount of 0.1 to 10 parts by weight. The layer made of the polyamide resin composition (C) has a relative peak intensity ratio of 60 or less. The relative peak intensity ratio is represented by the formula: B/A × 100, wherein A and B are intensities of the strongest peak and the next stronger peak appearing in a diffraction angle 2θ ranging from 15° to 25° of a CuKα X-ray diffraction pattern of the layer made of the polyamide resin composition (C), provided that A is the peak intensity of the peak at a lower angle and B is the peak intensity of the peak at a higher angle.
本发明的双轴拉伸薄膜包括一种聚酰胺树脂组合物(C),该组合物是通过熔化捏合一种烟晶石(B)和一种聚酰胺(A)而得到的,聚酰胺(A)是由含有 70 摩尔%或更高的间二甲苯二胺的二胺组分和含有 70 摩尔%或更高的 C4-C20α,ω-线性脂肪族二羧酸的二羧酸组分缩聚而成的,或者包括至少一层由聚酰胺树脂组合物(C)制成的薄膜。聚酰胺树脂组合物 (C) 包括聚酰胺 (A)(重量份数为 80 至 99.9 份)和烟晶石 (B)(重量份数为 0.1 至 10 份)。由聚酰胺树脂组合物(C)制成的层的相对峰值强度比为 60 或更低。相对峰强度比用公式表示为B/A×100,其中 A 和 B 是聚酰胺树脂组合物 (C) 制成的层的 CuKα X 射线衍射图样的 15°至 25°衍射角 2θ 范围内出现的最强峰和次强峰的强度,条件是 A 是较低角度峰的峰强度,B 是较高角度峰的峰强度。