cyclohex-2-enyl-phosphonic acid | 109660-02-8

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机膦酸及其衍生物
• 英文名称: cyclohex-2-enyl-phosphonic acid
• 英文别名: Cyclohex-2-enyl-phosphonsaeure；Cyclohex-2-en-1-ylphosphonic acid
• CAS: 109660-02-8
• 化学式: C₆H₁₁O₃P
• 分子量: 162.125
• InChiKey: FCPZWSAJRRKPLK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  10
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  57.5
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  cyclohex-2-enyl-phosphonic acid 在 溴 作用下， 生成 (2,3-dibromo-cyclohexyl)-phosphonic acid
  参考文献：
  名称：

  The Reaction of Cyclohexene with Phosphorus Pentasulfide

  摘要：

  DOI：

  10.1021/ja01139a058
• 作为产物：
  描述：

  3-cyclohexenylperthiophosphinic acid anhydride dimer 在 水 作用下， 生成 cyclohex-2-enyl-phosphonic acid
  参考文献：
  名称：

  The Reaction of Cyclohexene with Phosphorus Pentasulfide

  摘要：

  DOI：

  10.1021/ja01139a058

文献信息

• Trifunctional olefinic-capped polymers and compositions that include such polymers
  申请人：——

  公开号：US20030032732A1

  公开（公告）日：2003-02-13

  A polymer having at least one reactive terminal or pendant functional group that has been capped with a trifunctional olefinic compound. The polymer can be made by contacting a base polymer having at least one reactive terminal or pendant functional group with a trifunctional olefinic compound under conditions effective to react at least one of the terminal or pendant functional groups with the trifunctional olefinic compound. The capped polymers are particularly suitable as crosslinking toughening agents in multi-components compositions such as adhesives, coatings and matrices for composites.

  具有至少一个反应端或挂链官能团的聚合物，该聚合物已被三官能基烯烃化合物封顶。该聚合物可以通过将至少具有一个反应端或挂链官能团的基础聚合物与三官能基烯烃化合物接触，在有效反应条件下至少反应一个端或挂链官能团与三官能基烯烃化合物。封顶的聚合物在多组分组成物中特别适用于交联增韧剂，例如粘合剂、涂料和复合材料基体。
• Internally coordinated organoboranes
  申请人：Lord Corporation

  公开号：US20040242817A1

  公开（公告）日：2004-12-02

  Disclosed are internally coordinated organoboranes as 5, 6, or 7-membered rings formed from an unsaturated amine, amidine, or guanidine and dialkylhydroborane under hydroboration conditions, as well as two-part adhesive or coating kits containing radical polymerizable material and the internally coordinated organoborane. A representative internally coordinated organoborane is: 1

  本发明涉及在氢化硼条件下，从不饱和胺、酰胺或脲和二烷基氢硼烷形成的5、6或7元环的内部配位有机硼化合物，以及包含自由基聚合材料和内部配位有机硼烷的两部分粘合剂或涂料套件。代表性的内部配位有机硼化合物为：1。
• TRIFUNCTIONAL OLEFINIC-CAPPED POLYMERS AND COMPOSITIONS THAT INCLUDE SUCH POLYMERS
  申请人：——

  公开号：US20020128418A1

  公开（公告）日：2002-09-12

  A polymer having at least one reactive terminal or pendant functional group that has been capped with a trifunctional olefinic compound. The polymer can be made by contacting a base polymer having at least one reactive terminal or pendant functional group with a trifunctional olefinic compound under conditions effective to react at least one of the terminal or pendant functional groups with the trifunctional olefinic compound. The capped polymers are particularly suitable as crosslinking toughening agents in multi-components compositions such as adhesives, coatings and matrices for composites.

  具有至少一个反应末端或挂链官能团，并已用三官能双键化合物封顶的聚合物。该聚合物可以通过将至少具有一个反应末端或挂链官能团的基础聚合物与三官能双键化合物接触，在有效反应条件下使末端或挂链官能团中的至少一个与三官能双键化合物反应而制得。封顶聚合物特别适用于多组分组合物中的交联增韧剂，例如粘合剂、涂料和复合材料基体。
• Structural adhesive compositions, three component redox catalyst systems and their use in bonding metal surfaces together
  申请人：LORD CORPORATION

  公开号：EP0167223A1

  公开（公告）日：1986-01-08

  Two-package, equal-mix acrylic adhesive compositions are provided, containing as a curing agent a mixture of peroxygen compound, an organic thiol and certain metal ion-containing compounds. Also provided is a three-component oxidation-reduction catalyst system consisting of an organic hydroperoxide, an organic thiol and an inorganic or organic compound of a metal having a standard reduction potential of from +0.9 to -0.5

  提供了双包装、等量混合的丙烯酸粘合剂组合物，其中含有过氧化合物、有机硫醇和某些含金属离子化合物的混合物作为固化剂。 还提供了一种三组分氧化还原催化剂系统，该系统由有机过氧化氢、有机硫醇和无机或有机金属化合物组成，其标准还原电位为 +0.9 至 -0.5
• Structural adhesive formulations
  申请人：LORD CORPORATION

  公开号：EP0220555A2

  公开（公告）日：1987-05-06

  Two-pack adhesive systems which are curable by free radical polymerization at room temperatures are disclosed. The adhesives bond a variety of substrates, including metals and plastics. The adhesives comprise a first part containing free radical polymerizable unsaturated monomer and free radical source and a second part comprising free radical polymerizable unsaturated monomer and an activator compound for the free radical source. The activator compound is a bicyclic amidine, with 1,8-diaza-bicyclo [5.4.0] undec-7-ene being especially preferred. The use of cupric salts enhances polymerization rate.

  本发明公开了可在室温下通过自由基聚合固化的双组分粘合剂系统。这种粘合剂可粘合各种基材，包括金属和塑料。粘合剂包括第一部分（含可自由基聚合的不饱和单体和自由基源）和第二部分（含可自由基聚合的不饱和单体和自由基源的活化剂化合物）。活化剂化合物是一种双环脒，其中以 1,8-二氮双环[5.4.0]十一碳-7-烯为佳。使用铜盐可提高聚合速度。