N-phenyl-N,N'-di[m-tolyl]-N'-[(4-vinylphenyl)]biphenyl-4,4'-diamine | 227176-02-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-phenyl-N,N'-di[m-tolyl]-N'-[(4-vinylphenyl)]biphenyl-4,4'-diamine
• 英文别名: N-[4-[4-(4-ethenyl-N-(3-methylphenyl)anilino)phenyl]phenyl]-3-methyl-N-phenylaniline
• CAS: 227176-02-5
• 化学式: C₄₀H₃₄N₂
• 分子量: 542.723
• InChiKey: SDFBCGIQDKOYRX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.5
• 重原子数：
  42
• 可旋转键数：
  8
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  甲基三苯基溴化膦 、 N,N'-二苯基-N,N'-二(3-甲基苯基)-1,1'-联苯-4,4'-二胺 、 N,N-二甲基甲酰胺 在 三氯氧磷 作用下， 反应 2.5h， 以75%的产率得到N-phenyl-N,N'-di[m-tolyl]-N'-[(4-vinylphenyl)]biphenyl-4,4'-diamine
  参考文献：
  名称：

  空穴传输主体聚合物系列，由三苯胺基本结构组成，用于磷光聚合物发光二极管

  摘要：

  合成了一系列具有三苯胺基单元的新型苯乙烯衍生单体及其聚合物，并将其与众所周知的N，N'-双（3-甲基苯基）-N，N的聚合物结构进行了比较'-二苯基联苯胺在磷光聚合物发光二极管（PLED）中的空穴传输行为方面。选择乙烯基三苯胺结构作为基本单元，在对位具有以下侧基的官能团：二苯胺，3-甲基苯基-苯胺，1-和2-萘胺，咔唑和吩噻嗪。该聚合物在PLED中用作以下系统配置的共混体系的主体聚合物：玻璃/铟锡氧化物/ PEDOT：PSS /聚合物共混物/ CsF / Ca / Ag。除空穴传输主体聚合物外，聚合物共混物还包括磷光掺杂剂[Ir（Me-ppy）3 ]和电子传输分子（2-（4-联苯）-5-（4-叔丁基）-丁基苯基）-1,3,4-恶二唑）。我们证明，对于这些共混体系而言，两种聚合物是出色的空穴传输基质材料，因为它们具有良好的整体电致发光性能和较高的玻璃化转变温度。对于咔唑取代的聚合物（T g =

  DOI：

  10.1002/pola.24127

文献信息

• PHOSPHINE OXIDE COMPOUND, ORGANIC ELECTROLUMINESCENCE ELEMENT, PRODUCTION METHOD AND USES THEREOF
  申请人：TERASHIMA Takashi

  公开号：US20120256536A1

  公开（公告）日：2012-10-11

  A compound having a stable deposition rate suitable for forming an electron-transporting layer of an organic El element. The compound is represented by the following formula (1): wherein in the formula (1), plural R 1 are each an alkyl group having 1 to 10 carbon atoms, an alkoxy group having 1 to 10 carbon atoms, a halogen atom, or a hydrogen atom, and may be the same as or different from one another; and plural Ar are each a monovalent substituted or unsubstituted aromatic group optionally containing a hetero atom, and may be the same as or different from one another.

  一种化合物，具有稳定的沉积速率，适用于形成有机EL元件的电子传输层。该化合物由以下公式（1）表示：其中，在公式（1）中，复数R1分别是具有1到10个碳原子的烷基基团，具有1到10个碳原子的烷氧基团，卤素原子或氢原子，并且可以相同或不同; 复数Ar分别是具有杂原子的单价取代或未取代芳香基团，可以相同或不同。
• Hole-transporting polymers
  申请人：——

  公开号：US20010017155A1

  公开（公告）日：2001-08-30

  Polymers comprising triarylamine substituent monomers. The polymers are products of anionic or radical polymerization of monovinylated triarylamine monomers or of ROMP polymerization of monomers comprising a triarylamine component, a linker component, and a cyclic olefin that is capable of undergoing a ring-opening polymerization reaction. The resulting polymers possess hole-transporting properties and are useful as hole transport layers in light-emitting diodes or as components of photorefractive materials.

  包含三芳胺取代单体的聚合物。这些聚合物是单乙烯化三芳胺单体的阴离子或自由基聚合或由包含三芳胺组分、连接组分和能够进行环开启聚合反应的环烯烃的ROMP聚合单体聚合而成。所得到的聚合物具有传输空穴的性质，可用作发光二极管中的空穴传输层或作为光折变材料的组分。
• Diarylamino group-containing copolymer, organic electroluminescent device, and method of producing hole transport layer for organic electroluminescent device
  申请人：Kato Shinji

  公开号：US20050008893A1

  公开（公告）日：2005-01-13

  An organic electroluminescent device is provided which has a high degree of adhesion between an anode and a hole transport layer, the device emitting light of high luminance even when driven by low applied voltages. Copolymers useful in hole transport layers in organic electroluminescent devices are also provided. Methods of producing hole transport layers for organic electroluminescent devices which can emit light of high luminance even when driven by low applied voltages are also provided, the hole transport layers having high degrees of adhesion with anode. A copolymer comprises a monomer unit including in its structure an electron-donating N,N-diaryl-substituted amino group such as an N,N-diphenylaminophenyl group, or a group having an N,N-diaryl-substituted amino moiety, and a monomer unit having at least one functional group. Also, a hole transport layer, which has excellent thickness accuracy, has an extremely smooth surface, and is very thin, can be formed of this copolymer or a copolymer having the same hole transport functional group. An organic electroluminescent device, which emits light of high luminance even when driven by low applied voltages, can be obtained by using this hole transport layer.

  提供了一种有机电致发光器件，其阳极和空穴传输层之间具有高度的粘附性，即使在低电压驱动下也能发出高亮度的光。还提供了在有机电致发光器件中用于空穴传输层的共聚物。还提供了制备空穴传输层的方法，该方法可以在低电压驱动下发出高亮度的光，空穴传输层与阳极具有高度的粘附性。共聚物包括一个单体单元，其结构中包括一个电子给体的N，N-二芳基取代氨基，例如N，N-二苯基氨基苯基基团，或具有N，N-二芳基取代氨基基团的基团，以及至少具有一个功能基团的单体单元。此共聚物或具有相同空穴传输功能基团的共聚物可以形成具有优异厚度精度、极其光滑表面且非常薄的空穴传输层。通过使用此空穴传输层，可以获得发出高亮度光的有机电致发光器件，即使在低电压驱动下也能发光。
• IRIDIUM COMPLEX COMPOUND, ORGANIC ELECTROLUMINESCENT DEVICE OBTAINED BY USING THE SAME, AND USES OF THE DEVICE
  申请人：Igarashi Takeshi

  公开号：US20090315454A1

  公开（公告）日：2009-12-24

  The present invention provides an organic EL device having a high luminous efficiency and a long life, and an iridium complex compound used for preparing the above device. The iridium complex compound is represented by the following Formula (1): [in Formula (1), R 1 to R 4 are each independently a specific group; at least one of R 1 to R 4 is a group having 2 or more carbon atoms; R 5 to R 8 are each independently a specific group; and at least one of R 5 to R 8 is a specific electron-withdrawing group; (with the proviso that R 1 to R 8 are not combined with each other to form rings)].

  本发明提供了一种具有高发光效率和长寿命的有机EL器件，以及用于制备上述器件的铱配合物化合物。铱配合物化合物由以下公式（1）表示：[在公式（1）中，R1至R4各自独立地表示特定的基团；至少有一个R1至R4是具有2个或更多碳原子的基团；R5至R8各自独立地表示特定的基团；并且至少有一个R5至R8是特定的电子吸引基团；（前提是R1至R8不与彼此结合形成环）]。
• Phosphorescent polymer compound and organic light emitting device using the same
  申请人：Koyama Tamami

  公开号：US20070155928A1

  公开（公告）日：2007-07-05

  The present invention relates to a phosphorescent polymer compound comprising a phosphorescent monomer unit and a hole transporting monomer unit having a triphenylamine structure represented by the formula (1): (in the formula, the symbols have the same meanings as defined in the Description), and an organic light emitting device using the compound. Use of the phosphorescent polymer compound of the present invention enables production of organic light emitting device with a high light emitting efficiency at a low voltage, which is suitable for increasing the emission area and mass production.

  本发明涉及一种荧光聚合物化合物，包括一个荧光单体单元和一个孔传输单体单元，该孔传输单体单元具有三苯胺结构，由公式（1）表示：（在公式中，符号与说明中定义的含义相同），以及使用该化合物的有机发光装置。使用本发明的荧光聚合物化合物可以在低电压下生产具有高发光效率的有机发光装置，适用于增加发射面积和大规模生产。