N-(1,8-naphthalenedicarboximidyl) 10-camphorsulfonate | 83697-56-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: N-(1,8-naphthalenedicarboximidyl) 10-camphorsulfonate
• 英文别名: (1,3-Dioxobenzo[de]isoquinolin-2-yl) (7,7-dimethyl-2-oxo-1-bicyclo[2.2.1]heptanyl)methanesulfonate
• CAS: 83697-56-7
• 化学式: C₂₂H₂₁NO₆S
• 分子量: 427.478
• InChiKey: GQTLOGQTRXBOHV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  30
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  106
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  N-(1,8-naphthalenedicarboximidyl) 10-camphorsulfonate 、 螺[1,3,3-三甲基吲哚-(6'-硝基苯并二氢吡喃)] 在 poly(methylmethacrylate) 作用下， 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Stable Colored and Fluorescent Patterns Derived from Photochromic Spiropyran and Photoacid Generator

  摘要：

  When the poly(methylmethacrylate) films containing 1 ',3 '-dihydro-1 ',3 ',3 '-trimethyl-6-nitrospiro[2H-1-benzopyran-2,2 '-(2H)-indole] (SP1) and N-(1,8-naphthalene dicarboximidyl)-10-camphorsulfonate (NIC) were irradiated by UV light, a salt was formed from the reaction of phenolate in the merocyanine form (the photo-product of SP1) and the photo-generated acid. The original absorption of the film at 338nm decreased and a new absorption band appeared at 400 similar to 500nm due to the salt formation between the photo-generated acid and the merocyanine form of SP1. The resulting yellow films showed an orange-red emission centered around 520nm, while the original colorless films have no fluorescence. The irradiation of film through a mask produced a finely resolved pattern and the patterned image was quite stable over several months of storage in the dark at room temperature. The photo-irradiation of the film also induced the refractive index change as large as 0.0022.

  DOI：

  10.1080/15421400802330515

文献信息

• CYCLIC COMPOUND, PHOTORESIST BASE MATERIAL AND PHOTORESIST COMPOSITION
  申请人：Shibata Mitsuru

  公开号：US20100190107A1

  公开（公告）日：2010-07-29

  A cyclic compound shown by the following formula (I):

  一个由以下公式（I）所示的环状化合物：
• NOVEL SULFONIC ACID DERIVATIVE COMPOUND AND NOVEL NAPHTHALIC ACID DERIVATIVE COMPOUND
  申请人：Murai Toshihiko

  公开号：US20120289697A1

  公开（公告）日：2012-11-15

  Disclosed are a novel sulfonic acid derivative compound and a novel naphthalic acid derivative compound with high solubility in organic solvents, good photosensitivity, and suitability as a photoacid generator and a polymerization initiator. The sulfonic acid derivative compound is represented by the formula (I) (wherein R 01 , R 04 , R 05 , and R 06 represent a hydrogen atom; any one of R 02 and R 03 represents an alkoxy group having a carbon number of 4 to 18 which may be substituted with an alicyclic hydrocarbon group, a heterocyclic group, or a halogen atom and which may have a branch, or the like; and R 07 represents an aliphatic hydrocarbon group having a carbon number of 1 to 18 which may be substituted with a halogen atom and/or an alkylthio group, or the like).

  揭示了一种新颖的磺酸衍生物化合物和一种新颖的萘甲酸衍生物化合物，具有在有机溶剂中高溶解度、良好的光敏性，并适用于光酸发生剂和聚合引发剂。磺酸衍生物化合物由以下式(I)表示（其中R01、R04、R05和R06代表氢原子；R02和R03中的任一表示具有4至18个碳原子的烷氧基，可以被取代为脂环烃基、杂环基或卤素原子，并且可以具有支链等；R07表示具有1至18个碳原子的脂肪烃基，可以被取代为卤素原子和/或烷基硫基等）。
• Cured film-forming composition
  申请人：NISSAN CHEMICAL CORPORATION

  公开号：US10669376B2

  公开（公告）日：2020-06-02

  Provided are: a cured film-forming composition whereby a underlayer film for image formation formed from the composition exhibits high liquid repellency (lyophobicity) and lyophilic/liquid-repellent properties of the underlayer film can be easily changed even when exposed to a low amount of ultraviolet radiation; and a cured film obtained using the composition. The cured film-forming resin composition is characterized by containing: a polymer comprising a structural unit derived from a first monomer having the structure of formula (1) as component (A); a polymer other than component (A), which is a polymer in which the content of fluorine relative to the overall weight of the polymer is lower than in component (A), as component (B); a photoacid generator as component (C); and a solvent. (In the formula, R1 denotes hydrogen or a methyl group, and R2 denotes a fluorine-containing group able to be detached together with the oxygen atom bonded to R2.)

  提供的是一种治愈的成膜组合物，由该组合物形成的图像形成底层膜表现出高液体排斥性（亲疏性），即使暴露于低量紫外辐射下，底层膜的亲疏性和液体排斥性也可以轻松改变；以及使用该组合物获得的治愈膜。该治愈成膜树脂组合物的特点是包含：作为组分（A）的具有来自第一单体的结构单元的聚合物，该单体的结构式为（1）；除组分（A）外的另一种聚合物，其相对于聚合物总重量的含氟量低于组分（A），作为组分（B）；作为组分（C）的光酸发生剂；和溶剂。（在公式中，R1表示氢或甲基基团，R2表示能够与R2键合的氧原子一起脱落的含氟基团。）
• CALIXRESORCINARENE COMPOUND, PHOTORESIST BASE COMPRISING THE SAME, AND COMPOSITION THEREOF
  申请人：Watanabe, Takeo

  公开号：EP1886989A1

  公开（公告）日：2008-02-13

  A calixresorcinarene compound represented by the following formula (1): wherein eight Rs are n (n is an integer of 1 to 7) substituents that are one or more types of substituents selected from groups represented by the following formula (2), and m (m is an integer shown by 8-n) hydrogen atoms; and R's, which may be the same or different, are each a straight-chain aliphatic hydrocarbon group having 2 to 12 carbon atoms, a branched aliphatic hydrocarbon group having 3 to 12 carbon atoms, a phenyl group, a p-phenylphenyl group, a p-tert-butylphenyl group, and an aromatic group represented by the following formula (3), or a substituent formed by combining two or more of these substituents: wherein R" is a hydrogen atom or a substituent selected from the substituents represented by the formula (2).

  以下是一个由下式（1）表示的calixresorcinarene化合物： 其中，八个Rs是n（n是1到7的整数）取代基，是从以下式（2）所代表的基团中选择的一种或多种类型的取代基，m（m是8-n所示的整数）个氢原子；而R'可以相同也可以不同，每个都是具有2到12个碳原子的直链脂肪烃基，具有3到12个碳原子的支链脂肪烃基，苯基，p-苯基苯基，p-叔丁基苯基和由以下式（3）所代表的芳基或两个或更多这些取代基组合形成的取代基： 其中，R"是氢原子或从式（2）所代表的取代基中选择的取代基。
• CURED-FILM FORMATION COMPOSITION, ORIENTATION MATERIAL, AND RETARDATION MATERIAL
  申请人：NISSAN CHEMICAL INDUSTRIES, LTD.

  公开号：US20150275091A1

  公开（公告）日：2015-10-01

  There is provided a cured-film formation composition for providing an orientation material that has high photoreaction efficiency and excellent solvent resistance with adhesion durability, and that enables a polymerizable liquid crystal to be aligned even on a resin film in a highly sensitive manner. A cured-film formation composition including: (A) an acrylic polymer having a photo-aligning group; (B) a polymer having any one of a hydroxy group, a carboxy group, and an amino group on at least two terminals of a group bonded to a main chain; and (C) a cross-linking agent. An orientation material and a retardation material are obtained with the cured-film formation composition.

  提供了一种固化膜形成组合物，用于提供具有高光反应效率和优异溶剂抗性、附着耐久性的取向材料，并使可聚合液晶在树脂膜上高度敏感地对齐。该固化膜形成组合物包括：（A）具有光取向基团的丙烯酸聚合物；（B）在至少两个与主链结合的基团的末端具有羟基、羧基或氨基中的任意一种的聚合物；以及（C）交联剂。使用该固化膜形成组合物可以获得取向材料和减 retardation材料。