申请人:Bridgestone Corporation
公开号:EP0854168A1
公开(公告)日:1998-07-22
The present invention is a rubber composition comprising 0.2 to 10 parts by weight of at least one compound selected from the group consisting of 2-mercaptobenzothiazole compound containing an alkoxy groups represented by the following general formulae (I), (II) and (III) based on 100 parts by weight of at least one rubber raw material selected from the group consisting of natural rubber and diene-based synthetic rubbers: General formula (I)
General formula (II)
General formula (III)
wherein R1 represents an alkyl group, alkenyl group or cycloalkyl group having 1 to 8 carbon atoms; R2 represents a hydrogen atom or an amino group represented by -N(R3)R4; R3 and R4 each independently represent a hydrogen atom or an alkyl group or cyclohexyl group having 2 to 4 carbon atoms (wherein, R3 and R4 do not simultaneously represent a hydrogen atom); R5 and R6 each independently represent an alkyl group, alkenyl group or cycloalkyl group having 1 to 8 carbon atoms; X represent a Zn atom, Cu atom or an amino group represented by >N-R9; R9 represents an alkyl group or cyclohexyl group having 2 to 4 carbon atoms; and R7 and R8 have the same meaning as R5. By this rubber composition, high breaking resistance after heat aging is provided.
本发明是一种橡胶组合物,以 100 重量份的至少一种选自天然橡胶和二烯基合成橡胶的橡胶原料为基准,含有 0.2 至 10 重量份的至少一种选自含有以下通式(I)、(II)和(III)代表的烷氧基的 2-巯基苯并噻唑化合物的化合物:通式 (I)
通式 (II)
通式(III)
其中 R1 代表具有 1 至 8 个碳原子的烷基、烯基或环烷基;R2 代表氢原子或由 -N(R3)R4 代表的氨基;R3 和 R4 各自独立地代表氢原子或具有 2 至 4 个碳原子的烷基或环己基(其中,R3 和 R4 不同时代表氢原子);R5 和 R6 各自独立地代表具有 1 至 8 个碳原子的烷基、烯基或环烷基;X 代表 Zn 原子、Cu 原子或由 >N-R9 表示的氨基;R9 代表具有 2 至 4 个碳原子的烷基或环己基;R7 和 R8 的含义与 R5 相同。这种橡胶组合物在热老化后具有很高的抗断裂性。