Sylvestren-diepoxyd | 112047-48-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧杂环己烷
• 英文名称: Sylvestren-diepoxyd
• 英文别名: 1,6;8,9-diepoxy-m-menthane；1-Methyl-3-(2-methyloxiran-2-yl)-7-oxabicyclo[4.1.0]heptane
• CAS: 112047-48-0
• 化学式: C₁₀H₁₆O₂
• 分子量: 168.236
• InChiKey: XOIZUVFIXICDDB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  25.1
• 氢给体数：
  0
• 氢受体数：
  2

文献信息

• GREASE COMPOSITION
  申请人：JX NIPPON OIL & ENERGY CORPORATION

  公开号：US20150133353A1

  公开（公告）日：2015-05-14

  The grease composition of the present invention comprises at least one base oil selected from a mineral oil and a synthetic oil, and based on the total amount of the grease composition, 2 to 35% by mass of a thickener, 0.05 to 5% by mass of an epoxy compound and 0.1 to 20% by mass of an antiwear additive. The grease of the present invention is good in stability, lubricity and friction characteristics and excellent in long-term reliability even under severe use conditions as compared with conventional grease.

  本发明的润滑脂组合物包括至少一种从矿物油和合成油中选择的基础油，并且基于润滑脂组合物的总量，包括2至35%的质量厚化剂，0.05至5%的质量环氧化合物和0.1至20%的质量抗磨添加剂。与传统润滑脂相比，本发明的润滑脂在稳定性、润滑性和摩擦特性方面表现良好，并且在恶劣使用条件下具有卓越的长期可靠性。
• Composition for refrigerator working fluid use
  申请人：KAO CORPORATION

  公开号：EP0501440A1

  公开（公告）日：1992-09-02

  This invention provides a refrigerator working fluid composition characterized by excellent compatibility, lubricating ability, thermal stability, and electrical insulation capacity, and comprising a refrigerating machine oil and a hydrofluorocarbon compound, wherein the refrigerating machine oil comprises: (A) 100 parts by weight of at least one ester compound selected from the group consisting of: (1) ester compounds obtained from (a) an aliphatic polyhydric alcohol having 1 to 6 primary hydroxyl groups, (b) a straight or branched chain saturated aliphatic monocarboxylic acid having 2 to 9 carbon atoms or a derivative thereof, and (c) a straight or branched chain saturated aliphatic dicarboxylic acid having 2 to 10 carbon atoms or a derivative thereof; and (2) ester compounds obtained from (a) an aliphatic polyhydric alcohol having 1 to 6 primary hydroxyl groups, (d) a straight or branched chain saturated aliphatic monohydric alcohol having 1 to 10 carbon atoms, and (e) a polycarboxylic acid having 2 to 10 carbon atoms or a derivative thereof; and (B) at least one compound selected from the group consisting of 0.1 to 5.0 parts by weight of a triaryl phosphate, a triaryl phosphite, or a mixture thereof; 0.001 to 0.1 parts by weight of benzotriazole, a derivative thereof, or a mixture thereof; 0.05 to 2.0 parts by weight of an epoxy group-containing compound; and 0.001 to 2.0 parts by weight of a metal deactivator having a chelating function.

  本发明提供了一种冰箱工作液组合物，其特点是具有优异的相容性、润滑性、热稳定性和电绝缘能力，由冷冻机油和氢氟碳化合物组成，其中冷冻机油包括： (A) 至少 100 重量份的一种酯类化合物，该化合物选自由下列物质组成的组 (1) 从下列物质中获得的酯化合物 (a) 具有 1 至 6 个伯羟基的脂肪族多元醇、 (b) 具有 2 至 9 个碳原子的直链或支链饱和脂肪族一羧酸或其衍生物，和 (c) 具有 2 至 10 個碳原子的直鏈或支鏈飽和脂肪族二羧酸或其衍生物； 及 (2) 从以下物质中获得的酯化合物 (a) 具有 1 至 6 个伯羟基的脂肪族多元醇、 (d) 具有 1 至 10 個碳原子的直鏈或支鏈飽和脂肪族一元醇，及 (e) 具有 2 至 10 个碳原子的聚羧酸或其衍生物；及 (B) 至少一种选自以下组别的化合物：0.1 至 5.0 重量份的三芳基磷酸酯、三芳基亚磷酸酯或其混合物；0.001 至 0.1 重量份的苯并三唑、其衍生物或其混合物；0.05 至 2.0 重量份的含环氧基化合物；以及 0.001 至 2.0 重量份的具有螯合功能的金属失活剂。
• Refrigerator oil composition and fluid composition for refrigerator
  申请人：NIPPON OIL CO. LTD.

  公开号：EP0699742A2

  公开（公告）日：1996-03-06

  A refrigerator oil for use with an HFC refrigerant containing HFC-134a and/or HFC-125, which comprises: (A) 70 to 99% by weight of an alkylbenzene oil containing at least 60% by weight (based on the total weight of the component (A)) of alkylbenzenes having a molecular weight of 200 to 350 and (B) 30 to 1% by weight of a synthetic oil containing oxygen. There is also proposed a refrigerator fluid composition comprising the above-mentioned refrigerator oil and an HFC refrigerant containing HFC-134a and/or HFC-125, together with or without an additive such as a phosuphorus compound.

  一种与含 HFC-134a 和/或 HFC-125 的 HFC 制冷剂配合使用的冷冻机油，包括 (A) 70%至 99%（按重量计）的烷基苯油，其中至少 60%（按重量计）的烷基苯 分子重量为 200 至 350；以及 (B) 30%至 1%（按重量计）的含氧合成油。此外，还提出了一种冰箱流体组合物，包括上述冰箱油和含有 HFC-134a 和/或 HFC-125 的氢氟碳化物制冷剂，以及或不包括添加剂，例如磷佛尔化合物。
• Lubricating oil and composition for refrigerating machine, and refrigerating machine
  申请人：NIPPON OIL CO. LTD.

  公开号：EP0711824A2

  公开（公告）日：1996-05-15

  A lubricating oil for refrigerating machines mainly comprises polyoxyalkylene compounds represented by the following formula (I);    wherein A represents a residue obtained from a compound which has both a heterocyclic ring having an ether linkage and hydroxyl groups in the molecule by eliminating the hydroxyl groups from the compound; R¹ and R² are each an alkylene group; R³ is an alkyl group; R⁴ is hydrogen atom or an alkyl group; a and b are each a positive integer and ℓ, m and n are each an integer of 0 or more with the proviso that a·ℓ + b·m = 2 to 100 and ℓ + m + n = 2 to 20; further,    the polyoxyalkylene compounds satisfying the following two conditions: (a) the compounds have a hydroxyl value ranging from 0 mgKOH/g to 30.0 mgKOH/g and (b) a ratio of butylene groups of all alkylene groups represented by R¹ and R² to the all alkylene groups satisfies the following formula (1)0.5 ≦ p/(p + q) ≦ 1.0    wherein "p" is the number of butylene groups, "q" is the number of alkylene groups excluding the butylene groups. In other embodiments, this invention relates to a composition for refrigerating machines comprising the lubricating oil mentioned above and an alkane fluoride and/or alkane chlorofluoride refrigerant, and also to a refrigerating machine wherein the composition is used.

  冷冻机润滑油主要包括下式 (I) 所代表的聚氧亚烷基化合物； 其中，A 代表通过消除化合物中的羟基，从分子中既有醚键的杂环又有羟基的化合物中获得的残留物；R¹ 和 R² 各为一个亚烷基，R³ 为一个烷基；R⁴ 为氢原子或烷基；R³ 是烷基；R⁴ 是氢原子或烷基；a 和 b 分别是正整数，ℓ、m 和 n 分别是 0 或 0 以上的整数，但 a-ℓ + b-m = 2 至 100，ℓ + m + n = 2 至 20；此外、 满足以下两个条件的聚氧亚烷基化合物： (a) 化合物的羟值范围为 0 mgKOH/g 至 30.0 mgKOH/g，以及 (b) R¹和 R² 所代表的所有亚烷基的丁烯基团与所有亚烷基的比例满足下式 (1)0.5 ≦ p/(p + q) ≦ 1.0 其中，"p "是丁烯基团的数目，"q "是不包括丁烯基团的亚烷基的数目。 在其他实施方案中，本发明涉及一种用于制冷机的组合物，该组合物包含上述润滑油和氟化烷烃和/或氟氯化烷制冷剂，还涉及一种使用该组合物的制冷机。
• A refrigerating machine oil and a fluid composition for use in a refrigerating machine
  申请人：NIPPON OIL CO. LTD.

  公开号：EP0717098A2

  公开（公告）日：1996-06-19

  A refrigerating machine oil for use with a hydrofluorocarbon refrigerant in a refrigerator, which comprises at least one member selected from the group consisting of hydrocarbon compounds represented by the following general formulas (1), (2) and (3)    (wherein R represents an alkylene group or alkenylene group having 1 to 8 carbon atoms; R¹, R², R³ and R⁴ may be the same or different and are each a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, the total number of carbon atoms of R, R¹, R², R³ and R⁴ being within a range of 1 to 8; and R⁶, R⁷, R⁸ and R⁹ may be the same or different and are each a hydrogen atom or a hydrocarbon group having 1 to 10 carbon atoms, the total number of carbon atoms of R⁶, R⁷, R⁸ and R⁹ being within a range of 1 to 10). In other embodiments, a fluid composition for use in refrigerating machine which comprises a hydrofluorocarbon refrigerant and at least one hydrocarbon compound, a refrigerating machine which uses therein the fluid composition as a circulating fluid, and a method of lubricating a cooling system of a refrigerator using therein a hydrofluorocarbon refrigerant by using said refrigerator oil in the cooling system.

  一种在冰箱中与氢氟碳化合物制冷剂配合使用的冷冻机油，它由至少一种从以下通式（1）、（2）和（3）所代表的碳氢化合物组成的组中选出的成员构成 (其中 R 代表具有 1 至 8 个碳原子的亚烷基或烯基；R¹、R²、R³ 和 R⁴ 可以相同或不同，并且各自为氢原子或具有 1 至 4 个碳原子的烷基，R、R¹、R²、R³ 和 R⁴ 的碳原子总数在 1 至 8 的范围内；R⁶、R⁷、R⁸和R⁹可以相同或不同，并且各自为氢原子或具有 1 至 10 个碳原子的烃基，R⁶、R⁷、R⁸和 R𠞙 的碳原子总数在 1 至 10 的范围内）。在其他实施例中，一种用于制冷机的流体组合物，它包括氢氟碳制冷剂和至少一种碳氢化合物；一种制冷机，其中使用该流体组合物作为循环流体；以及一种通过在制冷系统中使用所述冷冻机油润滑其中使用氢氟碳制冷剂的制冷机的冷却系统的方法。