2-(dibenzo[b,d]furan-4-yl)-4-fluoropyridine

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 2-(dibenzo[b,d]furan-4-yl)-4-fluoropyridine
• 英文别名: 2-Dibenzofuran-4-yl-4-fluoropyridine；2-dibenzofuran-4-yl-4-fluoropyridine
• 化学式: C₁₇H₁₀FNO
• 分子量: 263.271
• InChiKey: AEDUCYYTUGHGBS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  26
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  potassium tetrachloroplatinate(II) 、 2-(dibenzo[b,d]furan-4-yl)-4-fluoropyridine 以 乙二醇乙醚 为溶剂， 反应 24.0h， 生成
  参考文献：
  名称：

  Substituent effect on photo- and electroluminescence properties of heteroleptic cyclometalated platinum(II) complexes based on a 2-(dibenzo[b,d]furan-4-yl)pyridine ligand

  摘要：

  A series of heteroleptic cyclometalated platinum(II) complexes based on a 4- (Pt-1) and 5-substituted (Pt-2) cyclometalated ligand were prepared, and their photoluminescence (PL) and electroluminescence (EL) properties were investigated. In dichloromethane, the complexes bearing a fluoro (Pt-1a and Pt-2a) or a methyl (Pt-1b and Pt-2b) substituent exhibited green PL, whereas a trifluoromethyl substituent induced a red shift, affording yellow PL (Pt-1c and Pt-2c). For poly(methyl methacrylate) thin films doped with Pt-1a-c, higher PL quantum yields were obtained in comparison with the solution samples. Polymer light-emitting diodes (PLEDs) containing the platinum(II) complexes were fabricated, and the devices doped with Pt-1b and Pt-2b showed relatively high external quantum efficiencies. PLEDs doped with varying concentrations of Pt-1b were also fabricated, where generation of excimer-based EL led to significant shifts of the Commision Internationale de L'Eclairage chromaticity coordinate from (0.40, 0.56) (green) to (0.51, 0.48) (orange) with the device efficiency almost constant. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2015.09.015
• 作为产物：
  描述：

  2-氯-4-氟吡啶 、 4-二苯并呋喃硼酸 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 乙二醇二甲醚 、 乙醇 、 水 为溶剂， 反应 24.0h， 以67%的产率得到2-(dibenzo[b,d]furan-4-yl)-4-fluoropyridine
  参考文献：
  名称：

  Substituent effect on photo- and electroluminescence properties of heteroleptic cyclometalated platinum(II) complexes based on a 2-(dibenzo[b,d]furan-4-yl)pyridine ligand

  摘要：

  A series of heteroleptic cyclometalated platinum(II) complexes based on a 4- (Pt-1) and 5-substituted (Pt-2) cyclometalated ligand were prepared, and their photoluminescence (PL) and electroluminescence (EL) properties were investigated. In dichloromethane, the complexes bearing a fluoro (Pt-1a and Pt-2a) or a methyl (Pt-1b and Pt-2b) substituent exhibited green PL, whereas a trifluoromethyl substituent induced a red shift, affording yellow PL (Pt-1c and Pt-2c). For poly(methyl methacrylate) thin films doped with Pt-1a-c, higher PL quantum yields were obtained in comparison with the solution samples. Polymer light-emitting diodes (PLEDs) containing the platinum(II) complexes were fabricated, and the devices doped with Pt-1b and Pt-2b showed relatively high external quantum efficiencies. PLEDs doped with varying concentrations of Pt-1b were also fabricated, where generation of excimer-based EL led to significant shifts of the Commision Internationale de L'Eclairage chromaticity coordinate from (0.40, 0.56) (green) to (0.51, 0.48) (orange) with the device efficiency almost constant. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2015.09.015

文献信息

• Substituent effect on photo- and electroluminescence properties of heteroleptic cyclometalated platinum(II) complexes based on a 2-(dibenzo[b,d]furan-4-yl)pyridine ligand
  作者：Tatsuya Shigehiro、Qiang Chen、Shigeyuki Yagi、Takeshi Maeda、Hiroyuki Nakazumi、Yoshiaki Sakurai

  DOI：10.1016/j.dyepig.2015.09.015

  日期：2016.1

  A series of heteroleptic cyclometalated platinum(II) complexes based on a 4- (Pt-1) and 5-substituted (Pt-2) cyclometalated ligand were prepared, and their photoluminescence (PL) and electroluminescence (EL) properties were investigated. In dichloromethane, the complexes bearing a fluoro (Pt-1a and Pt-2a) or a methyl (Pt-1b and Pt-2b) substituent exhibited green PL, whereas a trifluoromethyl substituent induced a red shift, affording yellow PL (Pt-1c and Pt-2c). For poly(methyl methacrylate) thin films doped with Pt-1a-c, higher PL quantum yields were obtained in comparison with the solution samples. Polymer light-emitting diodes (PLEDs) containing the platinum(II) complexes were fabricated, and the devices doped with Pt-1b and Pt-2b showed relatively high external quantum efficiencies. PLEDs doped with varying concentrations of Pt-1b were also fabricated, where generation of excimer-based EL led to significant shifts of the Commision Internationale de L'Eclairage chromaticity coordinate from (0.40, 0.56) (green) to (0.51, 0.48) (orange) with the device efficiency almost constant. (C) 2015 Elsevier Ltd. All rights reserved.