4,4'-bis[N-(9-phenylcarbazol-3-yl)-N-phenylamino]stilbene

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4,4'-bis[N-(9-phenylcarbazol-3-yl)-N-phenylamino]stilbene
• 英文别名: N,9-diphenyl-N-[4-[(E)-2-[4-(N-(9-phenylcarbazol-3-yl)anilino)phenyl]ethenyl]phenyl]carbazol-3-amine
• 化学式: C₆₂H₄₄N₄
• 分子量: 845.058
• InChiKey: APJQAVDWJQNWQB-QVIHXGFCSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.8
• 重原子数：
  66
• 可旋转键数：
  10
• 环数：
  12.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  16.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  N,9-二苯基-9H-咔唑-3-胺 、 4,4'-二溴-反-芪 在 三叔丁基膦 、 bis(dibenzylideneacetone)-palladium⁽⁰⁾ sodium t-butanolate 作用下， 以 正己烷 、 甲苯 为溶剂， 反应 7.0h， 以47%的产率得到4,4'-bis[N-(9-phenylcarbazol-3-yl)-N-phenylamino]stilbene
  参考文献：
  名称：

  Stilbene derivatives, light-emitting element and light-emitting device

  摘要：

  本发明提供了一种具有优异蓝色纯度的新颖物质、一种发光元件以及使用该新颖物质的发光装置。一种stilbene衍生物具有通式（1）所示的结构。在通式（1）中，R1为氢、具有1至4个碳原子的烷基基团，或具有6至25个碳原子的芳基基团。R2为具有1至4个碳原子的烷基基团或具有6至25个碳原子的芳基基团。R3至R5中的每一个为氢或具有1至4个碳原子的烷基基团。Ar1为具有6至25个碳原子的芳基基团。

  公开号：

  US20070080630A1

文献信息

• ANTHRACENE DERIVATIVE AND LIGHT-EMITTING DEVICES, ELECTRONIC DEVICES, AND LIGHTING DEVICE USING THE ANTHRACENE DERIVATIVE
  申请人：Ogita Kaori

  公开号：US20100099890A1

  公开（公告）日：2010-04-22

  An anthracene derivative is disclosed, and a light-emitting element, a light-emitting device, an electronic device, and a lighting device using the anthracene derivatives are demonstrated. The structure of the anthracene derivative is described in detail in the specification. The use of the anthracene derivative enables the production of a blue emissive light-emitting element having high emission efficiency, excellent purity of emission color, and a long lifetime, which contributes to the production of a high-performance light-emitting device, electronic device, and lighting device.

  揭示了一种蒽衍生物，并展示了使用该蒽衍生物的发光元件、发光装置、电子设备和照明装置。蒽衍生物的结构在说明书中被详细描述。使用蒽衍生物可以生产具有高发射效率、发射颜色纯度优异和长寿命的蓝色发光元件，有助于生产高性能的发光装置、电子设备和照明装置。
• ANTHRACENE DERIVATIVE, AND LIGHT-EMITTING MATERIAL, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING THE SAME
  申请人：OSAKA Harue

  公开号：US20090174321A1

  公开（公告）日：2009-07-09

  Novel anthracene derivatives, novel materials capable of blue light emission with high color purity, and a light-emitting element, a light-emitting device, and an electronic device using any of the novel materials. The anthracene derivative represented by general formula (1) is provided. With the anthracene derivative, a light-emitting element with high emission efficiency can be provided. With the anthracene derivative, a light-emitting element emitting blue light with high color purity can be provided. In the formula, A 1 represents a substituted or unsubstituted phenyl group, B 1 represents any of an alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted phenyl group, α represents any of a substituted or unsubstituted phenylene group or a substituted or unsubstituted biphenyl-4,4′-diyl group, and R 1 to R 9 individually represent any of hydrogen, an alkyl group having 1 to 4 carbon atoms, or a substituted or unsubstituted phenyl group.

  新型蒽衍生物，能够发出高色纯度蓝光的新材料，以及使用任何新材料的发光元件、发光装置和电子装置。提供了通式（1）所代表的蒽衍生物。利用这种蒽衍生物可以提供具有高发射效率的发光元件。利用这种蒽衍生物可以提供发出高色纯度蓝光的发光元件。在该通式中，A1代表取代或未取代的苯基，B1代表具有1至4个碳原子的烷基或取代或未取代的苯基之一，α代表取代或未取代的苯基或取代或未取代的联苯基-4,4'-二基基团之一，R1至R9分别代表氢、具有1至4个碳原子的烷基，或取代或未取代的苯基之一。
• [EN] ANTHRACENE DERIVATIVE, AND LIGHT-EMITTING MATERIAL, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE USING THE SAME<br/>[FR] DÉRIVÉ D'ANTHRACÈNE ET MATÉRIAU ÉLECTROLUMINESCENT, ÉLÉMENT ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTROLUMINESCENT ET DISPOSITIF ÉLECTRONIQUE UTILISANT CEUX-CI
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2009081800A1

  公开（公告）日：2009-07-02

  Novel anthracene derivatives, novel materials capable of blue light emission with high color purity, and a light-emitting element, a light-emitting device, and an electronic device using any of the novel materials. The anthracene derivative represented by general formula (1) is provided. With the anthracene derivative, a light-emitting element with high emission efficiency can be provided. With the anthracene derivative, a light-emitting element emitting blue light with high color purity can be provided. In the formula, A1 represents a substituted or unsubstituted phenyl group, B1 represents any of an alkyl group having 1 to 4 carbon atoms or a substituted or unsubstituted phenyl group, represents any of a substituted or unsubstituted phenylene group or a substituted or unsubstituted biphenyl-4,4'-diyl group, and R1 to R9 individually represent any of hydrogen, an alkyl group having 1 to 4 carbon atoms, or a substituted or unsubstituted phenyl group.

  提供了新型蒽衍生物，新型材料能够发出高纯度蓝光，并使用这些新型材料制造了发光元件、发光装置和电子设备。提供了通式（1）所表示的蒽衍生物。使用该蒽衍生物，可以提供高发射效率的发光元件。使用该蒽衍生物，可以提供发出高纯度蓝光的发光元件。在该通式中，A1表示取代或未取代的苯基，B1表示具有1至4个碳原子的烷基或取代或未取代的苯基之一，表示取代或未取代的苯基亚甲基或取代或未取代的联苯-4,4'-二基基团之一，R1至R9分别表示氢、具有1至4个碳原子的烷基或取代或未取代的苯基之一。
• Light-Emitting Element, Light-Emitting Device, and Electronic Appliance
  申请人：Ushikubo Takahiro

  公开号：US20090058278A1

  公开（公告）日：2009-03-05

  By use of a 2,9,10-triaryl anthracene derivative in which a diarylamino-substituted aryl group is bonded to the 2-position of a 9,10-diarylanthracene for a light-emitting element, a light-emitting element having high efficiency can be obtained. The emission wavelength of the anthracene derivative is suitable for use in a white light-emitting element. By use of the anthracene derivative for a white light-emitting element, a white light-emitting element having high efficiency can be obtained.

  通过使用一种2,9,10-三芳基蒽衍生物，其中一个二芳基氨基取代的芳基基团连接到9,10-二芳基蒽的2位，可以得到高效的发光元件。该蒽衍生物的发射波长适用于白色发光元件。通过使用该蒽衍生物制备白色发光元件，可以获得高效的白色发光元件。
• ORGANIC COMPOUND, ANTHRACENE DERIVATIVE, AND LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, AND ELECTRONIC DEVICE IN WHICH THE ANTHRACENE DERIVATIVE IS USED
  申请人：KAWAKAMI Sachiko

  公开号：US20080268284A1

  公开（公告）日：2008-10-30

  An anthracene derivative represented by a general formula (1) and an organic compound represented by a general formula (8) are provided. Further, by use of the anthracene derivative represented by the general formula (1), a light-emitting element with high emission efficiency can be obtained. Furthermore, by use of the anthracene derivative represented by the general formula (1), a light-emitting element that emits blue light with high color purity can be obtained.

  提供了一个通式（1）所代表的蒽衍生物和一个通式（8）所代表的有机化合物。此外，通过使用通式（1）所代表的蒽衍生物，可以获得具有高发射效率的发光元件。此外，通过使用通式（1）所代表的蒽衍生物，可以获得发射高纯度蓝光的发光元件。