1-N,N,N'-Trimethyl-N'-<2,3-bis(hexadecyloxy)propyl>ethylenediamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1-N,N,N'-Trimethyl-N'-<2,3-bis(hexadecyloxy)propyl>ethylenediamine
• 英文别名: N'-(2,3-dihexadecoxypropyl)-N,N,N'-trimethyl-ethane-1,2-diamine；N'-(2,3-dihexadecoxypropyl)-N,N,N'-trimethylethane-1,2-diamine
• 化学式: C₄₀H₈₄N₂O₂
• 分子量: 625.119
• InChiKey: AVNACAYMPJTAAR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.6
• 重原子数：
  44
• 可旋转键数：
  38
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  24.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,2-O-双十六烷基-rac-甘油 在 吡啶 、 potassium carbonate 作用下， 以 四氢呋喃 、 乙醚 为溶剂， 反应 99.0h， 生成 1-N,N,N'-Trimethyl-N'-<2,3-bis(hexadecyloxy)propyl>ethylenediamine
  参考文献：
  名称：

  Lipid-catalyzed transport of copper(II) through liquid membranes

  摘要：

  Six long-chained ligands were synthesized and examined for their ability to transport Cu(II) through a liquid membrane. The transport was proton-driven and capable of moving metal ions ''up-hill''. The time-dependence of the Cu(II) concentrations was determined for each carrier and for all three phases of the liquid membrane system. Thus, it was possible to follow the transfer of Cu(II) from the aqueous source phase to the organic layer and from the organic layer to the aqueous receiving phase. In addition, relative partitioning equilibria of Cu(III) between the organic layer and the aqueous phases were compared. It was found that all transport rates were kinetically controlled. Of the six carriers, only one was truly effective (the others experiencing difficulties releasing Cu(II) into the receiving phase). This one carrier displayed a remarkable activity exceeding that of LIX63 (a 'standard' in industrial extractions from copper ore). The activity was attributed to the carrier bearing polar hydroxyls at the ligand end of molecule, thereby enhancing the affinity for the organic/water interface where the rate-determining reactions take place. Studies were carried out varying the pH of the aqueous phases, the carrier concentration, and the nature of the organic layer.

  DOI：

  10.1021/jo00059a050

文献信息

• Lipid-catalyzed transport of copper(II) through liquid membranes
  作者：F. M. Menger、Jeng Jong Lee

  DOI：10.1021/jo00059a050

  日期：1993.3

  Six long-chained ligands were synthesized and examined for their ability to transport Cu(II) through a liquid membrane. The transport was proton-driven and capable of moving metal ions ''up-hill''. The time-dependence of the Cu(II) concentrations was determined for each carrier and for all three phases of the liquid membrane system. Thus, it was possible to follow the transfer of Cu(II) from the aqueous source phase to the organic layer and from the organic layer to the aqueous receiving phase. In addition, relative partitioning equilibria of Cu(III) between the organic layer and the aqueous phases were compared. It was found that all transport rates were kinetically controlled. Of the six carriers, only one was truly effective (the others experiencing difficulties releasing Cu(II) into the receiving phase). This one carrier displayed a remarkable activity exceeding that of LIX63 (a 'standard' in industrial extractions from copper ore). The activity was attributed to the carrier bearing polar hydroxyls at the ligand end of molecule, thereby enhancing the affinity for the organic/water interface where the rate-determining reactions take place. Studies were carried out varying the pH of the aqueous phases, the carrier concentration, and the nature of the organic layer.