4-[4-(2-hydroxyphenyl)butyl]phenol

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4-[4-(2-hydroxyphenyl)butyl]phenol
• 英文别名: Butylenephenol；2-[4-(2-hydroxyphenyl)butyl]phenol
• 化学式: C₁₆H₁₈O₂
• 分子量: 242.318
• InChiKey: BFCOFCKCRLHGNP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2,3-二氢苯并呋喃 在 lithium 、 copper dichloride 、 氯化铵 作用下， 以 四氢呋喃 为溶剂， 反应 0.75h， 以53%的产率得到4-[4-(2-hydroxyphenyl)butyl]phenol
  参考文献：
  名称：

  铜（I）或（II）介导的官能化有机锂化合物的共轭加成或二聚†

  摘要：

  不同官能化有机锂中间体的反应1 - 3与若干电烯烃6在铜的存在下（2-环戊烯酮，2-环己烯酮，甲基乙烯基酮，亚苄基，benzylideneacetophenone和丙烯酸乙酯）（I）盐（溴化物和碘化物）在-78°C的THF中，用氯化铵水解后，可得自共轭物的加成物。在铜的存在下（Ⅱ）氯化物中间体1 - 5进行二聚化，得到预期的二聚体。

  DOI：

  10.1016/s0040-4039(99)02336-9

文献信息

• New reactivity of functionalised organolithium compounds in the presence of Cu(I) or Cu(II) salts: conjugate addition, acylation or dimerisation
  作者：Isidro M Pastor、Miguel Yus

  DOI：10.1016/s0040-4020(01)00105-3

  日期：2001.3

  compounds 1 with electrophilic olefins 2 in the presence of copper(I) iodide and HMPA in THF at −78°C leads, after hydrolysis with a saturated solution of ammonium chloride, to the corresponding products 3 resulting from a conjugate addition. The same process but using an acyl chloride instead of the electrophilic olefins affords the expected ketone 4 from an acylation process. Finally, when intermediates

  官能化的有机锂化合物1与亲电烯烃2在碘化亚铜（I）和HMPA存在下于THF中在-78°C下反应，在用氯化铵饱和溶液水解后，生成由共轭物得到的相应产物3添加。相同的方法，但是使用酰氯代替亲电子的烯烃，从酰化过程提供了期望的酮4。最后，当中间体-1在-78°C下用四氯化铜（II）在THF中处理时，相应的二聚体5在相同的水解处理后被分离出来。
• RUBBER GRAFT COPOLYMER, AND THERMOPLASTIC RESIN COMPOSITION CONTAINING RUBBER GRAFT COPOLYMER
  申请人：Kaneka Corporation

  公开号：EP2840116A1

  公开（公告）日：2015-02-25

  The present invention relates to a thermoplastic resin composition comprising a rubber graft copolymer comprising a core layer containing a rubber copolymer and a shell layer grafted on the core layer and a thermoplastic resin comprising a polycarbonate resin and an aliphatic polyester resin in the mass ratio of the rubber graft copolymer/the thermoplastic resin of 3/100 or more, wherein the shell layer is obtained by polymerizing or copolymerizing a (meth)acrylate: monomer having an epoxy group, and the amount of the (meth)acrylate monomer having an epoxy group is 3 parts by mass or more and less than 29 parts by mass based on 100 parts by mass of the rubber graft copolymer. The thermoplastic resin composition of the present invention can be utilized in various applications, for example, electric and electronic applications such as a personal computer, a liquid crystal display, a projector, a PDA, a printer, a copy machine, a facsimile, a video camera, a digital camera, a cellular phone (smart phone), a portable audio device, a game machine, a DVD recorder, a microwave oven, a rice cooker; building applications such as a light transmitting plate for road, a lighting window, a carport, a lens for lighting, a cover for lighting, a siding for building, and a door; vehicle applications such as a handle, a shift lever, a vibration absorber for an automobile, and a window, a display, a light, a panel of driving seat for train, and the like.

  本发明涉及一种热塑性树脂组合物，该组合物包括一种橡胶接枝共聚物，该橡胶接枝共聚物包括含有橡胶共聚物的芯层和接枝在芯层上的壳层，以及一种热塑性树脂，该热塑性树脂包括聚碳酸酯树脂和脂肪族聚酯树脂，橡胶接枝共聚物/热塑性树脂的质量比为 3/100 或以上，其中壳层是通过聚合或共聚具有环氧基的（甲基）丙烯酸酯单体而获得的：具有环氧基的(甲基)丙烯酸酯单体，且具有环氧基的(甲基)丙烯酸酯单体的量为 3 份(质量分数)或以上，且小于 29 份(质量分数)橡胶接枝共聚物的 100 份(质量分数)。本发明的热塑性树脂组合物可应用于多种领域，例如电子电气领域，如个人电脑、液晶显示器、投影仪、掌上电脑、打印机、复印机、传真机、摄像机、数码相机、手机（智能手机）、便携式音频设备、游戏机、DVD 录像机、微波炉、电饭煲；建筑应用，如道路透光板、照明窗、车棚、照明透镜、照明盖、建筑护墙板和门；车辆应用，如汽车把手、换挡杆、减震器，以及窗、显示器、灯、火车驾驶座面板等。
• Rubber graft copolymer, and thermoplastic resin composition containing rubber graft copolymer
  申请人：KANEKA CORPORATION

  公开号：US10138314B2

  公开（公告）日：2018-11-27

  The present invention relates to a thermoplastic resin composition comprising a rubber graft copolymer comprising a core layer containing a rubber copolymer and a shell layer grafted on the core layer and a thermoplastic resin comprising a polycarbonate resin and an aliphatic polyester resin in the mass ratio of the rubber graft copolymer/the thermoplastic resin of 3/100 or more, wherein the shell layer is obtained by polymerizing or copolymerizing a (meth)acrylate monomer having an epoxy group, and the amount of the (meth)acrylate monomer having an epoxy group is 3 parts by mass or more and less than 29 parts by mass based on 100 parts by mass of the rubber graft copolymer. The thermoplastic resin composition of the present invention can be utilized in various applications.

  本发明涉及一种热塑性树脂组合物，该组合物由橡胶接枝共聚物和热塑性树脂组成，橡胶接枝共聚物包括含有橡胶共聚物的芯层和接枝在芯层上的壳层，热塑性树脂包括聚碳酸酯树脂和脂肪族聚酯树脂，橡胶接枝共聚物/热塑性树脂的质量比为 3/100 或以上、其中，壳层是通过聚合或共聚具有环氧基的（甲基）丙烯酸酯单体而得到的，具有环氧基的（甲基）丙烯酸酯单体的量为 3 份或更多，且以 100 份质量的橡胶接枝共聚物为基准，小于 29 份质量。本发明的热塑性树脂组合物可用于各种用途。
• US4175175A
  申请人：——

  公开号：US4175175A

  公开（公告）日：1979-11-20