N,N',N'',N'''-tetrakis(1-naphthylmethyl)-cyclam

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N,N',N'',N'''-tetrakis(1-naphthylmethyl)-cyclam
• 英文别名: 1,4,8,11-Tetrakis(naphthalen-1-ylmethyl)-1,4,8,11-tetrazacyclotetradecane
• 化学式: C₅₄H₅₆N₄
• 分子量: 761.065
• InChiKey: BJWHAHZKXQEWNY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.8
• 重原子数：
  58
• 可旋转键数：
  8
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.26
• 拓扑面积：
  13
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  1,4,8,11-四氮杂环十四烷 、 (氯甲基)萘 在 三乙胺 作用下， 以 四氢呋喃 为溶剂， 反应 9.0h， 以49%的产率得到N,N',N'',N'''-tetrakis(1-naphthylmethyl)-cyclam
  参考文献：
  名称：

  Synthesis, Complexation and Emission Behavior of N,N',N'',N'''-Tetrakis-(1-naphthylmethyl)-1,4,8,11-tetraazacyclotetradecane

  摘要：

  Cyclam derivative (2) having four naphthylmethyl pendants was found to display unique photophysical properties in the presence of the guest metal salts. The fluorescence of the cyclam (2) was enhanced with various metal salts. The photoinduced electron transfer (PET) sensor (2)exhibited high Zn2+ selectivity.

  DOI：

  10.3987/com-98-8181

文献信息

• Synthesis, Complexation and Emission Behavior of N,N',N'',N'''-Tetrakis-(1-naphthylmethyl)-1,4,8,11-tetraazacyclotetradecane
  作者：Kanji Kubo、Emi Yamamoto、Tadamitsu Sakurai

  DOI：10.3987/com-98-8181

  日期：——

  Cyclam derivative (2) having four naphthylmethyl pendants was found to display unique photophysical properties in the presence of the guest metal salts. The fluorescence of the cyclam (2) was enhanced with various metal salts. The photoinduced electron transfer (PET) sensor (2)exhibited high Zn2+ selectivity.