N-(2'-dimethylphosphinothioylethyl)-N,N',N'-trimethylethylenediamine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(2'-dimethylphosphinothioylethyl)-N,N',N'-trimethylethylenediamine
• 英文别名: N'-(2-dimethylphosphinothioylethyl)-N,N,N'-trimethylethane-1,2-diamine
• 化学式: C₉H₂₃N₂PS
• 分子量: 222.335
• InChiKey: BNEJXHHQCQVIOS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  13
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  N-(2'-dimethylphosphinothioylethyl)-N,N',N'-trimethylethylenediamine 在 lithium aluminium tetrahydride 作用下， 以 1,4-二氧六环 为溶剂， 以69%的产率得到N-(2'-dimethylphosphinoethyl)-N,N',N'-trimethyl-ethylenediamine
  参考文献：
  名称：

  Nucleophilic addition to dimethylvinylphosphine sulfide as a convenient route to polydentate ligands containing the 2-dimethylphosphinoethyl unit

  摘要：

  The synthesis of a range of new phosphine-containing polydentate ligands has been achieved by addition of sulfur and nitrogen nucleophiles to dimethylvinylphosphine sulfide, followed by reduction of the resulting phosphine sulfides with lithium aluminium hydride. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2005.03.012
• 作为产物：
  描述：

  dimethyl(vinyl)phosphine sulfide 、 N,N,N'-三甲基乙二胺 以 乙醇 为溶剂， 反应 72.0h， 以51%的产率得到N-(2'-dimethylphosphinothioylethyl)-N,N',N'-trimethylethylenediamine
  参考文献：
  名称：

  Nucleophilic addition to dimethylvinylphosphine sulfide as a convenient route to polydentate ligands containing the 2-dimethylphosphinoethyl unit

  摘要：

  The synthesis of a range of new phosphine-containing polydentate ligands has been achieved by addition of sulfur and nitrogen nucleophiles to dimethylvinylphosphine sulfide, followed by reduction of the resulting phosphine sulfides with lithium aluminium hydride. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2005.03.012