n-Bu₂SnCl₂*1,10-phenathroline

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 菲咯啉
• 英文名称: n-Bu₂SnCl₂*1,10-phenathroline
• 英文别名: n-Bu₂SnCl₂*phen；dibutyl(dichloro)stannane;1,10-phenanthroline
• 化学式: C₂₀H₂₆Cl₂N₂Sn
• 分子量: 484.056
• InChiKey: MMLROIGPGPCPFV-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.29
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  n-Bu₂SnCl₂*1,10-phenathroline 在 乙酰氯 作用下， 以 硝基苯 为溶剂， 生成
  参考文献：
  名称：

  Siddiqi, K. S.; Kureshy, R. I.; Khan, N. H., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1985, vol. 24, # 3, p. 220 - 222

  摘要：

  DOI：
• 作为产物：
  描述：

  di(n-butyl)tin dichloride triphenylphosphine oxide 在 1,10-菲罗啉 作用下， 生成 n-Bu₂SnCl₂*1,10-phenathroline
  参考文献：
  名称：

  Bajpai, K. K.; Bajpai, Beena, Journal of the Indian Chemical Society, 1982, vol. 59, p. 1090 - 1092

  摘要：

  DOI：

文献信息

• The synthesis and tin-119m mössbauer spectra of some diorganotin dihalide and dipseudohalide complexes with nitrogen- and oxygen-donor ligands
  作者：Alan J. Crowe、Peter J. Smith

  DOI：10.1016/s0022-328x(00)85834-9

  日期：1982.1

  The synthesis and 119mSn Mössbauer spectra of 114 complexes of the type R2SnX2, L2 (R  Me, Et, n-Pr, n-Bu, n-Oct, Ph, Bz; X  F, Cl, Br, I, NCS; L2  2 monodentate or 1 bidentate O- or N-donor ligand(s)), 74 of which are new, are reported. The majority of the complexes are isostructural, having an octahedral trans-R2SnX4 geometry about tin, whilst five of the diphenyltin complexes (R  Ph; X  Cl;

  合成和119米的类型R的114个络合物的Sn穆斯堡尔谱2 SNX 2，L 2（RME等，正PR，正丁基，正-十月中，Ph，BZ; X氟，氯，溴，I，NCS，L 2 2单齿或二齿1 O-或N-供配体（S）），其中74个是新的，则报告。大部分复合物是同构的，具有八面体反式-R 2 SNX 4几何约锡，而二苯基复合物5（RPh值; X氯，L 2 AMP，Nphen; XNCS，L 2  bipy，phen，TMphen）采用顺式-R 2 SnX 4八面体结构。
• Synthesis, characterisation and antimicrobial studies of organotin(IV) complexes with 1,10-phenanthroline derivatives
  作者：Niamh Dolan、John McGinley、John C. Stephens、Kevin Kavanagh、Daniel Hurley、Niall J. Maher

  DOI：10.1016/j.ica.2013.09.038

  日期：2014.1

  The synthesis of several diorganotin(IV) dicarboxylate compounds, including acetates and nicotinates as well as diorganotin(IV) dichloride complexes of the ligands phen, dione and dppz were undertaken. Several difficulties in either the syntheses or complexation reactions with the organic ligands were encountered. The diorganotin(IV) dichloride complexes of the ligands (R2SnCl2 center dot L where R = Me, n-Bu or Ph and L = phen, dione or dppz) were tested against Escherichia coli, Staphylococcus aureus and Pseudomonas aeruginosa. The dibutyltin(IV) derivatives exhibited the broadest range of activity in comparison to the dimethyltin(IV) or diphenyltin(IV) derivatives. The addition of the nicotinate group did not promote activity against any of the bacteria. Furthermore, only in the case of Ph2SnCl2 center dot dione was there improved activity compared to the organic ligand itself. (C) 2013 Elsevier B.V. All rights reserved.
• Qingsham, Li; Pin, Yang; Yianni, Tian, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1996, vol. 26, p. 561 - 572
  作者：Qingsham, Li、Pin, Yang、Yianni, Tian、Jiazhu, Wan、Wenshi, Wu

  DOI：——

  日期：——
• Siddiqi, K. S.; Kureshy, R. I.; Khan, P., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1983, vol. 22, # 7, p. 616 - 617
  作者：Siddiqi, K. S.、Kureshy, R. I.、Khan, P.、Zaidi, S. A. A.

  DOI：——

  日期：——