n-pentyl glycidyl carbonate

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机碳酸及其衍生物
• 英文名称: n-pentyl glycidyl carbonate
• 英文别名: Oxiran-2-ylmethyl pentyl carbonate；oxiran-2-ylmethyl pentyl carbonate
• 化学式: C₉H₁₆O₄
• 分子量: 188.224
• InChiKey: IARGQXJRJXBFJV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.89
• 拓扑面积：
  48.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  戊醇 、 3-O-tosyl glycerol 1,2-carbonate 在 sodium hydride 、 四丁基溴化铵 作用下， 以 四氢呋喃 为溶剂， 以83%的产率得到n-pentyl glycidyl carbonate
  参考文献：
  名称：

  Tosylated glycerol carbonate, a versatile bis-electrophile to access new functionalized glycidol derivatives

  摘要：

  The reactivity of tosylated glycerol carbonate 2 toward nucleophiles has been exploited to generate glycidol analogues protected with carbonate or carbamate groups. The activated glycerol 2 is a reasonable linking agent with thiol and alcohol nucleophiles and an excellent and selective one with primary amines, allowing efficient bis-functionalizations of glycerol. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2009.07.095

文献信息

• Curable adhesive compositions, Process, and applications
  申请人：Liang Rong-Chang

  公开号：US20090181165A1

  公开（公告）日：2009-07-16

  The invention provides an improvement to the useable lifetimes of phenolic-epoxy, phenolic-benzoxazine, phenolic-epoxy-benzoxazine mixtures and other phenolic mixtures through the use of protected phenolics, where a phenolic compound, polymer, or resin is released on demand by the addition of a deblocking agent.

  该发明通过使用受保护酚类化合物，通过添加解保护剂，可以提高酚醛-环氧树脂、酚醛-苯并噁嗪、酚醛-环氧-苯并噁嗪混合物和其他酚类混合物的可用寿命。
• CURABLE ADHESIVE COMPOSITIONS, PROCESS, AND APPLICATIONS
  申请人：Liang Rong-Chang

  公开号：US20120029116A1

  公开（公告）日：2012-02-02

  The invention provides an improvement to the useable lifetimes of phenolic-epoxy, phenolic-benzoxazine, phenolic-epoxy-benzoxazine mixtures and other phenolic mixtures through the use of protected phenolics, where a phenolic compound, polymer, or resin is released on demand by the addition of a deblocking agent.

  本发明提供了一种改进酚酮类、苯并噁嗪类、酚酮-苯并噁嗪混合物以及其他酚类混合物的可用寿命，通过使用保护性的酚类化合物，其中酚类化合物、聚合物或树脂可以通过加入脱保护剂来按需释放。
• Curable liquid resin composition for outermost covering layers of optical fiber line
  申请人：DSM IP Assets B.V.

  公开号：EP2428498A1

  公开（公告）日：2012-03-14

  This invention is a material for coating the outermost layer of optical fiber lines having excellent ability to withstand external stress such as friction or bending with respect to other optical fiber lines or cable coatings, low adhesion between optical fiber lines, and excellent transparency. The composition includes the following components (A), (B), (C), and (D); (A) 30-90 wt.% of total mass urethane (meth)acrylates having structures derived from polyols having aliphatic structures as well as structures derived from polyols having aromatic structures or alicyclic structures, and; (B) 1-60 wt.% of total mass compounds other than urethane (meth)acrylate having ethylene unsaturated radicals, and; (C) 0.1-10 wt.% of total mass polymerization initiator, and; (D) 0.1-10 wt.% of total mass silicone compounds of number-average molecular weight 1000 to 30 000 g/mol.

  本发明是一种用于光纤线路最外层涂层的材料，与其他光纤线路或光缆涂层相比，具有极佳的承受摩擦或弯曲等外部应力的能力，光纤线路之间的附着力低，透明度高。组合物包括以下成分（A）、（B）、（C）和（D）； (A) 占总质量 30-90 重量百分比的聚氨酯（甲基）丙烯酸酯，其结构来源于具有脂族结构的多元醇以及具有芳香族结构或脂环结构的多元醇，以及； (B) 除具有乙烯不饱和基的聚氨酯(甲基)丙烯酸酯外，占总质量 1-60 重量%的化合物，以及 (C) 总质量为 0.1-10 重量百分比的聚合引发剂，以及 (D) 总质量为 0.1-10 重量百分比的硅化合物，其数均分子量为 1000 至 30000 克/摩尔。
• D1563 radiation curable secondary coating for optical fibers
  申请人：DSM IP Assets B.V.

  公开号：US10370557B2

  公开（公告）日：2019-08-06

  A radiation curable secondary coating composition for optical fiber is described and claimed. This radiation curable secondary coating composition includes component (A) which is a urethane (meth)acrylate and component (B) which is a (meth)acrylate compound with two or more ethylenically unsaturated groups and one or more bisphenol structures; wherein the content of component (B) in the composition is 60-300 mass parts per 100 mass parts of component (A). The liquid secondary coating has a viscosity at 25° C. of from about 0.1 Pa·s to about 15 Pa·s. Films obtained by curing the liquid radiation curable secondary coating composition of the present invention have a Young's modulus of from about 600 MPa to about 500 MPa and the breaking elongation of the cured film is from about to 5% to about 50%.

  本发明描述并声称了一种用于光纤的辐射固化二次涂层组合物。这种可辐射固化的二次涂层组合物包括组分（A）和组分（B），组分（A）是聚氨酯（甲基）丙烯酸酯，组分（B）是具有两个或多个乙烯不饱和基团和一个或多个双酚结构的（甲基）丙烯酸酯化合物；其中组分（B）在组合物中的含量为每 100 质量份组分（A）中占 60-300 质量份。液态二次涂层在 25° C 时的粘度约为 0.1 Pa-s 至 15 Pa-s。通过固化本发明的液态辐射固化型二次涂层组合物而获得的薄膜的杨氏模量为约 600 兆帕至约 500 兆帕，固化薄膜的断裂伸长率为约 5%至约 50%。
• JP2011509340A
  申请人：——

  公开号：JP2011509340A

  公开（公告）日：2011-03-24