perfluoro-3-methoxy-2-methylpentane

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: perfluoro-3-methoxy-2-methylpentane
• 英文别名: 1,1,1,2,2,3,4,5,5,5-Decafluoro-3-(trifluoromethoxy)-4-(trifluoromethyl)pentane
• 化学式: C₇F₁₆O
• 分子量: 404.051
• InChiKey: JBWZBFSAKYDCPY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  24
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为产物：
  描述：

  2-(Trifluoromethyl)-3-methoxy-1,1,1,3,4,4,5,5,5-nonafluoropentane 在 cobalt (III) fluoride 、 fluorine 作用下， 生成 perfluoro-3-methoxy-2-methylpentane
  参考文献：
  名称：

  Moldavskii; Bispen; Furin, Russian Journal of Applied Chemistry, 1996, vol. 69, # 4, p. 575 - 582

  摘要：

  DOI：

文献信息

• Synthesis of trifluoromethyl fluoroformate from trifluoromethyl hypofluorite and carbon monoxide: Thermal and catalyzed reaction
  作者：Libin Du、Darryl D. DesMarteau、V. Tortelli、M. Galimberti

  DOI：10.1016/j.jfluchem.2009.07.004

  日期：2009.9

  New and improved routes to trifluoromethyl fluoroformate were developed. Sterically hindered halogenated olefins initiated the reaction of CF3OF and CO under mild conditions, giving yields of up to 80%. The thermal reaction of CF3OF and CO in a flow system was highly dependent on temperature and the type of tubular reactor material. A PTFE reactor gave moderate conversion and high selectivity for the

  开发了新的和改进的途径来制备三氟甲基氟甲酸酯。立体位阻卤代烯烃在温和条件下引发了CF 3 OF和CO的反应，产率高达80％。CF 3 OF和CO在流动系统中的热反应高度依赖于温度和管式反应器材料的类型。PTFE反应器在120°C下对甲酸酯具有中等转化率和较高的选择性。
• The addition of trifluoromethylhypofluorite to hexafluoropropene dimers
  作者：Carlo Corvaja、Francesca Cremonese、Walter Navarrini、Claudio Tonelli、Vito Tortelli

  DOI：10.1016/0040-4039(95)00553-o

  日期：1995.5

  The reaction of trifluomethylhypofluorite with the two anionic dimers of hexafluoropropene leads to the trifluoromethylether adducts in excellent yield. The radical intermediates of the reaction have been detected using the EPR technique.

  三氟甲基次萤石与六氟丙烯的两个阴离子二聚体的反应导致三氟甲基醚加合物的产率极高。反应的自由基中间体已使用EPR技术进行了检测。
• Technology for the preparation of perfluoro-organic compounds
  作者：Dmitrii D Moldavskii、Tatjana A Bispen、Galina I Kaurova、Georgii G Furin

  DOI：10.1016/s0022-1139(98)00351-0

  日期：1999.4

  Fluorination by elemental fluorine of fluorine-containing alkenes, alkanes, ethers and tertiary amines was investigated, aimed at obtaining the perfluorinated analogs. The factors affecting yield of the target compounds were studied. Elements of technology were elucidated. (C) 1999 Elsevier Science S.A. All rights reserved.