{Co(diethylenetriamine)2}Cl3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: {Co(diethylenetriamine)2}Cl3
• 英文别名: [Co(diethylenetriamine)₂]Cl₃；[Co(dien)₂]Cl₃；Co(dien)2Cl3；N'-(2-aminoethyl)ethane-1,2-diamine;cobalt(3+);chloride
• 化学式: C₈H₂₆CoN₆*3Cl
• 分子量: 371.687
• InChiKey: DLYPITIISXBOIA-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -6.01
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  128
• 氢给体数：
  6
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  {Co(diethylenetriamine)2}Cl3 以 not given 为溶剂， 生成 钴
  参考文献：
  名称：

  Kramer, M. D.; Swann, S.; Bailar, J. C., Transactions of the Electrochemical Society, 1947, vol. 90, p. 55 - 62

  摘要：

  DOI：
• 作为产物：
  描述：

  二乙烯三胺 、 cobalt(II) chloride 在 甲烷 作用下， 以 not given 为溶剂， 生成 {Co(diethylenetriamine)2}Cl3
  参考文献：
  名称：

  Kapanadze, T. Sh.; Kokunov, Yu. V.; Tsintsadze, G. V., Doklady Chemistry, 1989, vol. 304, p. 56 - 59

  摘要：

  DOI：

文献信息

• Synthesis, Structure, and Photoluminescence Property of a New Layered Zirconium Phosphate |Co(dien)₂|[Zr₄H₈P₅O₂₆]·3H₂O
  作者：Yu Du、Qinhe Pan、Jiyang Li、Jihong Yu、Ruren Xu

  DOI：10.1021/ic061873i

  日期：2007.7.1

  A new layered zirconium phosphate |Co(dien)(2)|[Zr(4)H(8)P(5)O(26)] x 3H(2)O (denoted ZrPO-CJ37) has been synthesized hydrothermally by using a racemic mixture of a chiral cobaltammine complex Co(dien)(2)Cl(3) as the template. Its structure is determined by single-crystal X-ray diffraction analysis and further characterized by X-ray powder diffraction, inductively coupled plasma, thermogravimetric

  通过使用水热法合成了一种新的层状磷酸锆| Co（dien）（2）| [Zr（4）H（8）P（5）O（26）] x 3H（2）O（表示为ZrPO-CJ37）。手性钴胺碱配合物Co（dien）（2）Cl（3）的外消旋混合物。它的结构通过单晶X射线衍射分析确定，并进一步通过X射线粉末衍射，感应耦合等离子体，热重分析，紫外可见和光致发光分析来表征。ZrPO-CJ37的无机层是通过Zr中心的八面体和P中心的四面体通过顶点氧原子形成4.6网片的连接而建立的。它的结构具有Zr（OM）（6）（M = P，H）八面体的边共享链。钴胺胺络合物阳离子位于夹层区域中，并通过H键与宿主网络相互作用。ZrPO-CJ37在紫外可见光谱区域表现出令人感兴趣的光致发光。Zr（OM）（6）八面体在无机层中的边缘共享链可能是这种异常的光致发光的原因。
• Two layered gallophosphates assembled about the chiral metal complexes: Co(en)3·Ga3P4O16·5H2O and trans−Co(dien)2·Ga3P4O16·3H2O
  作者：Yu Wang、Jihong Yu、Yu Du、Ruren Xu

  DOI：10.1016/j.jssc.2004.03.032

  日期：2004.7

  Two new layered gallophosphates Co(en)3·Ga3P4O16·5H2O (1) and trans-Co(dien)2·Ga3P4O16·3H2O (2) have been hydrothermally synthesized using the racemic mixture of chiral metal complex Co(en)3Cl3 and Co(dien)2Cl3 as the structure-directing agent, respectively. Their structures are determined by single-crystal X-ray diffraction analysis and further characterized by X-ray power diffraction, ICP, elemental

  两种新的层状镓磷酸盐Co（en）3 ·Ga 3 P 4 O 16 ·5H 2 O（1）和反式Co（dien）2 ·Ga 3 P 4 O 16 ·3H 2 O（2）已被水热合成。手性金属配合物Co（en）3 Cl 3和Co（dien）2 Cl 3的外消旋混合物分别作为结构导向剂。它们的结构通过单晶X射线衍射分析确定，并通过X射线功率衍射，ICP，元素分析和TG分析进一步表征。1和2的结构由顶点连接的GaO 4和PO 3（= O）四面体单元组成，形成带有4.6网的大阴离子[Ga 3 P 4 O 16 ] 3-薄片。4.6网是手性[3.3.3]螺旋状样结构图案的特征。1张薄片按ABAB顺序堆叠，带有一对手性Co（en）3 3+的对映异构体居住在中间层区域的阳离子。的片材2阵列以螺旋方式与ABCDEF堆叠序列，只有一种对映体的手性的Co（二烯）的2层3+居住在中间层区域的阳离子。的结构解析1和2揭
• The Synthesis and Characterization of an Aluminophosphate with Chiral Layers;trans-Co(dien)2·Al3P4O16·3H2O
  作者：David A. Bruce、Angus P. Wilkinson、Mark G. White、J.Aaron Bertrand

  DOI：10.1006/jssc.1996.0290

  日期：1996.9

  trans-Co(dien)2·Al3P4O16·3H2O (GTex3) (dien - bis-(2-aminoethyl)amine) was prepared hydrothermally using Co(dien)2Cl3as a structure-directing agent in an aluminophosphate gel. The structure of GTex3 was determined using single-crystal X-ray diffraction. It contains chiral layers distinct from, but related to, those previously found ind,l-Co(en)3·Al3P4O16·xH2O. They are stacked in a helical fashion

  以Co（dien）2 Cl 3为结构导向剂水热制备反式-Co（dien）2 ·Al 3 P 4 O 16 ·3H 2 O（GTex3）（dien-双-（2-氨基乙基）胺）。在铝磷酸盐凝胶中。GTex3的结构使用单晶X射线衍射确定。它包含与先前在d，l -Co（en）3 ·Al 3 P 4 O 16 · x H 2中发现的手性层不同但与之相关的手性层O.它们以螺旋方式与任何一种晶体中的磷酸铝大阴离子的一种对映异构体堆叠在一起。Co（C 4 N 3 H 13）2 ·Al 3 P 4 O 16 ·3H 2 O，M r = 780.1，六角形，P 6 5 2 2，a = b = 8.457（3），c = 63.27（2）埃，V = 3920（2）埃3，ž = 6，ρ X = 1.98 GCM -3，ρ Ë = 1.95 GCM -3，λ（莫ķ对于2277次反射F >4σ（F），α）= 0.71073Å，μ=
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Co: SVol.A, 71, page 336 - 337
  作者：

  DOI：——

  日期：——
• Synthesis and characterization of s-fac-[Co(dien)2](4-np)3(4-npH)·2H2O containing symmetric, [4-np…H…4-np]− and unsymmetric, [4-np-H…4-np−] dimers of 4-nitrophenolate (4-np−)
  作者：Ritu Bala、Amrinder Kaur、Amalija Golobič、Vinit Prakash

  DOI：10.1016/j.poly.2019.114274

  日期：2020.2

  Symmetric [4-np center dot center dot center dot H center dot center dot center dot 4-np](-) and unsymmetric [4-np center dot center dot center dot H center dot center dot center dot 4-np(-)] dimers of 4-np - have been isolated in s-fac-Ko(dien)(2)](4-nP)(3)(4-npH)center dot 2H(2)O (dien = diethylenetriamine) using a one pot synthesis. The crystal structure of the title complex revealed a strong network of H-bonding interactions which lead to the formation of layers of [H(4-np)(2)](-) (symmetric and unsymmetric), s-fac-[Co(dien)(2)](3+) and water molecules. These layers formed their respective columns and the intermolecular cohesion of 4-npH within the columns of the 4-np(-) ions is achieved via nitro-pi and pi-pi stacking interactions. Water also played a dominant role in stabilizing the structure, in which the H-O-H center dot center dot center dot O (4-np(-)) interaction is weaker than [4-np center dot center dot center dot H center dot center dot center dot 4-np](-), but stronger than the N-H center dot center dot center dot O (4-np)(-) and N-H (dien)center dot center dot center dot-H-O interactions. The H-bond present in the symmetric dimer is the strongest one, having an O center dot center dot center dot O contact distance of 2.433(3) angstrom. The presence of the s-fac-isomer of the cation is also supported by IR and H-1, C-13 and 2D H-1-C-13 NMR spectroscopy. The XRD pattern of the product (bulk) was also determined and it shows the presence of a single phase. The binding capacity (log beta = 27.101 +/- 0.06) of [Co(dien)(2)](3+) with the 4-np(-) was determined by UV-vis spectroscopic titrations and the ionic behaviour of the complex was confirmed by molar conductance measurements at infinite dilution (lambda(o) = 800 S cm(2) mol(-1)). (C) 2019 Elsevier Ltd. All rights reserved.