八氢-2H-茚并[1,2-b]环氧乙烯 | 872793-84-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 氧烷类
• 中文名称: 八氢-2H-茚并[1,2-b]环氧乙烯
• 英文名称: Octahydro-1ah-indeno[1,2-b]oxirene
• 英文别名: 1b,2,3,4,5,5a,6,6a-octahydro-1aH-indeno[1,2-b]oxirene
• CAS: 872793-84-5
• 化学式: C₉H₁₄O
• 分子量: 138.21
• InChiKey: SPIDPQOHMQCQPI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.5
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3a,4,7,7a-四羟基茚 在 盐酸 、 水 、 双氧水 、 potassium hydroxide 作用下， 以 乙醚 为溶剂， 反应 2.5h， 生成 1,2:5,6-二环氧六氢茚满 、 2,2a,3,4,5,5a,6,6a-octahydro-1aH-indeno[5,6-b]oxirene 、 八氢-2H-茚并[1,2-b]环氧乙烯
  参考文献：
  名称：

  使用金属卤化物和过氧化氢液相合成环状二烯二环氧化合物

  摘要：

  发现了在[MHlg-HA或HHlg] -H 2 O系统中诱导环二烯（四氢茚，4-乙烯基环己烯和5-乙烯基和5-环己烯基双环[2.2.1]庚-2-烯）的羟基卤化的最佳条件。2（或NaClO）。用粉末状碳酸钾将如此获得的氯代和溴代醇脱氢卤化，得到相应的二环氧衍生物，它们的水解导致形成立体异构的四元醇的混合物。

  DOI：

  10.1134/s1070428012100077

文献信息

• Nonaqueous ink, ink set, image-forming method, image-forming apparatus and recorded article
  申请人：Fujifilm Corporation

  公开号：EP2236569A2

  公开（公告）日：2010-10-06

  A nonaqueous ink, having: colorant particles, the colorant particles having an average particle diameter of 1 nm or more and less than 50 nm, and the value (D90-D10) of being 100 nm or less, a dispersant; and a cationically-polymerizable compound; wherein D90-D10 is a value obtained by subtracting D10 from D90; D90 and D10 represent respectively the particle diameters at cumulative colorant particle numbers of 0.9 (90 number %) and 0.1 (10 number %) in an integral value of the distribution function dG=F(D)dD; and G represents the number of the pigment particles; and D represents the diameter of the particles.

  一种非水性油墨，具有：着色剂颗粒，着色剂颗粒的平均颗粒直径为 1 nm 或以上且小于 50 nm，且值（D90-D10）为 100 nm 或以下，分散剂；以及阳离子可聚合化合物；其中，D90-D10 是用 D90 减去 D10 得到的值；D90 和 D10 分别代表累积着色剂颗粒数为 0.9(90个数%)和0.1(10个数%)的分布函数dG=F(D)dD的积分值；G代表颜料颗粒的数量；D代表颗粒的直径。
• SEMICONDUCTOR ELEMENT AND INSULATING-LAYER-FORMING COMPOSITION
  申请人：FUJIFILM Corporation

  公开号：EP3125277A1

  公开（公告）日：2017-02-01

  Provided is a semiconductor element having a semiconductor layer and an insulating layer adjacent to the semiconductor layer, in which the insulating layer is formed of a crosslinked product of a polymer compound having a repeating unit (IA) represented by the following General Formula (IA) and a repeating unit (IB) represented by the following General Formula (IB). In General Formula (IA), R1a represents a hydrogen atom, a halogen atom, or an alkyl group. L1a and L2a each independently represent a single bond or a linking group. X represents a crosslinkable group. m2a represents an integer of 1 to 5, and in a case where m2a is 2 or more, m2a number of X's may be the same or different from each other. m1a represents an integer of 1 to 5, and in a case where m1a is 2 or more, m1a number of (-L2a-(X)m2a)'s may be the same or different from each other. In General Formula (IB),' R1b represents a hydrogen atom, a halogen atom, or an alkyl group. L1b represents a single bond or a linking group, and Ar1b represents an aromatic ring. m1b represents an integer of 1 to 5.

  本发明提供了一种半导体元件，该元件具有半导体层和与半导体层相邻的绝缘层，其中绝缘层由聚合物化合物的交联产物形成，该聚合物化合物具有如下通式(IA)表示的重复单元(IA)和如下通式(IB)表示的重复单元(IB)。 通式（IA）中，R1a 代表氢原子、卤素原子或烷基。L1a 和 L2a 各自独立地代表单键或连接基团。X 代表可交联基团。m2a 代表 1 至 5 的整数，在 m2a 为 2 或 2 以上的情况下，m2a 中 X 的数目可以相同或不同。m1a 代表 1 至 5 的整数，在 m1a 为 2 或 2 以上的情况下，m1a 中 (-L2a-(X)m2a) 的数目可以相同或不同。通式（IB）中，' R1b 代表氢原子、卤素原子或烷基。L1b 代表单键或连接基团，Ar1b 代表芳香环。
• SEMICONDUCTOR ELEMENT AND INSULATING LAYER-FORMING COMPOSITION
  申请人：Fujifilm Corporation

  公开号：EP3142160A1

  公开（公告）日：2017-03-15

  A semiconductor element which comprises a semiconductor layer and an insulating layer that is adjacent to the semiconductor layer, and wherein the insulating layer is formed of a crosslinked product of a polymer compound that has a repeating unit (IA) represented by general formula (IA) and a repeating unit (IB) represented by general formula (IB); and an insulating layer-forming composition for forming an insulating layer of a semiconductor element, which contains a polymer compound that has the repeating structures (IA) and (IB). (In general formulae, each of R1a and R1b independently represents a hydrogen atom, a halogen atom or an alkyl group; each of L1a, L2a and L1b independently represents a single bond or a linking group; X represents a crosslinkable group; YB represents a decomposable group or a hydrogen atom; each of m1a and m2a independently represents an integer of 1-5; and each * represents a bonding position of the repeating units.)

  一种半导体元件，它包括半导体层和与半导体层相邻的绝缘层，其中绝缘层由具有通式(IA)代表的重复单元(IA)和通式(IB)代表的重复单元(IB)的聚合物化合物的交联产物形成；以及一种用于形成半导体元件绝缘层的绝缘层形成组合物，它含有具有重复结构(IA)和(IB)的聚合物化合物。(通式中，R1a和R1b各自独立地代表氢原子、卤原子或烷基；L1a、L2a和L1b各自独立地代表单键或连接基团；X代表可交联基团；YB代表可分解基团或氢原子；m1a和m2a各自独立地代表1-5的整数；每个*代表重复单元的键合位置)。
• Radiation curable cycloaliphatic barrier sealants
  申请人：Herr E. Donald

  公开号：US20070117917A1

  公开（公告）日：2007-05-24

  A curable barrier sealant comprises a curable resin having a cycloaliphatic backbone and a reactive functional group present at a level that provides an equivalent weight of less than 400 grams per mole of reactive functional group.
• PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL, AND MOLDED PRINTED MATERIAL
  申请人：HAYATA Yuuichi

  公开号：US20080075883A1

  公开（公告）日：2008-03-27

  A process for producing a molded printed material is provided that includes (A) a step of forming an image by discharging an ink composition on a support by an inkjet method, the ink composition comprising at least one compound of monofunctional cationically polymerizable monomer selected from the group consisting of an oxetane compound, an oxirane compound, and a vinyl ether compound, and the proportion of the monofunctional cationically polymerizable monomer in the entire ink composition being at least 30 wt %, (B) a step of curing the ink composition by irradiating with actinic radiation the image obtained so as to obtain a printed material having the image cured on the support, and (C) a step of molding the printed material. There is also provided a molded printed material obtained by the process for producing a molded printed material.