2.2.4.-Trimethyl-glutarsaeure-dinitril

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 2.2.4.-Trimethyl-glutarsaeure-dinitril
• 英文别名: 2,2,4-Trimethylpentanedinitrile；2,2,4-trimethylpentanedinitrile
• 化学式: C₈H₁₂N₂
• 分子量: 136.197
• InChiKey: SIJDDBXWZSHHJP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  10
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  辛基亚硝酸盐 在 偶氮二异丁腈 、 甲苯 作用下， 生成 2.2.4.-Trimethyl-glutarsaeure-dinitril
  参考文献：
  名称：

  亚硝酸辛酯在烃类溶剂中的热分解

  摘要：

  DOI：

  10.1039/jr9540003508

文献信息

• Reactions in Water: Alkyl Nitrile Coupling Reactions Using Fenton’s Reagent
  作者：Christopher L. Keller、James D. Dalessandro、Richard P. Hotz、Allan R. Pinhas

  DOI：10.1021/jo7026905

  日期：2008.5.1

  The coupling reaction of water-soluble alkyl nitriles using Fenton’s reagent (Fe(II) and H2O2) is described. The best metal for the reaction is iron(II), and the greatest yields are obtained when the concentration of the metal is kept low. Hydrogen-atom abstraction is selective, preferentially producing the radical α to the nitrile. In order to increase the production of dinitrile, in situ reduction

  描述了使用芬顿试剂（Fe（II）和H 2 O 2）的水溶性烷基腈的偶联反应。用于该反应的最佳金属是铁（II），当金属的浓度保持在较低水平时，可获得最大的产率。氢原子的提取是选择性的，优先生成腈基的腈基。为了增加二腈的产量，研究了使用多种还原剂将铁（III）原位还原为铁（II）的方法。
• Rate constants for the addition of the 2-cyano-2-propyl radical to alkenes in solution
  作者：K. H?berger、H. Fischer

  DOI：10.1002/kin.550250405

  日期：1993.4

  AbstractAbsolute rate constants for the addition of the 2‐cyano‐2‐propyl radical to 26 alkenes CH2=CXY at 315 K were determined in solution by time‐resolved electron‐spin‐resonance spectroscopy. They vary with the alkene substituents from 30 M−1 s−1 to 7′010 M−1 s−1. For styrene the temperature dependence is given by log k/M−1 s−1 = 7.7 − 26.1/Θ where Θ = 2.303 RT in kJ/mol. An analysis of the substituent effects in terms of polar and enthalpic factors reveals a dominant influence of the overall reaction enthalpy. © 1993 John Wiley & Sons, Inc.
• FLUOROSILICON NITRILE COMPOUNDS
  申请人：Arkema Inc.

  公开号：US20170283443A1

  公开（公告）日：2017-10-05

  Novel fluorosilicon nitrile compounds, and methods of preparing them, are described. The fluorosilicon nitrile compounds are characterized by having a total of four substituents attached to a silicon atom, wherein one or two of the substituents are fluorine atoms, one or two of the substituents are cyanoalkyl groups, which are the same as or different from each other, and the remainder of the substituents, if any, are alkyl groups, which are the same as or different from each other.
• The thermal decomposition of octyl nitrite in hydrocarbon solvents
  作者：Bernard A. Gingras、William A. Waters

  DOI：10.1039/jr9540003508

  日期：——