2-ethyl-N-(2,4,7-trinitrofluorenylidene)aniline

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 2-ethyl-N-(2,4,7-trinitrofluorenylidene)aniline
• 英文别名: N-(2-ethylphenyl)-2,4,7-trinitrofluoren-9-imine
• 化学式: C₂₁H₁₄N₄O₆
• 分子量: 418.365
• InChiKey: NGZDLENDIZDKJC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  31
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  150
• 氢给体数：
  0
• 氢受体数：
  7

反应信息

• 作为产物：
  描述：

  2,4,7-三硝基芴酮 、 2-乙基苯胺 在 zinc(II) chloride 作用下， 反应 6.0h， 以73%的产率得到2-ethyl-N-(2,4,7-trinitrofluorenylidene)aniline
  参考文献：
  名称：

  Synthesis of N-(nitrofluorenylidene)anilines and their application as electron transport materials in positive charge electrophotography

  摘要：

  N-(Nitrofluorenylidene)anilines were synthesized by the condensation of nitrofluorenones with substituted anilines in the presence of zinc chloride. 2-Methyl, 2-ethyl, 2-isopropyl and 2-trifluoromethyl derivatives from 2,4,7-trinitrofluorenone showed high compatibility to polycarbonate and good properties as electron transport materials in positive charge electrophotography. The 2-isopropyl and 2-trifluoromethyl derivatives were substantially stable for the repetition test. N-(2,4,7-Trinitro-fluorenylidene)-2-isopropylaniline was negative for the Ames test.

  DOI：

  10.1039/p29930001107

文献信息

• Synthesis of N-(nitrofluorenylidene)anilines and their application as electron transport materials in positive charge electrophotography
  作者：Masaki Matsui、Katsuyuki Fukuyasu、Katsuyoshi Shibata、Hiroshige Muramatsu

  DOI：10.1039/p29930001107

  日期：——

  N-(Nitrofluorenylidene)anilines were synthesized by the condensation of nitrofluorenones with substituted anilines in the presence of zinc chloride. 2-Methyl, 2-ethyl, 2-isopropyl and 2-trifluoromethyl derivatives from 2,4,7-trinitrofluorenone showed high compatibility to polycarbonate and good properties as electron transport materials in positive charge electrophotography. The 2-isopropyl and 2-trifluoromethyl derivatives were substantially stable for the repetition test. N-(2,4,7-Trinitro-fluorenylidene)-2-isopropylaniline was negative for the Ames test.