2-((3-sulfonic acid)propyl)isoquinolin-2-ium

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异喹啉及其衍生物
• 英文名称: 2-((3-sulfonic acid)propyl)isoquinolin-2-ium
• 英文别名: Hydron;3-isoquinolin-2-ium-2-ylpropane-1-sulfonate；hydron;3-isoquinolin-2-ium-2-ylpropane-1-sulfonate
• 化学式: C₁₂H₁₄NO₃S
• 分子量: 252.314
• InChiKey: TZOTUGCLLXKSEG-UHFFFAOYSA-O

计算性质

• 辛醇/水分配系数(LogP)：
  0.6
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  66.6
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  phosphododecatungstate 、 2-((3-sulfonic acid)propyl)isoquinolin-2-ium 以 水 为溶剂， 反应 24.0h， 生成 [2-((3-sulfonic acid)propyl)isoquinolin-2-ium]₃*PW₁₂O₄₀
  参考文献：
  名称：

  A new organic–inorganic hybrid ionic liquid polyoxometalate for biodiesel production

  摘要：

  A series of organic-inorganic hybrid ionic liquid polyoxometalate were synthesized by combining of 12-tungstophosphoric acid with different sulfonated organic cations. These compounds were used as catalysts in the esterification of oleic acid with methanol. Key physicochemical properties of these hybrids, including their melting points, acidities and solubilities in methanol were determined. Special attention was paid to the temperature-dependence solubilities of these hybrids as a function of their organic cations. Based on experimental findings, a new thermoregulated recoverable homogeneous catalysis system was introduced for biodiesel production. The hybrid catalyst could be reused several times without significant loss of its catalytic activity. As a preliminary application, the hybrid was used as a catalyst in biodiesel production from soybean oil and methanol. Studies reveal that our catalytic system is a promising candidate for biodiesel production from feedstock with high free fatty acids and water content. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molliq.2014.08.034
• 作为产物：
  描述：

  异喹啉 、 1,3-丙烷磺内酯 以 甲苯 为溶剂， 反应 72.0h， 生成 2-((3-sulfonic acid)propyl)isoquinolin-2-ium
  参考文献：
  名称：

  A new organic–inorganic hybrid ionic liquid polyoxometalate for biodiesel production

  摘要：

  A series of organic-inorganic hybrid ionic liquid polyoxometalate were synthesized by combining of 12-tungstophosphoric acid with different sulfonated organic cations. These compounds were used as catalysts in the esterification of oleic acid with methanol. Key physicochemical properties of these hybrids, including their melting points, acidities and solubilities in methanol were determined. Special attention was paid to the temperature-dependence solubilities of these hybrids as a function of their organic cations. Based on experimental findings, a new thermoregulated recoverable homogeneous catalysis system was introduced for biodiesel production. The hybrid catalyst could be reused several times without significant loss of its catalytic activity. As a preliminary application, the hybrid was used as a catalyst in biodiesel production from soybean oil and methanol. Studies reveal that our catalytic system is a promising candidate for biodiesel production from feedstock with high free fatty acids and water content. (C) 2014 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molliq.2014.08.034

文献信息

• THIOSULFATE POLYMER COMPOSITIONS AND ARTICLES
  申请人：Shukla Deepak

  公开号：US20140287349A1

  公开（公告）日：2014-09-25

  A thiosulfate polymer composition includes an electron-accepting photosensitizer component, either as a separate compound or as an attachment to the thiosulfate polymer. The thiosulfate polymer composition can be applied to various articles, or used to form a predetermined polymeric pattern after photothermal reaction to form crosslinked disulfide bonds, removing non-crosslinked polymer, and reaction with a disulfide-reactive material. Such thiosulfate polymer compositions can also be used to sequester metals in nanoparticulate form, and as a way for shaping human hair in hairdressing operations.
• US9772552B2
  申请人：——

  公开号：US9772552B2

  公开（公告）日：2017-09-26
• A new organic–inorganic hybrid ionic liquid polyoxometalate for biodiesel production
  作者：Ezzat Rafiee、Sara Eavani

  DOI：10.1016/j.molliq.2014.08.034

  日期：2014.11

  A series of organic-inorganic hybrid ionic liquid polyoxometalate were synthesized by combining of 12-tungstophosphoric acid with different sulfonated organic cations. These compounds were used as catalysts in the esterification of oleic acid with methanol. Key physicochemical properties of these hybrids, including their melting points, acidities and solubilities in methanol were determined. Special attention was paid to the temperature-dependence solubilities of these hybrids as a function of their organic cations. Based on experimental findings, a new thermoregulated recoverable homogeneous catalysis system was introduced for biodiesel production. The hybrid catalyst could be reused several times without significant loss of its catalytic activity. As a preliminary application, the hybrid was used as a catalyst in biodiesel production from soybean oil and methanol. Studies reveal that our catalytic system is a promising candidate for biodiesel production from feedstock with high free fatty acids and water content. (C) 2014 Elsevier B.V. All rights reserved.