(+/-)-4-Hydroxy-1-(1.4-dimethyl-pentyl)-benzol | 857629-71-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: (+/-)-4-Hydroxy-1-(1.4-dimethyl-pentyl)-benzol
• 英文别名: 4-(1,4-Dimethyl-pentyl)-phenol；4-(1,4-Dimethylpentyl)phenol；4-(5-methylhexan-2-yl)phenol
• CAS: 857629-71-1
• 化学式: C₁₃H₂₀O
• 分子量: 192.301
• InChiKey: DRBKPEIFCPZWCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  (+/-)-4-Hydroxy-1-(1.4-dimethyl-pentyl)-benzol 、 1-Alapha-萘异氰酸酯 生成 [1]naphthyl-carbamic acid-[4-(1,4-dimethyl-pentyl)-phenyl ester]
  参考文献：
  名称：

  Revision of species of the “Oligia” semicana group (Lepidoptera: Noctuidae) with descriptions of a new genus and 12 new species

  摘要：

  AbstractThe name Neoligiagen.nov. is proposed for the "Oligia" semicana (Walker) species group in North America and 12 species, N. rubirena sp.nov., N. pagosa sp.nov., N. hardwicki sp.nov、N. inermis sp.nov.、N. invenusta sp.nov.、N. albirena sp.nov.、N. lancea sp.nov.、N. elephas sp.nov.、N. lillooet sp.nov.、N. surdirena sp.nov.、N. canadensis sp.nov.和 N. atlantica sp.nov.等 12 个种。Hadenella laevigata Smith 与 Hadena tonsa Grote 同源（同义恢复），Hadena hausta Grote 与 Miana semicana Walker 同源（同义恢复）。所有物种的成体以及已知的雄性和雌性生殖器均附有插图。

  DOI：

  10.4039/ent134157-2
• 作为产物：
  描述：

  magnesium,2-methylbutane,bromide 、 对甲氧基苯乙酮 生成 (+/-)-4-Hydroxy-1-(1.4-dimethyl-pentyl)-benzol
  参考文献：
  名称：

  Revision of species of the “Oligia” semicana group (Lepidoptera: Noctuidae) with descriptions of a new genus and 12 new species

  摘要：

  AbstractThe name Neoligiagen.nov. is proposed for the "Oligia" semicana (Walker) species group in North America and 12 species, N. rubirena sp.nov., N. pagosa sp.nov., N. hardwicki sp.nov、N. inermis sp.nov.、N. invenusta sp.nov.、N. albirena sp.nov.、N. lancea sp.nov.、N. elephas sp.nov.、N. lillooet sp.nov.、N. surdirena sp.nov.、N. canadensis sp.nov.和 N. atlantica sp.nov.等 12 个种。Hadenella laevigata Smith 与 Hadena tonsa Grote 同源（同义恢复），Hadena hausta Grote 与 Miana semicana Walker 同源（同义恢复）。所有物种的成体以及已知的雄性和雌性生殖器均附有插图。

  DOI：

  10.4039/ent134157-2

文献信息

• Polyvinyl halide resin compositions containing 1,3 Dicarbonyl compounds
  申请人：PHOENIX CHEMICAL CORPORATION

  公开号：EP0040286A2

  公开（公告）日：1981-11-25

  1,3-Dicarbonyl compounds are provided having the formula: wherein: R1 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR1, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms, and R2 is selected from the group consisting of hydrocarbon having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR1, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; R3 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR1, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; as well as metal and organotin enolate salts thereof. The compounds are effective in enhancing the resistance to deterioration by heat and light of polyvinyl halide resins.

  1,3-二羰基化合物的化学式如下 其中 R1 选自氢、具有 1 至约 18 个碳原子的烃基和被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基的基团取代的此类基团组成的组，和 R2 选自具有 1 至约 18 个碳原子的烃以及被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基的基团取代的烃所组成的组； R3 选自由氢、具有 1 至约 18 个碳原子的烃基以及被 1 个或多个选自由卤素、羟基、烷氧基 OR1、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基组成的基团取代的烃基所组成的组； 以及它们的金属盐和有机锡烯酸盐。 这些化合物可有效提高聚乙烯卤化树脂的耐热和耐光劣化性能。
• Stabilizer composition comprising a thio-1,3-dicarbonyl compound and a heat stabilizer, and vinyl halide polymer composition stabilized therewith
  申请人：S.A. Diamond Shamrock Benelux N.V.

  公开号：EP0028268A1

  公开（公告）日：1981-05-13

  A stabilizer composition is disclosed for increasing the resistance to yellowing and loss of clarity of a vinyl halidepolymer upon heating, which comprises a thio-1,3-dicarbonyl compound represented by the formula in which M represents hydrogen, an organotin group or a metal, R represents hydrogen, a hydrocarbon group or a group-C-R'", each of R,R", and R'" represents hydrogen x or an organic group, X is oxygen or sulfur, and n representing thevalence of M is an integer from 1 to 4. and at least one heat stabilizer which is an alkyltin compound or a metal salt of a non-nitrogenous monocarboxylic acid or of a hydrocarbon-substituted phenol. Stablized vinyl halide polymer compositions, in which the above stabilizer composition is used to improve the resistance to yellowing and the clarity, are also disclosed.

  本发明公开了一种稳定剂组合物，用于提高卤化乙烯基聚合物在加热时的耐黄变性和透明度，该稳定剂组合物由硫代-1,3-二羰基化合物组成，其式如下 其中 M 代表氢、有机锡基或金属，R 代表氢、烃基或基团-C-R'"，R、R "和 R'"各自代表氢 x 或有机基团，X 是氧或硫，代表 M 的价数的 n 是 1 至 4 的整数。 本发明还公开了稳定的卤化乙烯聚合物组合物，其中上述稳定剂组合物用于提高抗黄变性和透明度。
• Stabilized Polyvinylhalide resin
  申请人：PHOENIX CHEMICAL CORPORATION

  公开号：EP0046161A2

  公开（公告）日：1982-02-24

  1,3-Dicarbonyl compounds are provided having the formula: wherein: R1 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COORl, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms, and R2 is selected from the group consisting of hydrocarbon having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR1, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms; one R1 and R2 may be linked together as an alkylene group to form a cyclic or ring structure; n is number from 1 to 3; and Z is a polyvalent linking radical selected from the group consisting of a direct linkage between the groups; polyvalent hydrocarbon R3; wherein: R3 is a polyvalent hydrocarbon group having from one to about eighteen carbon atoms; R4 and Rs are selected from the group consisting of hydrogen and hydrocarbon groups having from one to about eighteen carbon atoms; and R4 and R5 may be linked together as an alkylene to form a cyclic or ring structure; X is -O- od -S-; m is 0 or 1; and R6 is selected from the group consisting of hydrogen, hydrocarbon having from one to about eighteen carbon atoms, and -R3-; as well as metal and organotin enolate salts thereof. The compounds are effective in enhancing the resistance to deterioration by heat and light of polyvinyl halide resins.

  1,3-二羰基化合物的化学式如下 其中 R1 选自氢、具有 1 至约 18 个碳原子的烃基和被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COORl、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基的基团取代的此类基团组成的组，以及 R2 选自具有 1 至约 18 个碳原子的烃组成的组，以及被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基烷基组成的组取代的此类基团； 一个 R1 和 R2 可作为亚烷基连接在一起，形成环状或环状结构； n 为 1 至 3；以及 Z 是多价连接基，选自由基团之间的直接连接、多价烃基 R3 组成的组； 其中 R3 是具有 1 至约 18 个碳原子的多价烃基； R4 和 Rs 选自氢和具有 1 至约 18 个碳原子的烃基；R4 和 R5 可作为亚烷基连接在一起，形成环状或环状结构； X 是-O- od -S- ； m 是 0 或 1；以及 R6选自由氢、具有一至十八个碳原子的烃和-R3-组成的组，以及它们的金属盐和有机锡烯醇盐。 这些化合物可有效提高聚乙烯卤化树脂的耐热和耐光劣化性能。
• Beta-diketone and hydrotalcite stabilizer compositions for halogen-containing polymers and polymer compositions containing the same
  申请人：ADEKA ARGUS CHEMICAL CO., Ltd.

  公开号：EP0063180A1

  公开（公告）日：1982-10-27

  Stabilizer compositions for halogen-containing polymers are provided composed of a β-diketone having the formula: wherein: R1 is selected from the group consisting of hydrogen, hydrocarbon groups having from one to about eighteen carbon atoms and such groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR1, ester COOR,, alkyl and alkoxycarbonyl alkyl having from one to about eighteen carbon atoms, and R2 is selected from the group consisting of hydrogen; hydroxyl; hydrocarbon having from one to about eighteen carbon atoms and such hydrocarbon groups substituted with one or more groups selected from the group consisting of halogen, hydroxy, alkoxy OR,, ester COOR1, alkyl and alkoxycarbonyl having from one to about eighteen carbon atoms; and if Z is R2 or n is 1 to 3, then no more than one R2 is hydrogen; one R1 and one R2 or two R2 may be linked together as an alkylene group to form a cyclic or ring structure; n is a number from 0 to 3; and Z is selected from the group consisting of R2 and a polyvalent linking radical selected from the group consisting of a direct linkage between the polyvalent hydrocarbon R3; wherein: R3 is a polyvalent hydrocarbon group having from one to about eighteen carbon atoms; R4 and R5 are selected from the group consisting of hydrogen and hydrocarbon groups having from one to about eighteen carbon atoms; and R4 and R5 may be linked together as an alkylene to form a cyclic or ring structure; X is -0- or -S-; m is 0 or 1; and R6 is selected from the group consisting of hydrogen, hydrocarbon having from one to about eighteen carbon atoms, and -R3-; as well as metal and organotin enolate salts thereof; and a hydrotalcite having the general formula: wherein x is a number from 0 to 0.5; A is CO3= or S04=, and m is a number representing the number of H20 in the molecule. The stabilizer compositions are effective in enhancing the resistance to deterioration by heat and light of halogen-containing polymers and especially polyvinyl halide resins. The β-diketone and hydrotalcite in these compositions exhibit a synergistic stabilizing effectiveness superior to either alone in like amount.

  提供了用于含卤聚合物的稳定剂组合物，该组合物由具有以下式子的 β-二酮组成： 其中 R1 选自氢、具有 1 至约 18 个碳原子的烃基和被 1 个或多个选自卤素、羟基、烷氧基 OR1、酯 COOR、具有 1 至约 18 个碳原子的烷基和烷氧羰基烷基的基团取代的烃基组成的组，和 R2 选自由下列组成的组：氢；羟基；具有 1 至约 18 个碳原子的烃基，以及被 1 个或多个选自由下列组成的组的基团取代的烃基：卤素、羟基、烷氧基 OR、酯 COOR1、烷基和具有 1 至约 18 个碳原子的烷氧羰基；如果 Z 是 R2 或 n 是 1 至 3，则不超过一个 R2 是氢； 一个 R1 和一个 R2 或两个 R2 可作为亚烷基连接在一起，形成环状或环状结构； n 是 0 至 3 的数字；以及 Z 选自 R2 和多价连接基组成的组，多价连接基选自以下组成的组 多价烃 R3； 其中 R3 是具有 1 至约 18 个碳原子的多价烃基； R4 和 R5 选自氢和具有 1 至约 18 个碳原子的烃基；R4 和 R5 可作为亚烷基连接在一起，形成环状或环状结构； X 是-0-或-S-； m 是 0 或 1；以及 R6 选自由氢、具有 1 至约 18 个碳原子的烃和-R3-组成的组； 及其金属盐和有机锡烯酸盐；以及通式为 其中 x 是 0 至 0.5 的数字； A 是 CO3= 或 S04=，以及 m 是代表分子中 H20 数量的数字。 这些稳定剂组合物能有效提高含卤聚合物，特别是聚卤乙烯树脂的耐热和耐光劣化性能。这些组合物中的β-二酮和氢滑石具有协同稳定效果，其效果优于单独使用相同数量的其中一种。
• Procédé de stabilisation de polymères à base de chlorure de vinyle
  申请人：RHONE-POULENC CHIMIE

  公开号：EP0108023A1

  公开（公告）日：1984-05-09

  L'invention concerne la stabilisation des polymères à base de chlorure de vinyle ainsi que les mélanges stabilisants servant à la réalisation de la stabilisation et les compositions polymériques stabilisées obtenues. Le procédé de stabilisation est caractérisé par l'emploi conjoint de quantités efficaces d'au moins un dérivé organique de lanthanide et d'au moins un dérivé organique de zinc ou de cadmium. A l'aide des polymères stabilisés, on prépare des objets conformés présentant une bonne clarté.

  本发明涉及氯乙烯基聚合物的稳定化，以及用于进行稳定化的稳定化混合物和获得的稳定化聚合物组合物。 该稳定化工艺的特点是联合使用有效数量的至少一种有机镧系衍生物和至少一种有机锌或镉衍生物。 稳定聚合物可用于生产具有良好透明度的成型物品。