1,11-diamino-3,6,9-trioxaundecane

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,11-diamino-3,6,9-trioxaundecane
• 英文别名: 2-[2-(Aminomethoxy)ethoxy]ethoxymethanamine
• 化学式: C₆H₁₆N₂O₃
• 分子量: 164.205
• InChiKey: KHMNXQINDWIXOT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.9
• 重原子数：
  11
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  79.7
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  1,11-diamino-3,6,9-trioxaundecane 、 以 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Aguiari, A.; Brianese, N.; Tamburini, S., New Journal of Chemistry, 1995, vol. 19, p. 627 - 640

  摘要：

  DOI：

文献信息

• COMPOSITION CONTAINING VINYL-GROUP-CONTAINING COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20160046552A1

  公开（公告）日：2016-02-18

  A composition containing a novel vinyl-group-containing compound. This composition contains a vinyl-group-containing compound represented by general formula (1). In the formula: W 1 and W 2 represent a group represented by general formula (2) (where a ring (Z) is an aromatic hydrocarbon ring, X is a single bond or —S—, R 1 is a single bond or a C1-4 alkylene group, R 2 is a specific substituent group such as a monovalent hydrocarbon, and m is an integer equal to 0 or higher), a group represented by general formula (4) (where the ring (Z), X, R 1 , R 2 , and m are as previously stated), a hydroxyl group, or a (meth)acryloyloxy group; rings (Y 1 , Y 2 ) are aromatic hydrocarbon rings; R represents a single bond or a specific divalent group; R 3a and R 3b represent a cyano group, a halogen atom, or a monovalent hydrocarbon group; and n1 and n2 are integers of 0-4.

  这个组合物包含一种含有新颖乙烯基团的化合物。该组合物包含一个由通式（1）表示的含有乙烯基团的化合物。在该式中：W1和W2代表由通式（2）表示的一个基团（其中环（Z）是芳香烃环，X是一个单键或—S—，R1是一个单键或C1-4烷基基团，R2是特定的取代基团，如一价碳氢化合物，m是大于或等于0的整数），一个由通式（4）表示的基团（其中环（Z）、X、R1、R2和m如前述），一个羟基，或一个（甲基）丙烯酰氧基团；环（Y1、Y2）是芳香烃环；R代表一个单键或一个特定的二价基团；R3a和R3b代表氰基、卤素原子或一价碳氢基团；n1和n2是0-4的整数。
• Efficient, Convenient and Mild Three Component Template Preparation and Characterization of Some New Schiff Base Complexes
  作者：Hossein Naeimi、Azam Karshenas

  DOI：10.1002/jccs.201300034

  日期：2013.8

  A few kinds of novel Schiff base complexes have been prepared by three component reaction of the substituted hydroxyacetophenone with several aliphatic diamines and transition metals such as; Ni(II), Zn(II) and UO2(II) under mild reaction conditions. The products have been afforded with excellent yields and appropriate reaction times. The structure of these ligands has been characterized by their IR

  通过取代的羟基苯乙酮与几种脂族二胺和过渡金属（如）的三组分反应，已经制备了几种新颖的席夫碱配合物。Ni（II），Zn（II）和UO 2（II）在温和的反应条件下。已经以优异的产率和适当的反应时间提供了产物。这些配体的结构已通过其IR，1 H NMR，13 C NMR和MS光谱和物理数据进行了表征。
• BASE GENERATOR, PHOTOSENSITIVE RESIN COMPOSITION, PATTERN FORMING MATERIAL COMPRISING THE PHOTOSENSITIVE RESIN COMPOSITION, AND PATTERN FORMING METHOD AND ARTICLE USING THE PHOTOSENSITIVE RESIN COMPOSITION
  申请人：Katayama Mami

  公开号：US20110086311A1

  公开（公告）日：2011-04-14

  A photosensitive resin composition which is excellent in resolution, low in cost, and usable in a wide range of structures of polymer precursors each of which is reacted into a final product by a basic substance or by heating in the presence of a basic substance. The photosensitive resin composition includes a base generator which has a specific structure and generates a base by exposure to electromagnetic radiation and heating, and a polymer precursor which is reacted into a final product by the base generator and by a basic substance or by heating in the presence of a basic substance.

  一种光敏树脂组合物，具有分辨率优良、成本低廉和可用于一系列聚合物前体结构的特点，其中每种聚合物前体都可以通过碱性物质或在碱性物质的存在下加热反应成为最终产物。该光敏树脂组合物包括一种具有特定结构并通过电磁辐射和加热产生碱性物质的基发生剂，以及一种聚合物前体，该聚合物前体通过基发生剂和碱性物质或在碱性物质的存在下加热反应成为最终产物。
• BASE GENERATOR, PHOTOSENSITIVE RESIN COMPOSITION, PATTERN FORMING MATERIAL COMPRISING THE PHOTOSENSITIVE RESIN COMPOSITION, PATTERN FORMING METHOD USING THE PHOTOSENSITIVE RESIN COMPOSITION AND PRODUCTS COMPRISING THE SAME
  申请人：Katayama Mami

  公开号：US20120070781A1

  公开（公告）日：2012-03-22

  An object of the present invention is to provide a base generator which has sensitivity and is applicable to a wide range of applications, and a photosensitive resin composition which is applicable to a wide range of applications due to the structure of a polymer precursor in which reaction into a final product is promoted by a basic substance or by heating in the presence of a basic substance. The base generator generates a base by exposure to electromagnetic radiation and heating. The photosensitive resin composition comprises a polymer precursor in which reaction into a final product is promoted by the base generator and a basic substance or by heating in the presence of a basic substance.

  本发明的目的是提供一种具有灵敏度并适用于广泛应用的基础发生器，以及一种光敏树脂组合物，由于聚合物前体的结构在碱性物质的促进下或在碱性物质存在下加热反应成最终产物，因此适用于广泛的应用范围。基础发生器通过电磁辐射和加热生成碱性物质。光敏树脂组合物包括聚合物前体，其在基础发生器和碱性物质的促进下或在碱性物质存在下加热反应成最终产物。
• POLYAMIC ACID, POLYIMIDE, PROCESS FOR PRODUCING THESE, AND FILM OF THE POLYIMIDE
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1321487A1

  公开（公告）日：2003-06-25

  Disclosed are a polyamic acid having repeating units represented by the formula (1): wherein the norbornane skeleton of comprises four components of and their contents satisfy the following:1 % ≤ 2,5-[diexo] ≤ 90 %,1 % ≤ 2,5-[exo,endo] ≤ 90 %,1 % ≤ 2,6-[diexo] ≤ 90 %,1 % ≤ 2,6-[exo,endo] ≤ 90 %, provided that(2,5-[diexo]) + (2,5-[exo,endo]) + (2,6-[diexo]) + (2,6-[exo,endo]) = 100 %, R represents from 4 to 27 carbon atoms, and represents a tetravalent group selected from the group consisting of an aliphatic group, a monocyclic aliphatic group, a condensed polycyclic aliphatic group, a monocyclic aromatic group, a condensed polycyclic aromatic group, and a non-condensed polycyclic aliphatic or aromatic group which is composed of cycloaliphatic or aromatic groups mutually bonded to each other either directly or via a crosslinking member; and a polyimide which is obtained by imidizing the polyamic acid and which has good properties intrinsic to polyimides, or that is, thermal resistance, mechanical properties, slidability, low water absorption, electric properties and radiation resistance intrinsic thereto. By varying the composition ratio of the starting diamine isomers, various polyimides having controlled thermal resistance, melt flowability, optical properties, chemical resistance and electric properties and capable of forming films of various forms can be obtained.

  本发明公开了一种聚酰胺酸，其重复单元由式（1）表示： 其中降冰片烷骨架 的降冰片烷骨架由以下四个组分组成 其含量满足以下要求：1 % ≤ 2,5-[diexo] ≤ 90 %，1 % ≤ 2,5-[exo,endo] ≤ 90 %，1 % ≤ 2,6-[diexo] ≤ 90 %，1 % ≤ 2,6-[exo,endo] ≤ 90 %，条件是(2,5-[diexo]) + (2,5-[exo,endo]) + (2、(2,6-[exo,endo]) = 100 %，R 代表 4 至 27 个碳原子，并代表选自以下组别的四价基团： 脂肪族基团、单环脂肪族基团、缩合多环脂肪族基团、单环芳香族基团、缩合多环芳香族基团，以及由环脂族或芳香族基团直接或通过交联构件相互结合而成的非缩合多环脂肪族或芳香族基团组成的组；以及一种聚酰亚胺，该聚酰亚胺由聚酰胺酸酰亚胺化而得，具有聚酰亚胺固有的良好性能，即其固有的耐热性、机械性能、滑动性、低吸水性、电性能和耐辐射性。通过改变起始二胺异构体的组成比例，可以获得各种聚酰亚胺，这些聚酰亚胺具有可控的耐热性、熔体流动性、光学性能、耐化学性和电性能，并能形成各种形式的薄膜。