双(2-甲基苯基氨基)甲烷 | 54560-77-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 双(2-甲基苯基氨基)甲烷
• 英文名称: bis(2-methylphenylamino)methane
• 英文别名: N,N'-di-o-tolyl-methanediamine；N,N'-di-m-tolyl-methanediamine；N,N'-di-o-tolyl-methylenediamine；N,N'-Di-o-tolyl-methylendiamin；Methylen-di-o-toluidin；Di-o-toluidino-methan；Methylendi-o-toluidin；N,N'-bis(2-methylphenyl)methanediamine
• CAS: 54560-77-9
• 化学式: C₁₅H₁₈N₂
• 分子量: 226.321
• InChiKey: KOHZWSHQSHYQGV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  双(2-甲基苯基氨基)甲烷 在 盐酸 、 乙醇 作用下， 生成 bis-(4-amino-3-methyl-phenyl)-methane; hydrochloride
  参考文献：
  名称：

  The Political Role of the Internet in Societies in Transition: Russia and Ukraine Compared

  摘要：

  Our research investigates the opportunities provided by the Internet for political parties to communicate to the electorate, and the extent to which party websites are used versus other information sources on the Web. We find that parties in Parliament, major parties and newly created parties are more prominent online than others, and, based on standard quality indicators, that parliamentary parties and new parties have better quality websites. This confirms some of the findings concerning parties online in established democracies. On comparing party with news websites, however, we find that sites of online-only newspapers are the most popular; that online versions of offline news outlets are of secondary importance, in contrast to what has been found in established democracies; and that party and politician websites are of least importance to users, based on the number of hits to these websites. The political role of the Internet in Russia and Ukraine is discussed in conclusion.

  DOI：

  10.1177/1354068803009001720
• 作为产物：
  描述：

  聚合甲醛 、 邻甲苯胺 在 水 作用下， 生成 双(2-甲基苯基氨基)甲烷
  参考文献：
  名称：

  Eibner, Justus Liebigs Annalen der Chemie, 1898, vol. 302, p. 349

  摘要：

  DOI：

文献信息

• ORGANOMETALLIC COMPOUND, ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME, AND DIAGNOSTIC COMPOSITION INCLUDING THE ORGANOMETALLIC COMPOUND
  申请人：Samsung Electronics Co., Ltd.

  公开号：US20210167303A1

  公开（公告）日：2021-06-03

  An organometallic compound represented by Formula 1, an organic light-emitting device including the organometallic compound, and a diagnostic composition including the organometallic compound are provided: M 1 (L 11 ) n11 (L 12 ) n12 Formula 1 wherein, in Formula 1, L 11 may be a ligand represented by Formula 1-1, and the other substituents may be understood by referring to the descriptions thereof provided in the detailed description:

  提供一个由公式1表示的有机金属化合物，包括该有机金属化合物的有机发光器件，以及包括该有机金属化合物的诊断组合物：M1(L11)n11(L12)n12公式1在公式1中，L11可以是由公式1-1表示的配体，其他取代基可通过参考详细描述中提供的描述来理解。
• Insight into the mechanism of 3,3′-dimethyl-4,4′-diaminodiphenylmethane synthesis over Hβ zeolite
  作者：Yingkuo Yang、Yingxian Zhao、Jianhua Shao、Shengjian Zhang、Rongqiang Yang

  DOI：10.1016/j.molcata.2014.10.028

  日期：2015.3

  Heterogeneous synthesis of 3,3′-dimethyl-4,4′-diaminodiphenylmethane (MDT) from o-tolylamine and formaldehyde on acidic zeolites HY, HZSM-5, Hβ and TS-1 was investigated. Hβ zeolite with strong Bronsted acidity and proper textural property demonstrated better catalytic performance than other three zeolites for this synthetic reaction. Yield and selectivity of product MDT from the catalytic reaction

  研究了在酸性沸石HY，HZSM-5，Hβ和TS-1上由邻甲苯胺和甲醛异构合成3,3'-二甲基-4,4'-二氨基二苯甲烷（MDT）。具有强布朗斯台德酸度和适当质构性质的Hβ沸石在该合成反应中显示出比其他三种沸石更好的催化性能。Hβ催化反应产物MDT的收率和选择性强烈依赖于温度，最佳反应温度约为433K。根据LC / MS和1 H NMR分析反应中间体，表明合成方法经历了涉及中间体邻甲苯基氨基甲醇，亚甲基邻甲苯基胺，N，N的多个步骤′-二-邻甲苯基-甲二胺和2-甲基-4-（邻甲苯基氨基-甲基）-苯胺。解释了各种中间体的形成和转化机理。
• [EN] BISPHENOL M DIPHTHALONITRILE ETHER RESIN, BISPHENOL P DIPHTHALONITRILE ETHER RESIN, METHODS OF MAKING SAME, RESIN BLENDS, AND TWO COMPONENT SYSTEMS<br/>[FR] RÉSINE DE BISPHÉNOL M-DIPHTALONITRILÉTHER, RÉSINE BISPHÉNOL P-DIPHTALONITRILÉTHER, PROCÉDÉS POUR LEUR FABRICATION, MÉLANGES DE RÉSINE ET SYSTÈMES À DEUX CONSTITUANTS
  申请人：3M INNOVATIVE PROPERTIES CO

  公开号：WO2017172515A1

  公开（公告）日：2017-10-05

  Resins are provided including bisphenol M diphthalonitrile ether resin or bisphenol P diphthalonitrile either resin. Compositions are also provided, including a primary amine curative and the bisphenol M diphthalonitrile ether resin or the bisphenol P diphthalonitrile either resin. Further, polymerized products are provided of the bisphenol M diphthalonitrile ether resin or the bisphenol P diphthalonitrile either resin. In addition, a method of making a polymerized network is provided. A two component system is further provided, including a curative in one of the components and the bisphenol M diphthalonitrile ether resin or the bisphenol P diphthalonitrile either resin in the other component. In addition, a resin blend is provided, including a blend of at least two of bisphenol M diphthalonitrile ether resin, bisphenol P diphthalonitrile either resin, or bisphenol T diphthalonitrile ether resin.

  提供了树脂，其中包括双酚M二苯甲腈醚树脂或双酚P二苯甲腈醚树脂。还提供了组合物，包括一种主要胺固化剂和双酚M二苯甲腈醚树脂或双酚P二苯甲腈醚树脂。此外，还提供了经聚合的产物，其中包括双酚M二苯甲腈醚树脂或双酚P二苯甲腈醚树脂。此外，还提供了一种制备聚合网络的方法。还提供了一个双组分系统，其中一个组分中含有固化剂，另一个组分中含有双酚M二苯甲腈醚树脂或双酚P二苯甲腈醚树脂。此外，还提供了一种树脂混合物，包括至少两种双酚M二苯甲腈醚树脂、双酚P二苯甲腈醚树脂或双酚T二苯甲腈醚树脂的混合物。
• DIIMINES AND SECONDARY DIAMINES
  申请人：Lee Y. John

  公开号：US20080033210A1

  公开（公告）日：2008-02-07

  This invention provides aromatic diimines which have imino hydrocarbylidene groups with at least two carbon atoms, and aromatic secondary diamines which have amino hydrocarbyl groups with at least two carbon atoms. Both the aromatic diimines and the aromatic secondary diamines either are in the form of one phenyl ring, or are in the form of two phenyl rings connected by an alkylene bridge; each position ortho to an imino group or an amino group bears a hydrocarbyl group. When in the form of one phenyl ring, there are two imino groups on the ring or two amino groups on the ring; the imino groups or amino groups are meta or para relative to each other. When in the form of two phenyl rings connected by an alkylene bridge, there is either one imino group or one amino group on each phenyl ring. Also provided are processes for forming diimines and secondary diamines.

  本发明提供了具有至少两个碳原子的亚胺烃基亚胺基的芳香族二亚胺和具有至少两个碳原子的氨基烃基氨基的芳香族二级二胺。芳香族二亚胺和芳香族二级二胺均为一个苯环的形式或由一个烷基桥连接的两个苯环的形式；每个对位于亚胺基或氨基的位置都带有一个烃基基团。当为一个苯环的形式时，环上有两个亚胺基或两个氨基；亚胺基或氨基相对于彼此是间位或对位的。当为由一个烷基桥连接的两个苯环的形式时，每个苯环上有一个亚胺基或一个氨基。还提供了形成二亚胺和二级二胺的方法。
• Diimines and Secondary Diamines
  申请人：Lee John Y.

  公开号：US20080194788A1

  公开（公告）日：2008-08-14

  This invention provides aromatic diimines where the diimines have imino groups with at least two carbon atoms, and either are in the form of one benzene ring having two imino groups on the ring, which imino groups are meta or para relative to each other, and in which each position ortho to an imino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one imino group on each ring, and in which each position ortho to an imino group bears a hydrocarbyl group. This invention also provides aromatic secondary diamines where the diamines have amino hydrocarbyl groups with at least two carbon atoms, and either are in the form of one benzene ring having two amino groups on the ring, which amino groups are meta or para relative to each other, and in which each position ortho to an amino group bears a hydrocarbyl group, or are in the form of two benzene rings connected by an alkylene bridge and having one amino group on each ring, and in which each position ortho to an amino group bears a hydrocarbyl group. Also provided are processes for forming diimines and secondary diamines from primary diamines, including the aromatic diimines and aromatic secondary diamines of the invention.

  本发明提供了芳香二亚胺，其中二亚胺具有至少两个碳原子的亚胺基，并且可以是具有一个苯环的形式，在该苯环上具有两个亚胺基，这些亚胺基互为间位或对位，并且在每个与亚胺基相邻的位置上带有一个烃基团，或者是由一个烷基桥连接的两个苯环的形式，并且在每个与亚胺基相邻的位置上带有一个烃基团。本发明还提供了芳香二级二胺，其中二胺具有至少两个碳原子的氨基烃基团，并且可以是具有一个苯环的形式，在该苯环上具有两个氨基团，这些氨基团互为间位或对位，并且在每个与氨基团相邻的位置上带有一个烃基团，或者是由一个烷基桥连接的两个苯环的形式，并且在每个与氨基团相邻的位置上带有一个烃基团。本发明还提供了从一级二胺制备二亚胺和二级二胺的方法，包括本发明的芳香二亚胺和芳香二级二胺。