bis(η(5)-indenyl)iron(II)

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: bis(η(5)-indenyl)iron(II)
• 英文别名: bis(η5-indenyl)iron(II)；Fe(η5-C9H7)2}；diindenyliron(II)；bis(indenyl)iron；dibenzoferrocene；Fe(η⁵-indenyl)2
• 化学式: C₁₈H₁₄Fe
• 分子量: 286.156
• InChiKey: GALRLURATBTHJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis(η(5)-indenyl)iron(II) 、 氢气 在 [(η(5)-C5Me5)(η(5)-tetrahydroindenyl)ZrH2]2 作用下， 生成 bis(4,5,6,7-tetrahydroindenyl)iron(II)
  参考文献：
  名称：

  具有烷基取代的环戊二烯基配体的单体和二聚体IV族茂金属二氢化物的制备和表征

  摘要：

  通过氢化相应的二甲基配合物，制备了一系列具有[R n Cp）2 ZrH 2 ] x的具有取代的环戊二烯基配体的一系列锆茂二氢化物配合物。最拥挤空间成员（CP *（η 5 -C 5 HME 4）ZRH 2，（CP * =（η 5 -C 5我5））中，Cp * {η 5 -C 5 H ^ 3 -1,3- （CME 3）2 } ZRH 2和{η 5 -C 5 H ^ 3 -1,3-（CME3）2 } 2 ZrH 2）是单体；那些不太拥挤的构件（的[Cp * {η 5 -C 5 H ^ 4（CME 3）} ZRH 2 ] 2，混合[Cp *（THI）ZRH 2 ] 2（THI =η 5 -tetrahydroindenyl），和[{η 5 -C 5 H 3 -1,3-（CHMe 2）2 } 2 ZrH 2 ] 2）在苯溶液中主要为二聚体。的Cp * {η 5 -C 5 H ^ 3 -1,3-（CHME2）2

  DOI：

  10.1021/om9810293
• 作为产物：
  描述：

  以 not given 为溶剂， 生成 bis(η(5)-indenyl)iron(II)
  参考文献：
  名称：

  Belmont, James A.; Wrighton, Mark S., Organometallics, 1986, vol. 5, # 7, p. 1421 - 1428

  摘要：

  DOI：

文献信息

• Synthesis and properties of optically active helical metallocene oligomers
  作者：Thomas J. Katz、Anantha Sudhakar、Mark F. Teasley、Adam M. Gilbert、William E. Geiger、Matthew P. Robben、Martin Wuensch、Michael D. Ward

  DOI：10.1021/ja00061a018

  日期：1993.4

  Syntheses are described for optically active oligomers 9 and 27. The steps required have three essential features. (1) A bromine directs a photocyclization, blocking both the position it occupies and the one adjacent. (2) An acid scavenger (propylene oxide) prevents benzylic ethers from being eliminated during photocyclization. (3) The stereogenicity of one carbon controls the direction in which the

  描述了光学活性低聚物 9 和 27 的合成。所需的步骤具有三个基本特征。(1) 溴引导光环化，同时阻断它占据的位置和相邻的位置。(2) 酸清除剂（环氧丙烷）可防止苯甲醚在光环化过程中被消除。(3) 一种碳的立体性控制螺旋缠绕的方向。低聚物是第一个制备的，其中茂金属通过双键的共轭系统连接。它们的光学活性非常高。9 的循环伏安图显示了两个阴极波，它们的接近意味着相邻单元之间的相互作用很弱。当 9 在 Pt 上被电化学还原时，会产生一层中性低聚物。该薄膜具有导电性，可催化电荷转移。它的重量，
• Novel organoiron compounds resulting from the attempted syntheses of dibenzofulvalene complexes
  作者：Brian R. Waldbaum、Robert C. Kerber

  DOI：10.1016/s0020-1693(99)00123-1

  日期：1999.8

  2′-biindenyl with Fe(CO)5 generates (η4-2,2′-biindenyl)Fe(CO)3 and a ferrole isomer of (μ,η3:η3-dibenzo[b,e]fulvalene)Fe2(CO)6. Reaction of the dianion of dibenzo[b,e]fulvalene with iron carbonyls produced a novel cyclized acyliron complex, whose structure was proven by X-ray crystallography; a mechanism is proposed for its formation. Reaction of the same dianion with (η5-cyclopentadienyl)Fe(CO)2Br generated

  以Fe（CO）2,2'- biindenyl的热反应5产生（η 4 -2,2'- biindenyl）的Fe（CO）3和（μ的ferrole异构体，η 3：η 3 -二苯并[b， e]富瓦烯）Fe 2（CO）6。二苯并[b，e]富瓦烯的二价阴离子与羰基铁的反应生成了一种新型的环化酰基丙隆配合物，其结构已通过X射线晶体学证实。提出了一种形成它的机制。用（η相同二价阴离子的反应5 -环戊二烯基）铁（CO）2溴生成另一个新的环状化合物（C 18 H ^ 12）的Fe（CO）2（C 5 H ^ 4），可能是通过η分子内自由基攻击5结合的环戊二烯基环。二苯并治疗并[a，d]富瓦烯为Fe 2（CO）9产生（η 2 -二苯并[a，d]富瓦烯）的Fe（CO）4，（μ，η 2：η 2 -二苯并[a，d]富瓦烯）的Fe 2（CO）8，和与双两种化合物（η 5）的结构。这些似乎有CO和Fe（CO）4个基团插入的活性铁-铁键（μ，η
• Diels−Alder Reactions of Benzyne with Indenyl Iron Complexes
  作者：Baiquan Wang、Bin Mu、Dafa Chen、Shansheng Xu、Xiuzhong Zhou

  DOI：10.1021/om049430e

  日期：2004.12.1

  tetramethyldisilylene-bridged bis(indenyl) iron (Me2SiSiMe2)(η5-C9H6)2Fe (12) with benzyne gave only the monoadduct (13). Complex 2 was also tested for ring-opening metathesis polymerization (ROMP) in the presence of Grubbs' catalyst [(PCy3)2RuCl2CHPh] but was found to be inactive under normal conditions. The molecular structures of 2, 5, 8, and 13 have been determined by X-ray diffraction.

  茚基铁化合物（η 5 -C 9 ħ 7）的Fe（η 5 -C 5 H ^ 5）（1）被发现与苯炔反应，从生成ö由氟化物诱导1,2-消除-trimethylsilylphenyl三氟甲磺酸酯，对得到Diels-Alder加合物1，2-（1，4-二氢萘-1，4-二基）二茂铁（2）。当双（茚基）铁配合物（η 5 -RC 9 ħ 6）2的Fe [R = H（3）; 2Me（6）; 1-SiMe 3（9）]与苯并，双加合物[R = H（5）; 2Me（8）; 与相应的单加合物[R = H（4）; 1-SiMe 3（11）]一起获得。2Me（7）; 1-SiMe 3（10）]。tetramethyldisilylene桥连双（茚基）铁的反应（ME 2 SiSiMe 2）（η 5 -C 9 ħ 6）2的Fe（12）与苯炔，得到仅单加成物（13）。在Grubbs催化剂[[PCy 3）2存在下，还测试了配合
• Synthesis, structures and spectroelectrochemistry of methyl-substituted bis(η5-indenyl)iron(II) complexes
  作者：Owen J. Curnow、Glen M. Fern

  DOI：10.1016/j.jorganchem.2005.03.036

  日期：2005.6

  Several new methyl-substituted indenyl ferrocenes were prepared by metathesis reactions of the indenide (generated from the appropriate indene with BuLi) with ferrous chloride. The indenides used to prepare new ferrocenes were: 2-methyl-, 1,2-dimethyl-, 4,7-dimethyl-, 1,4,7-trimethyl-, and 1,3,4,7-tetramethyl-indenide. These indenyl ferrocenes, along with those prepared from indenide, 1-methylindenide, and 1,3-dimethylindenide, were then characterized by H-1 and C-13 NMR, UV/visible spectroscopy, cyclic voltammetry and mass spectrometry. The cyclic voltammetry showed an additive relationship between oxidation potential and the number of methyl groups which is also position-dependent, whereas the UV/visible spectra showed two absorptions essentially unaffected by methyl substitution. Additionally, bis(2-methylindenyl)iron(II) and bis(4,7-dimethylindenyl)iron(II) were characterized by X-ray crystallography. (c) 2005 Elsevier B.V. All rights reserved.
• Synthesis of iron complexes [(η5-indenyl)FeL3]+ from the readily available[(η5-indenyl)Fe(η6-indene)]+
  作者：Dmitry S. Perekalin、Maria V. Babak、Eduard E. Karslyan、Yulia V. Nelyubina、Alexander R. Kudinov

  DOI：10.1016/j.ica.2012.06.018

  日期：2012.9

  The iron complex [(eta(5)-indenyl)Fe(eta(6)-indene)](+) (1) was prepared via one-pot procedure in 25% yield by reaction of FeCl3 with indenyl lithium giving Fe(eta(5)-indenyl)(2) and its subsequent protonation with CF3COOH. Cation 1 reacts with 2e ligands L (L = (BuNC)-Bu-t, P(OMe)(3), P(OEt)(3), PMe(OEt)(2)) under visible light irradiation giving the half-sandwich complexes [(eta(5)-indenyl)FeL3](+) in 50-80% yields. Protonation of the related ruthenium complex Ru(eta(5)-indenyl)(2) gives cation [(eta(5)-indenyl)Ru(eta(6)-indene)](+) (23% yield). The structures of [1]BF4 and [(eta(5)-indenyl)Fe((BuNC)-Bu-t)(3)]PF6 were determined by X-ray diffraction. (C) 2012 Elsevier B. V. All rights reserved.

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