2-(4-methoxynaphthalen-1-yl)benzo[d]thiazole

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-(4-methoxynaphthalen-1-yl)benzo[d]thiazole
• 英文别名: 2-(4-Methoxynaphthalen-1-yl)-1,3-benzothiazole
• 化学式: C₁₈H₁₃NOS
• 分子量: 291.373
• InChiKey: ZMKUVJDSTSGSSM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.3
• 重原子数：
  21
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  50.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  iridium(III) chloride trihydrate 、 2-(4-methoxynaphthalen-1-yl)benzo[d]thiazole 以 乙二醇乙醚 、 水 为溶剂， 反应 18.0h， 以84%的产率得到
  参考文献：
  名称：

  Red Phosphorescent Naphthalene-Based Iridium(III) Complex for Solution-Processed Single-Emissive-Layer White Organic Light-Emitting Diodes

  摘要：

  We designed and synthesized a red phosphorescent iridium(III) complex, (BTMN)(2)Ir(acac), for solution-processed single-emissive-layer organic light-emitting diodes (OLEDs), which contains 2-(4-methoxynaphthalen-1-yl)benzo[d]thiazole (BTMN) as the main ligand and acetylacetone (acac) as the ancillary ligand. The photophysical, electrochemical, and electroluminescent (EL) properties of (BTMN) 2Ir(acac) were investigated. Solution-processed single-emissive-layer red and white OLEDs were fabricated using (BTMN) 2Ir(acac) doped in poly(9-vinylcarbazole) (PVK) as the emitting layer. The EL spectra of (BTMN) 2Ir(acac) exhibited a maximum emission peak at 598 nm with a full-width at half-maximum (FWHM) of 75 nm and Commission Internationale de L'Eclairage (CIE) coordinates of (0.59, 0.37) at 1000 cd.m(-2). In addition, white-light-emitting devices exhibited CIE coordinates of (0.32, 0.38) at 1000 cd.m(-)2, which are close to the standard white-light CIE coordinates of (0.33, 0.33).

  DOI：

  10.1166/jnn.2016.12496
• 作为产物：
  描述：

  4-甲氧基-1-萘甲醛 、 2-氨基苯硫醇 以 二甲基亚砜 为溶剂， 反应 24.0h， 以89%的产率得到2-(4-methoxynaphthalen-1-yl)benzo[d]thiazole
  参考文献：
  名称：

  Red Phosphorescent Naphthalene-Based Iridium(III) Complex for Solution-Processed Single-Emissive-Layer White Organic Light-Emitting Diodes

  摘要：

  We designed and synthesized a red phosphorescent iridium(III) complex, (BTMN)(2)Ir(acac), for solution-processed single-emissive-layer organic light-emitting diodes (OLEDs), which contains 2-(4-methoxynaphthalen-1-yl)benzo[d]thiazole (BTMN) as the main ligand and acetylacetone (acac) as the ancillary ligand. The photophysical, electrochemical, and electroluminescent (EL) properties of (BTMN) 2Ir(acac) were investigated. Solution-processed single-emissive-layer red and white OLEDs were fabricated using (BTMN) 2Ir(acac) doped in poly(9-vinylcarbazole) (PVK) as the emitting layer. The EL spectra of (BTMN) 2Ir(acac) exhibited a maximum emission peak at 598 nm with a full-width at half-maximum (FWHM) of 75 nm and Commission Internationale de L'Eclairage (CIE) coordinates of (0.59, 0.37) at 1000 cd.m(-2). In addition, white-light-emitting devices exhibited CIE coordinates of (0.32, 0.38) at 1000 cd.m(-)2, which are close to the standard white-light CIE coordinates of (0.33, 0.33).

  DOI：

  10.1166/jnn.2016.12496

文献信息

• Red Phosphorescent Naphthalene-Based Iridium(III) Complex for Solution-Processed Single-Emissive-Layer White Organic Light-Emitting Diodes
  作者：Jae-Ho Jang、Min Ji Kim、Hee Un Kim、Seul Bee Lee、Jaemin Lee、Do-Hoon Hwang

  DOI：10.1166/jnn.2016.12496

  日期：2016.8.1

  We designed and synthesized a red phosphorescent iridium(III) complex, (BTMN)(2)Ir(acac), for solution-processed single-emissive-layer organic light-emitting diodes (OLEDs), which contains 2-(4-methoxynaphthalen-1-yl)benzo[d]thiazole (BTMN) as the main ligand and acetylacetone (acac) as the ancillary ligand. The photophysical, electrochemical, and electroluminescent (EL) properties of (BTMN) 2Ir(acac) were investigated. Solution-processed single-emissive-layer red and white OLEDs were fabricated using (BTMN) 2Ir(acac) doped in poly(9-vinylcarbazole) (PVK) as the emitting layer. The EL spectra of (BTMN) 2Ir(acac) exhibited a maximum emission peak at 598 nm with a full-width at half-maximum (FWHM) of 75 nm and Commission Internationale de L'Eclairage (CIE) coordinates of (0.59, 0.37) at 1000 cd.m(-2). In addition, white-light-emitting devices exhibited CIE coordinates of (0.32, 0.38) at 1000 cd.m(-)2, which are close to the standard white-light CIE coordinates of (0.33, 0.33).